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KONDENZATORJI

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KONDENZATORJI

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    1. KONDENZATORJI

    18. In a multilayer ceramic capacitor, a capacitance of more than 100µF can be acquired through combined use of the thin-layer technology in which the thickness of a dielectric layer approaches 1um, and the multilayer technology wherein hundreds to 1,000 layers are exceeded. As a result, a compact and high-capacitance multilayer ceramic capacitor has also been used for a decoupling capacitor, for which an electrolytic capacitor has been mainly used until now, or power smoothing capacitor. More effective decoupling performance or power smoothing characteristics is anticipated based on the excellent frequency characteristics of a multilayer ceramic capacitor. The application will be promoted more and more in the future. Acquired Capacitance Range Fig.1 shows various capacitors mainly used for general electronic equipment according to the relation between the acquired capacitance value and rated voltage. In a capacitance range of less than 1µF, a type 1 (temperature compensating) ceramic capacitor, a type 2 (high dielectric constant) ceramic capacitor, and a film capacitor are put into use. An aluminum electrolytic capacitor or tantalum electrolytic capacitor has been mainly used in the high-capacitance range exceeding 1µF. In recent years, with the progress of the high-capacitance technology in a multilayer ceramic capacitor, the capacitance value per volume has been rapidly expanded (Fig.2), and a capacitance range of more than 100µF can be acquired even in a multilayer ceramic capacitor. Fig.3 shows the relation between the acquired capacitance value and rated voltage of a high-capacitance multilayer ceramic capacitor exceeding 1µF for each chip size. The relation between each chip size and the maximum acquired capacitance value indicates that a capacitance value of up to 1µF can be acquired in 1005 size, that of up to 10µF can be acquired in 1608 size, and that of up to 100µF can be acquired in 3225 size. Moreover, the rated voltage is lined up so that it is provided up to DC 100V and widely used for various applications. Judging from the 48 AEI October 2004 High-Capacitance Multilayer Capacitor Delivers Better Performance Fig. 1: Relation between capacitance value and rated voltage in each capacitor Fig. 2: Transition of capacitance value per volume and dielectric thickness Fig. 3: Range of capacitance value and rated voltage in each size Copyright ? 2005 Dempa Publications, Inc. relation of the chip size and the maximum acquired capacitance value, the development of a compact and high-capacity multilayer ceramic capacitor will be promoted more and more in future by the progress of technology. Frequency Characteristics The structure of a multilayer ceramic capacitor is shown in Fig.4. In the capacitor, dielectric ceramics and electrodes are alternately accumulated for formation. A metal such as nickel is generally used for electrode materials. Therefore, the electrode resistance influencing the equivalent series resistance (ESR) value or loss of a capacitor is lower than for an electrolytic capacitor by a few digits. Fig.5 shows the comparison of the frequency impedance characteristics of a 10µF high-capacitance multilayer ceramic capacitor with those of an aluminum electrolytic capacitor and tantalum electrolytic capacitor. For the impedance characteristics of an ideal capacitor, the impedance decreases by one digit when a frequency increases by one digit. As shown in Fig.5, however, for the impedance characteristics of an aluminum electrolytic capacitor, the impedance value becomes constant at approximately 10? and does not decrease any longer when a frequency reaches a few kilohertz or more. In a tantalum electrolytic capacitor, the impedance value does not decrease when a frequency reaches some 10kHz or more. The impedance value becomes constant at some hundred milliohms. In a multilayer ceramic capacitor, an almost ideal impedance decrease is observed until a self-resonance frequency of approximately 1MHz is reached. The impedance value at that time is a few milliohms. When a frequency becomes higher, an impedance value increases due to the influence of an equivalent serial inductance (ESL) term. The value obtained when the impedance of each capacitor is lowest is equivalent to an ESR (equivalent serial resistance) value. The ESR value of a multilayer ceramic capacitor that uses a metal lower in a resistance value than for an electrolytic capacitor as the electrode of a capacitor is low. Fig.6 shows the relation between the current value and capacitor surface temperature occurring when a sine wave current with a frequency of 100kHz flows through each capacitor with a capacitance value of 100µF. For the multilayer ceramic capacitor whose ESR value is low, the heat generation caused by a heavy current is low and the increase in the surface temperature is less than for other capacitors. This indicates that the multilayer ceramic capacitor is suitable for a heavycurrent power smoothing capacitor. Application to Decoupling Capacitor In each circuit module or IC, a decoupling capacitor is set in the power circuit to secure the stabilized operation and function. The decoupling capacitor is used to remove or reduce the noise occurring via a power line or the noise generated by its own operation. In the past, a high-capacitance electrolytic capacitor and low-capacitance ceramic capacitor were frequently used in combination for a decoupling capacitor. However, in one decoupling capacitor, a high decoupling effect can be obtained over a wide-range frequency by using a Fig. 4: Structure of multilayer ceramic capacitor Fig. 5: Comparison of frequency and impedance characteristics in each capacitor Fig. 6: Comparison of high-frequency current and surface rising temperature in each capacitor 50 AEI October 2004 Copyright ? 