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Thermochemistry. Thermochemistry deals with the interaction of hest and energy with matter (heat flow that accompanies chemical reactions).Energy is defined as the capacity to do work, while heat is a form of energy.. Principles of Heat Flow. System: part of the universe of interest.Surroundings: exchange energy with the system, is the rest of the universe.In a chemical reaction, the system would be the reactants and the products and the surroundings would be the reaction vessel (beaker, te288

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