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(ii)

(i) symmetric contacts (NOE) with Me-18,19. Chiral Solvation of BNDHP by Cholate Micelles. (i) A hydrophobic pocket is formed by facial methyl groups of an antiparallel dimeric unit of cholate, and Me-21 lies in the hydrophobic plane. Me 19. Me 18. Me 21. H5. H6. H4. H7. H3.

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(ii)

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  1. (i) symmetric contacts (NOE) with Me-18,19 Chiral Solvation of BNDHP by Cholate Micelles (i) A hydrophobic pocket is formed by facial methyl groups of an antiparallel dimeric unit of cholate, and Me-21 lies in the hydrophobic plane Me19 Me18 Me21 H5 H6 H4 H7 H3 (ii) Enantiomers of BNDHP are preferentially solubilized against opposite edge of an antiparallel dimeric unit H8 Me19 Me21 Me18 H4 H5 H3 H6,H8 H7 {Chol}Me18 Me19 Me18 H3 {Chol}Me19 H7 H8 H4 {Chol}Me21 H7 Me21 H5 H6 Cholate R-BNDHP (ii) inverted contacts (NOE) for edge groups (ii) H12 H4 H5 H3 H6,H8 H7 H7 {Chol}H7 {Chol}H12 H7 S-BNDHP R-BNDHP H12

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