2005 Dempa Publications, Inc. high-capacitance multilayer ceramic capacitor with excellent frequency impedance characteristics. As shown in Fig.7, the peak values of waveforms obtained on the output side are compared for each capacitor when a peak value of 2V pulse wave, a frequency of 100kHz, and 1MHz are supplied to the circuit shown in Fig.7. The effect of noise absorption is investigated in this case. In a pulse wave of 100kHz, the peak value when an aluminum electrolytic capacitor with a capacitance value of 220µF is used is 46 mVp-p. However, the peak value decreases to 28 mVp-p at a capacitance value of 1/4 (47µF) when a tantalum electrolytic capacitor is used. When a multilayer ceramic capacitor is used instead of the tantalum electrolytic capacitor, the peak value decreases to the almost the same level as for the tantalum electrolytic capacitor at a capacitance value of 1/10 (22µF). In other words, by using a multilayer ceramic capacitor, a pulse absorption effect equal to or of more than when using these electrolytic capacitors is obtained at the 1/10-capacitance value of an aluminum electrolytic capacitor or the 1/2- capacitance value of a tantalum electrolytic capacitor. Even in a pulse wave of 1MHz, similarly, pulse absorption characteristics equal to or of more than these electrolytic capacitors can be obtained using a multilayer ceramic capacitor with the capacitance value that is 1/50 of an aluminum electrolytic capacitor and 1/10 of a tantalum electrolytic capacitor. Fig.8 shows the block diagram of a 40W output class D power amplifier circuit. Amultilayer ceramic decoupling capacitor of 10µF is used for decoupling capacitors C1 and C2 at the Vcc pin of IC. Two aluminum electrolytic capacitors are connected in parallel to decoupling capacitors C3 and C4 in the power input block on the board. The power ripple voltage waveforms when a multilayer ceramic capacitor is used instead of aluminum electrolytic capacitors C3 and C4 are shown in Fig.9. A ripple voltage of 88 mVp-p in an aluminum electrolytic capacitor becomes 71 mVp-p when two multilayer ceramic capacitors of 10µF are used instead. By using the multilayer ceramic capacitors, a ripple reduction effect equal to or of more than when using aluminum electrolytic capacitor can be obtained even at a capacitance value of 1/10. 51 AEI October 2004 Fig. 7: Comparison of noise absorption characteristic in each capacitor Fig. 8: Block diagram of class D power amplifier circuit Fig. 9: Comparison of power ripple voltage waveforms in aluminum electrolytic capacitor and multilayer ceramic capacitor Copyright ? 2005 Dempa Publications, Inc. Application to Smoothing Capacitor for DC/DC Converter Fig.10 shows the block diagram of the PWM DC/DC down-converter used for notebook computers. Several multilayer ceramic capacitors of 1 to 47µF are generally used for decoupling capacitor C1 used for the input side. Several electrolytic capacitors or multilayer ceramic capacitors of ten to some hundreds of microfarad are used for smoothing capacitor C2 on the output side. In the power circuit that outputs a heavy current, multiple highcapacitance capacitors are connected in parallel to reduce a ripple voltage or the heat generation of a capacitor and improve the stability of load fluctuations. Three polymer type aluminum electrolytic capacitors of 470µF and 4V that were used for C2 were replaced by three multilayer ceramic capacitors of 100µF and 6.3V. Fig.11 shows the output ripple waveform when an output voltage is 1.35V and when a load current is 20A. The ripple voltage in the polymer type aluminum electrolytic capacitor is 36 mVp-p, and the ripple voltage in the multilayer ceramic capacitor is 26 mVp-p. Even in this case, by using the multilayer ceramic capacitor, a ripple voltage reduction effect equal to or of more than electrolytic capacitors can be obtained at an electrostatic capacity value of approximately 1/5. Summary As introduced above, the same performance can be obtained at an electrostatic capacity value of 1/2 to 1/3 as compared with the conventional electrolytic capacitor used when a multilayer ceramic capacitor is employed as the decoupling capacitor or smoothing capacitor of a power circuit. The multilayer ceramic capacitor is lower in ESR or ESL value than other capacitors because of its structure and has the performance similar to a more ideal capacitor. Therefore, the multilayer ceramic capacitor is widely used in electronic equipment such as the power circuit or high-frequency circuit introduced this time as well as general electronic equipment. In future, Murata Manufacturing Co., Ltd. will step up efforts in expanding capacitance value and in developing more compact multilayer ceramic capacitors. About This Article: The author,Yukio Honda, is the Associate Manager of the Technical Administration Department at the Component Division I of Fukui Murata Manufacturing Co., Ltd. Fig. 10: Block diagram of PWM DC-DC down-converter Fig. 11: Comparison of output ripple waveforms in polymer type aluminum electrolytic capacitor and multilayer ceramic capacitor 52 AEI October 2004 Copyright ? 