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Literature Report

Literature Report. 光电催化还原 CO2 的发展现状. Ang Li 2013.7.25. Photo-induced CO 2 Reduction with GaN Electrode in Aqueous System. Satoshi Yotsuhashi, Masahiro Deguchi, Yuji Zenitani, Reiko Hinogami, Hiroshi Hashiba, Yuka Yamada, and Kazuhiro Ohkawa. Applied Physics Express4 (2011).

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Literature Report

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  1. Literature Report 光电催化还原CO2的发展现状 Ang Li 2013.7.25

  2. Photo-induced CO2Reduction with GaNElectrode in Aqueous System Satoshi Yotsuhashi, Masahiro Deguchi, Yuji Zenitani, Reiko Hinogami, Hiroshi Hashiba, Yuka Yamada, and Kazuhiro Ohkawa Applied Physics Express4 (2011)

  3. Analysis method: Gas phase products: • H2: GC-TCD • CO, CH4: GC-FID Liquid phase products: • HCOOH: HPLC

  4. Potential of Cu electrode: -1.07V -0.16V CO2reduction is realized without extra power input except for illumination with light.

  5. Faradic efficiency for HCOOH:3.2%

  6. Preliminary proposal Target: Gas phase products: H2, CO, CH4, CO2, N2 Liquid phase products: HCOOH, CH3OH Method: Gas phase products: GC Liquid phase products: GC(for HCOOH),HPLC (for CH3OH)

  7. Preliminary proposal

  8. HPLC Different from GC: • Free of the limitation of Volatility and thermal stability • A broad range of Objects: GC—20% of Organics • HPLC—80% of Organics • Mobile phase: GC— inert gas, no interact with Component • HPLC—liquid, have interact with Component, so • the Polarity, PH value, Composition of • mobile liquid is important for Separate • Temperature and pressure: GC—add the temperature • HPLC—room temperature • high pressure, for the Narrower • peaks because of the high • viscosity

  9. LLC LSC Different solubility in Two kinds of Solvent, just like L-L extraction.

  10. Sliver paste Which kind? SEM? How?Spin coating? How to control the Thickness to be Uniform?

  11. Thank You !

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