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Explore the properties, structures, and production of automotive glasses, including tempered, zoned tempered, and laminated glasses. Learn about glass applications, transition temperatures, and various types of popular glasses in the automotive industry. Discover the processes involved in flat glass production and tempering, as well as the benefits of laminating processes for automotive glass.
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Automotive Production Engineering; Glasses Somsak Siwadamrongpong 2/2552
Contents • Glass properties • Chemical, Physical and Optical properties • Glass structure • Automotive glasses • Tempered glasses • Zoned tempered glasses • Laminated Glasses • Automotive glass production
Glass Properties • General properties of glasses • High hardness / Brittle • Low density compared to high strength • Low thermal expansion coefficient • Low heat / electrical conductivity • High melting point • Good chemical resistance / Chemical inert • Wide range of optical transmission • Transparent • Translucent • Opaque
Glass transition temperature; Tg By TMA: Thermal Mechanical Analysis
Glass transition temperature; Tg By DSC: Differential Scanning Calorimetry
Popular Glasses • Silicate glasses • Soda lime silicate • Aluminosilicate • Borosilicate • Phosposilicate • Chalcogenide glasses • Fluoride glasses • Ceramic Glaze
Glass structure; silicate (SiO2) Crystalline Amorphous
Glass structure; silicate (SiO2) Tetrahedral SiO2
O O O Si O O O O Si O O Si Si O O O O Si O O O O O Si O Glass structure; silicate : Vitreous silica (SiO2) • Each Si tetrahedron links to 4 tetrahedra by sharing corner with each other • All oxygen are presence as bridging oxygen (BO)
O O O Si Na+ O Na+ O O O- O- Si O O- O- Si Na+ Si Na+ O O O O Si O O O O O Si O Glass structure; silicate : Binary silicate glass (6SiO2-2Na2O) • Network linkage is broken as entering of network modifier • Non-bridging oxygen (NBO) is initiated and its charge is compensated with the metal cation
O O O Na+ Si O O Na+ O O- O- Si O O O Si Si O O Al O O Si O O O O - O O O O Al O Si Na+ Na+ - O O Glass structure; silicate : Ternary alumino-silicate glass (6SiO2-Al2O3-2Na2O) • Network consists of Si and Al tetrahedra • Metal cation is compensated by AlO2- and the excess cation will break the network and compensate with NBO
2+ 2+ 2+ Glass structure; silicate : Ternary alumino-silicate glass (SiO2-Al2O3-CaO) system Al Si O Ca
Automotive Glasses • Tempered glasses / Zoned tempered glasses • Used for side and rare glasses • Laminated glasses • Used for front glass • Other glasses • UV / IR cut glass • Privacy glass • Water repelling glass
before cooling surface cooling further cooled compression cooler hot hot tension compression cooler Tempered glasses Strength increase 3-5 times of annealed glasses
Tempered glasses Tempered glass Zone tempered glass
Laminated Glasses PVB = Polyvinyl Butyral Interlaying Film
Glass Production Sand powder (SiO2), Al2O3, Na2O, CaO, MgO Raw Materials Floating Technique Flat Glass For construction, panel automotive and others • Tempered Glasses • Laminated Glasses
Floating Technique A A Section A-A
Glass Tempering Processes Washing / Drying Section Laminating / Heating Section
Glass Laminating Processes Inspection, Packing
Glass Laminating Processes Pre-Processes for Glass Laminating
Glass Laminating Processes Post-Processes for Glass Laminating
Q & A