2005 Dempa Publications, Inc. In a multilayer ceramic capacitor, a capacitance of more than 100µF can be acquired through combined use of the thin-layer technology in which the thickness of a dielectric layer approaches 1um, and the multilayer technology wherein hundreds to 1,000 layers are exceeded. As a result, a compact and high-capacitance multilayer ceramic capacitor has also been used for a decoupling capacitor, for which an electrolytic capacitor has been mainly used until now, or power smoothing capacitor. More effective decoupling performance or power smoothing characteristics is anticipated based on the excellent frequency characteristics of a multilayer ceramic capacitor. The application will be promoted more and more in the future. Acquired Capacitance Range Fig.1 shows various capacitors mainly used for general electronic equipment according to the relation between the acquired capacitance value and rated voltage. In a capacitance range of less than 1µF, a type 1 (temperature compensating) ceramic capacitor, a type 2 (high dielectric constant) ceramic capacitor, and a film capacitor are put into use. An aluminum electrolytic capacitor or tantalum electrolytic capacitor has been mainly used in the high-capacitance range exceeding 1µF. In recent years, with the progress of the high-capacitance technology in a multilayer ceramic capacitor, the capacitance value per volume has been rapidly expanded (Fig.2), and a capacitance range of more than 100µF can be acquired even in a multilayer ceramic capacitor. Fig.3 shows the relation between the acquired capacitance value and rated voltage of a high-capacitance multilayer ceramic capacitor exceeding 1µF for each chip size. The relation between each chip size and the maximum acquired capacitance value indicates that a capacitance value of up to 1µF can be acquired in 1005 size, that of up to 10µF can be acquired in 1608 size, and that of up to 100µF can be acquired in 3225 size. Moreover, the rated voltage is lined up so that it is provided up to DC 100V and widely used for various applications. Judging from the 48 AEI October 2004 High-Capacitance Multilayer Capacitor Delivers Better Performance Fig. 1: Relation between capacitance value and rated voltage in each capacitor Fig. 2: Transition of capacitance value per volume and dielectric thickness Fig. 3: Range of capacitance value and rated voltage in each size Copyright ? 2005 Dempa Publications, Inc. relation of the chip size and the maximum acquired capacitance value, the development of a compact and high-capacity multilayer ceramic capacitor will be promoted more and more in future by the progress of technology. Frequency Characteristics The structure of a multilayer ceramic capacitor is shown in Fig.4. In the capacitor, dielectric ceramics and electrodes are alternately accumulated for formation. A metal such as nickel is generally used for electrode materials. Therefore, the electrode resistance influencing the equivalent series resistance (ESR) value or loss of a capacitor is lower than for an electrolytic capacitor by a few digits. Fig.5 shows the comparison of the frequency impedance characteristics of a 10µF high-capacitance multilayer ceramic capacitor with those of an aluminum electrolytic capacitor and tantalum electrolytic capacitor. For the impedance characteristics of an ideal capacitor, the impedance decreases by one digit when a frequency increases by one digit. As shown in Fig.5, however, for the impedance characteristics of an aluminum electrolytic capacitor, the impedance value becomes constant at approximately 10? and does not decrease any longer when a frequency reaches a few kilohertz or more. In a tantalum electrolytic capacitor, the impedance value does not decrease when a frequency reaches some 10kHz or more. The impedance value becomes constant at some hundred milliohms. In a multilayer ceramic capacitor, an almost ideal impedance decrease is observed until a self-resonance frequency of approximately 1MHz is reached. The impedance value at that time is a few milliohms. When a frequency becomes higher, an impedance value increases due to the influence of an equivalent serial inductance (ESL) term. The value obtained when the impedance of each capacitor is lowest is equivalent to an ESR (equivalent serial resistance) value. The ESR value of a multilayer ceramic capacitor that uses a metal lower in a resistance value than for an electrolytic capacitor as the electrode of a capacitor is low. Fig.6 shows the relation between the current value and capacitor surface temperature occurring when a sine wave current with a frequency of 100kHz flows through each capacitor with a capacitance value of 100µF. For the multilayer ceramic capacitor whose ESR value is low, the heat generation caused by a heavy current is low and the increase in the surface temperature is less than for other capacitors. This indicates that the multilayer ceramic capacitor is suitable for a heavycurrent power smoothing capacitor. Application to Decoupling Capacitor In each circuit module or IC, a decoupling capacitor is set in the power circuit to secure the stabilized operation and function. The decoupling capacitor is used to remove or reduce the noise occurring via a power line or the noise generated by its own operation. In the past, a high-capacitance electrolytic capacitor and low-capacitance ceramic capacitor were frequently used in combination for a decoupling capacitor. However, in one decoupling capacitor, a high decoupling effect can be obtained over a wide-range frequency by using a Fig. 4: Structure of multilayer ceramic capacitor Fig. 5: Comparison of frequency and impedance characteristics in each capacitor Fig. 6: Comparison of high-frequency current and surface rising temperature in each capacitor 50 AEI October 2004 Copyright ? 