Chapter 7: Thermodynamic Driving Forces. “Thermodynamics is Two Laws and a Little Calculus”. I. Definitions. Thermodynamic system - what we study Open: can exchange U, V, n Closed: can exchange U, V, but not n Isolated: cannot exchange U, V, n Surroundings - everything else Boundaries
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“Thermodynamics is Two Laws and a Little Calculus”
dU = δq + δw
dU = T dS – p dV (for closed system)
dS = δq/T