2005 Dempa Publications, Inc. high-capacitance multilayer ceramic capacitor with excellent frequency impedance characteristics. As shown in Fig.7, the peak values of waveforms obtained on the output side are compared for each capacitor when a peak value of 2V pulse wave, a frequency of 100kHz, and 1MHz are supplied to the circuit shown in Fig.7. The effect of noise absorption is investigated in this case. In a pulse wave of 100kHz, the peak value when an aluminum electrolytic capacitor with a capacitance value of 220µF is used is 46 mVp-p. However, the peak value decreases to 28 mVp-p at a capacitance value of 1/4 (47µF) when a tantalum electrolytic capacitor is used. When a multilayer ceramic capacitor is used instead of the tantalum electrolytic capacitor, the peak value decreases to the almost the same level as for the tantalum electrolytic capacitor at a capacitance value of 1/10 (22µF). In other words, by using a multilayer ceramic capacitor, a pulse absorption effect equal to or of more than when using these electrolytic capacitors is obtained at the 1/10-capacitance value of an aluminum electrolytic capacitor or the 1/2- capacitance value of a tantalum electrolytic capacitor. Even in a pulse wave of 1MHz, similarly, pulse absorption characteristics equal to or of more than these electrolytic capacitors can be obtained using a multilayer ceramic capacitor with the capacitance value that is 1/50 of an aluminum electrolytic capacitor and 1/10 of a tantalum electrolytic capacitor. Fig.8 shows the block diagram of a 40W output class D power amplifier circuit. Amultilayer ceramic decoupling capacitor of 10µF is used for decoupling capacitors C1 and C2 at the Vcc pin of IC. Two aluminum electrolytic capacitors are connected in parallel to decoupling capacitors C3 and C4 in the power input block on the board. The power ripple voltage waveforms when a multilayer ceramic capacitor is used instead of aluminum electrolytic capacitors C3 and C4 are shown in Fig.9. A ripple voltage of 88 mVp-p in an aluminum electrolytic capacitor becomes 71 mVp-p when two multilayer ceramic capacitors of 10µF are used instead. By using the multilayer ceramic capacitors, a ripple reduction effect equal to or of more than when using aluminum electrolytic capacitor can be obtained even at a capacitance value of 1/10. 51 AEI October 2004 Fig. 7: Comparison of noise absorption characteristic in each capacitor Fig. 8: Block diagram of class D power amplifier circuit Fig. 9: Comparison of power ripple voltage waveforms in aluminum electrolytic capacitor and multilayer ceramic capacitor Copyright ? 2005 Dempa Publications, Inc. Application to Smoothing Capacitor for DC/DC Converter Fig.10 shows the block diagram of the PWM DC/DC down-converter used for notebook computers. Several multilayer ceramic capacitors of 1 to 47µF are generally used for decoupling capacitor C1 used for the input side. Several electrolytic capacitors or multilayer ceramic capacitors of ten to some hundreds of microfarad are used for smoothing capacitor C2 on the output side. In the power circuit that outputs a heavy current, multiple highcapacitance capacitors are connected in parallel to reduce a ripple voltage or the heat generation of a capacitor and improve the stability of load fluctuations. Three polymer type aluminum electrolytic capacitors of 470µF and 4V that were used for C2 were replaced by three multilayer ceramic capacitors of 100µF and 6.3V. Fig.11 shows the output ripple waveform when an output voltage is 1.35V and when a load current is 20A. The ripple voltage in the polymer type aluminum electrolytic capacitor is 36 mVp-p, and the ripple voltage in the multilayer ceramic capacitor is 26 mVp-p. Even in this case, by using the multilayer ceramic capacitor, a ripple voltage reduction effect equal to or of more than electrolytic capacitors can be obtained at an electrostatic capacity value of approximately 1/5. Summary As introduced above, the same performance can be obtained at an electrostatic capacity value of 1/2 to 1/3 as compared with the conventional electrolytic capacitor used when a multilayer ceramic capacitor is employed as the decoupling capacitor or smoothing capacitor of a power circuit. The multilayer ceramic capacitor is lower in ESR or ESL value than other capacitors because of its structure and has the performance similar to a more ideal capacitor. Therefore, the multilayer ceramic capacitor is widely used in electronic equipment such as the power circuit or high-frequency circuit introduced this time as well as general electronic equipment. In future, Murata Manufacturing Co., Ltd. will step up efforts in expanding capacitance value and in developing more compact multilayer ceramic capacitors. About This Article: The author,Yukio Honda, is the Associate Manager of the Technical Administration Department at the Component Division I of Fukui Murata Manufacturing Co., Ltd. Fig. 10: Block diagram of PWM DC-DC down-converter Fig. 11: Comparison of output ripple waveforms in polymer type aluminum electrolytic capacitor and multilayer ceramic capacitor 52 AEI October 2004 Copyright ? 2005 Dempa Publications, Inc.

    28. 1.2.1 Capacitor winding technology In the conventional production process, the capacitors are made by individually rolling the metallized films or the film/foils into cylindrical rolls and then covering them with an insulating sleeve or coating. In the MKT, MKP and MFP type series, our production range includes capacitors with space-saving flat wound bodies with insulating coatings or in plastic cases, as well as cylindrical wound capacitors. Flat windings are produced by compressing the cylindrical rolls before they are placed in the casings, so that the casing form is optimally used. 1.2.1 Capacitor winding technology In the conventional production process, the capacitors are made by individually rolling the metallized films or the film/foils into cylindrical rolls and then covering them with an insulating sleeve or coating. In the MKT, MKP and MFP type series, our production range includes capacitors with space-saving flat wound bodies with insulating coatings or in plastic cases, as well as cylindrical wound capacitors. Flat windings are produced by compressing the cylindrical rolls before they are placed in the casings, so that the casing form is optimally used.

    29. 1.2.2 Stacked-film technology In stacked-film production technology, large rings of metallized film are wound onto core wheels (with diameters of up to 60 cm). In this way, the “master capacitors” are produced under well-defined and constant conditions. As a result, the capacitor production lots obtained when the rings are sawed apart to produce the actual stacked-film capacitor bodies are especially homogenous. The pulse handling capabilities of stacked-film capacitors are of particular advantage. Since each individual layer acts as a separate capacitor element, any damage to the contacts due to overloading is restricted to the respective capacitor element and does not affect the entire capacitor, as is the case for wound capacitors. 1.2.2 Stacked-film technology In stacked-film production technology, large rings of metallized film are wound onto core wheels (with diameters of up to 60 cm). In this way, the “master capacitors” are produced under well-defined and constant conditions. As a result, the capacitor production lots obtained when the rings are sawed apart to produce the actual stacked-film capacitor bodies are especially homogenous. The pulse handling capabilities of stacked-film capacitors are of particular advantage. Since each individual layer acts as a separate capacitor element, any damage to the contacts due to overloading is restricted to the respective capacitor element and does not affect the entire capacitor, as is the case for wound capacitors.

    32. Capacitors with metallized plastic film have a decisive advantage over capacitors with metal foil electrodes: they have self-healing properties. These self-healing properties permit utilization of the full dielectric strength of the dielectric materials of metallized film capacitors, whereas metal-foil electrode capacitors must always be designed with a safety margin to allow for any possible faults in the dielectric. Metallized types thus have a distinct size advantage, which is particularly apparent with the larger capacitance ratings. With metallized-film designs, it is also possible to implement even complicated capacitor arrangements, e.g. multiple internal series connection to cope with high dc voltages coupled with high ac load capabilities. The combination of metal foils, metallized and plain film used in MFP and MFT capacitors gives an extremely high current carrying capability together with self-healing properties. 1.2.5 Self-healing The metal coatings, which are vacuum-deposited directly onto the plastic film, have a thickness of only 20 … 50 nm. If the dielectric breakdown field strength is exceeded locally at weak points, at pores or impurities in the dielectric, a dielectric breakdown occurs. The energy released by the arc discharge in the breakdown channel is sufficient to totally evaporate the thin metal coating in the vicinity of the channel. The rapid expansion of the plasma in the breakdown channel causes it to cool after a few microseconds, thus quenching the discharge. The insulated region thus resulting around the former faulty area will cause the capacitor to regain its full operation ability. Since the absence of any form of pressure in the individual dielectric layers and a good homogeneity improves the self-healing properties, stacked-film capacitors have better self-healing properties than wound capacitors. Note: At low voltages, anodic oxidation of the metal coatings leads to an electrochemical self-healing process. Capacitors with metallized plastic film have a decisive advantage over capacitors with metal foil electrodes: they have self-healing properties. These self-healing properties permit utilization of the full dielectric strength of the dielectric materials of metallized film capacitors, whereas metal-foil electrode capacitors must always be designed with a safety margin to allow for any possible faults in the dielectric. Metallized types thus have a distinct size advantage, which is particularly apparent with the larger capacitance ratings. With metallized-film designs, it is also possible to implement even complicated capacitor arrangements, e.g. multiple internal series connection to cope with high dc voltages coupled with high ac load capabilities. The combination of metal foils, metallized and plain film used in MFP and MFT capacitors gives an extremely high current carrying capability together with self-healing properties. 1.2.5 Self-healing The metal coatings, which are vacuum-deposited directly onto the plastic film, have a thickness of only 20 … 50 nm. If the dielectric breakdown field strength is exceeded locally at weak points, at pores or impurities in the dielectric, a dielectric breakdown occurs. The energy released by the arc discharge in the breakdown channel is sufficient to totally evaporate the thin metal coating in the vicinity of the channel. The rapid expansion of the plasma in the breakdown channel causes it to cool after a few microseconds, thus quenching the discharge. The insulated region thus resulting around the former faulty area will cause the capacitor to regain its full operation ability. Since the absence of any form of pressure in the individual dielectric layers and a good homogeneity improves the self-healing properties, stacked-film capacitors have better self-healing properties than wound capacitors. Note: At low voltages, anodic oxidation of the metal coatings leads to an electrochemical self-healing process.

    38. The ability of a capacitor to withstand a continuous (sine-wave) alternating voltage load Vrms or alternating current Irms is a function of the frequency and is limited by three different factors (refer to figure 13): Region : Limit at which corona discharges start to occur, VCD: Below a certain frequency limit f1 the applied ac voltage Vrms should not exceed the threshold voltage VCD at which corona discharges (partial discharges) would start to occur with some intensity in air pockets in the capacitor and thus eventually endanger its dielectric strength. The following relation must be taken into consideration: Vrms = VCD i.e. Irms = VCD 2? f C This voltage limit is determined, above all, by the internal construction of the capacitors (which determines the field strength at the edges); it also depends, to a lesser extent, on the thickness of the dielectric. This voltage limit can be raised, in particular, by using internal series connection designs. Region : Limit due to thermal power dissipation: Above the frequency limit f1 the permissible alternating voltage load must be reduced with increasing frequency in order to keep the power dissipation PE resulting in the capacitor body: PE = Vrms 2 2? f C tan d below the power PA which can be dissipated in the form of thermal energy by the surface area A of the capacitor: PA = a A T where: a = heat transfer coefficient. In order to prevent permanent damage to the capacitor, the steady-state overtemperature T attained at the hottest part of the capacitor surface in relation to the surrounding atmosphere must not exceed a certain value. By equating the power generated and the power that can be dissipated as thermal energy: PE = PA the conditions for the maximum permissible alternating voltages and alternating currents in this region can be deduced as: This can be simplified by the following close approximation: The frequency limit f1 is the maximum frequency at which the full permissible ac voltage Vac may be applied to the capacitor without the maximum permissible power dissipation being exceeded.The ability of a capacitor to withstand a continuous (sine-wave) alternating voltage load Vrms or alternating current Irms is a function of the frequency and is limited by three different factors (refer to figure 13): Region : Limit at which corona discharges start to occur, VCD: Below a certain frequency limit f1 the applied ac voltage Vrms should not exceed the threshold voltage VCD at which corona discharges (partial discharges) would start to occur with some intensity in air pockets in the capacitor and thus eventually endanger its dielectric strength. The following relation must be taken into consideration: Vrms = VCD i.e. Irms = VCD 2? f C This voltage limit is determined, above all, by the internal construction of the capacitors (which determines the field strength at the edges); it also depends, to a lesser extent, on the thickness of the dielectric. This voltage limit can be raised, in particular, by using internal series connection designs. Region : Limit due to thermal power dissipation: Above the frequency limit f1 the permissible alternating voltage load must be reduced with increasing frequency in order to keep the power dissipation PE resulting in the capacitor body: PE = Vrms 2 2? f C tan d below the power PA which can be dissipated in the form of thermal energy by the surface area A of the capacitor: PA = a A T where: a = heat transfer coefficient. In order to prevent permanent damage to the capacitor, the steady-state overtemperature T attained at the hottest part of the capacitor surface in relation to the surrounding atmosphere must not exceed a certain value. By equating the power generated and the power that can be dissipated as thermal energy: PE = PA the conditions for the maximum permissible alternating voltages and alternating currents in this region can be deduced as: This can be simplified by the following close approximation: The frequency limit f1 is the maximum frequency at which the full permissible ac voltage Vac may be applied to the capacitor without the maximum permissible power dissipation being exceeded.

    54. High voltage power capacitors KLV Advanced technology of KLV capacitors is based on construction of ALL-FILM capacitor sections, improved electrical and mechanical connections between sections and impregnation with environmentally compatible insulating oil. Application KLV capacitors are designed for reactive power compensation of electrical networks and industrial plants. When required voltages are higher then rated voltage of individual capacitor, units are integrated into banks by means of series connection. Fusing is provided according to national requirements. Owing to high partial discharge inception voltage, KLV capacitors are suitable for installation in networks with higher harmonics and transient voltages. Low temperature-dependent capacitance change makes them particularly suitable for filter circuit installations. Element fuses can extend the service life of a power capacitors and thus avoid interruptions of operation. However, the fuse mechanism is only intact as long as there is a sufficient number of elements connected in parallel - when the capacitors grow older, eventually the point of time will come at which the fuses of the remaining elements will no longer melt. For this reason is recommended to measure capacitance every one or two years. Besides, each capacitor bank should be monitored by means of an unbalance protection device or a phase comparison protection device. External fuses can also be used when internal fuses can not be used due to higher rated voltage or smaller rated output of capacitor. Pressure switch with terminal cap (on demand): Used for protection of capacitor units and banks, without unbalance protection. In case of a capacitor failure increased pressure may occur inside the container which finally might High voltage power capacitors KLV Advanced technology of KLV capacitors is based on construction of ALL-FILM capacitor sections, improved electrical and mechanical connections between sections and impregnation with environmentally compatible insulating oil. Application KLV capacitors are designed for reactive power compensation of electrical networks and industrial plants. When required voltages are higher then rated voltage of individual capacitor, units are integrated into banks by means of series connection. Fusing is provided according to national requirements. Owing to high partial discharge inception voltage, KLV capacitors are suitable for installation in networks with higher harmonics and transient voltages. Low temperature-dependent capacitance change makes them particularly suitable for filter circuit installations. Element fuses can extend the service life of a power capacitors and thus avoid interruptions of operation. However, the fuse mechanism is only intact as long as there is a sufficient number of elements connected in parallel - when the capacitors grow older, eventually the point of time will come at which the fuses of the remaining elements will no longer melt. For this reason is recommended to measure capacitance every one or two years. Besides, each capacitor bank should be monitored by means of an unbalance protection device or a phase comparison protection device. External fuses can also be used when internal fuses can not be used due to higher rated voltage or smaller rated output of capacitor. Pressure switch with terminal cap (on demand): Used for protection of capacitor units and banks, without unbalance protection. In case of a capacitor failure increased pressure may occur inside the container which finally might

    58. Carbon nanotubes and polymers, or carbon aerogels, are practical for supercapacitors. Carbon nanotubes have excellent nanoporosity properties, allowing tiny spaces for the polymer to sit in the tube and act as a dielectric. Polymers have a redox (reduction-oxidation) storage mechanism along with a high surface area. MIT's Laboratory of Electromagnetic and Electronic Systems (LEES) is researching using carbon nanotubes[1]. Supercapacitors are also being made of carbon aerogel. Carbon aerogel is a unique material providing extremely high surface area of about 400-1000 m2/g. Small aerogel supercapacitors are being used as backup batteries in microelectronics, but applications for electric vehicles are expected[2]. The electrodes of aerogel supercapacitors are usually made of non-woven paper made from carbon fibers and coated with organic aerogel, which then undergoes pyrolysis. The paper is a composite material where the carbon fibers provide structural integrity and the aerogel provides the required large surface. The capacitance of a single cell of an ultracapacitor can be as high as 2.6 kF (see photo at the beginning).Carbon nanotubes and polymers, or carbon aerogels, are practical for supercapacitors. Carbon nanotubes have excellent nanoporosity properties, allowing tiny spaces for the polymer to sit in the tube and act as a dielectric. Polymers have a redox (reduction-oxidation) storage mechanism along with a high surface area. MIT's Laboratory of Electromagnetic and Electronic Systems (LEES) is researching using carbon nanotubes[1]. Supercapacitors are also being made of carbon aerogel. Carbon aerogel is a unique material providing extremely high surface area of about 400-1000 m2/g. Small aerogel supercapacitors are being used as backup batteries in microelectronics, but applications for electric vehicles are expected[2]. The electrodes of aerogel supercapacitors are usually made of non-woven paper made from carbon fibers and coated with organic aerogel, which then undergoes pyrolysis. The paper is a composite material where the carbon fibers provide structural integrity and the aerogel provides the required large surface. The capacitance of a single cell of an ultracapacitor can be as high as 2.6 kF (see photo at the beginning).

    59. Nano World: Carbon Nanotube Capacitors File photo of carbon nanotubesby Charles Q. Choi New York (UPI) Feb 03, 2006 Carbon nanotubes could help release and hold electrical energy, for potential use in everything from microchips to hybrid cars, experts told UPI's Nano World. The nanotube devices are known as capacitors. While a battery stores compounds known as electrochemicals, a capacitor is made of a pair of electrodes separated by an insulator that each stores an opposite charge. Batteries release energy by reacting electrochemicals together, while capacitors do so when they are hooked into circuits. While capacitors might not be capable of storing as much energy as batteries of the same size, they could be much better at delivering more energy over a short time, explained researcher Gehan Amaratunga, an electronic engineer at Cambridge University in Britain. Amaratunga and his colleagues have developed nanoscale capacitors made from multi-walled carbon tubes roughly 70 nanometers or billionths of a meter wide. These nanotubes were grown vertically from nickel catalyst dots on niobium films. The scientists went on to cover this nanotube forest and its niobium floor with a silicon-nitride layer and then an aluminum film. The resulting capacitor is made from niobium and aluminum electrodes separated by an insulating silicon-nitride layer and carbon nanotubes. The nanotubes dramatically boost the amount of surface, and thus electrical charge, that each metal electrode can possess. The potential for smaller and more powerful capacitors might prove crucial in developing microchips with ever denser circuitry, Amaratunga said, which need high power "in the minimum area possible." Developing the kind of nanoscale capacitors needed for such ultra-dense circuitry has until now proven very complicated or unreliable. Moreover, such nanoscale capacitors might help improve the development of compact and cost effective supercapacitors, which has direct bearing on "electric or hybrid electric vehicles such as the Toyota Prius," Amaratunga said. These supercapacitors could help reduce the amount of battery weight these vehicles carry, thus improving their fuel consumption or performance or both, he explained. The researchers are currently pursuing supercapacitors for portable electronics "such as PDAs, where the optimization of battery weight and lifetime remains a significant issue," Amaratunga added. He and his colleagues published their findings in the journal Applied Physics Letters. The nanoscale capacitors might also serve in advanced memory chips, said Manish Chhowalla, a materials scientist at Rutgers University in Piscataway, N.J., who did not participate in this study. He noted that nanocapacitor conductance was high when they stored charge and low when they did not, which could serve as the equivalent of zeroes and ones "that are the basis of any memory device." The advantage nanotube capacitors might have over competing memory storage methods is the fact that they take up most of their space vertically, allowing more of them to be packed together onto a surface. In the future, Amaratunga hopes to move away from electron beam lithography, their current method of placing the nickel catalyst dots on the niobium films, to other techniques more viable for larger surfaces. He anticipated it would take six to eight years before their nanoscale capacitors are use in products. Their work is sponsored by Samsung, who "will guide the commercialization of the research," Amaratunga said. Nano World: Carbon Nanotube Capacitors File photo of carbon nanotubesby Charles Q. ChoiNew York (UPI) Feb 03, 2006Carbon nanotubes could help release and hold electrical energy, for potential use in everything from microchips to hybrid cars, experts told UPI's Nano World. The nanotube devices are known as capacitors. While a battery stores compounds known as electrochemicals, a capacitor is made of a pair of electrodes separated by an insulator that each stores an opposite charge. Batteries release energy by reacting electrochemicals together, while capacitors do so when they are hooked into circuits. While capacitors might not be capable of storing as much energy as batteries of the same size, they could be much better at delivering more energy over a short time, explained researcher Gehan Amaratunga, an electronic engineer at Cambridge University in Britain. Amaratunga and his colleagues have developed nanoscale capacitors made from multi-walled carbon tubes roughly 70 nanometers or billionths of a meter wide. These nanotubes were grown vertically from nickel catalyst dots on niobium films. The scientists went on to cover this nanotube forest and its niobium floor with a silicon-nitride layer and then an aluminum film. The resulting capacitor is made from niobium and aluminum electrodes separated by an insulating silicon-nitride layer and carbon nanotubes. The nanotubes dramatically boost the amount of surface, and thus electrical charge, that each metal electrode can possess. The potential for smaller and more powerful capacitors might prove crucial in developing microchips with ever denser circuitry, Amaratunga said, which need high power "in the minimum area possible." Developing the kind of nanoscale capacitors needed for such ultra-dense circuitry has until now proven very complicated or unreliable. Moreover, such nanoscale capacitors might help improve the development of compact and cost effective supercapacitors, which has direct bearing on "electric or hybrid electric vehicles such as the Toyota Prius," Amaratunga said. These supercapacitors could help reduce the amount of battery weight these vehicles carry, thus improving their fuel consumption or performance or both, he explained. The researchers are currently pursuing supercapacitors for portable electronics "such as PDAs, where the optimization of battery weight and lifetime remains a significant issue," Amaratunga added. He and his colleagues published their findings in the journal Applied Physics Letters. The nanoscale capacitors might also serve in advanced memory chips, said Manish Chhowalla, a materials scientist at Rutgers University in Piscataway, N.J., who did not participate in this study. He noted that nanocapacitor conductance was high when they stored charge and low when they did not, which could serve as the equivalent of zeroes and ones "that are the basis of any memory device." The advantage nanotube capacitors might have over competing memory storage methods is the fact that they take up most of their space vertically, allowing more of them to be packed together onto a surface. In the future, Amaratunga hopes to move away from electron beam lithography, their current method of placing the nickel catalyst dots on the niobium films, to other techniques more viable for larger surfaces. He anticipated it would take six to eight years before their nanoscale capacitors are use in products. Their work is sponsored by Samsung, who "will guide the commercialization of the research," Amaratunga said.

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