Ruthenium-Catalyzed Decarboxylative Allylation of Nonstabilized Ketone Enolates - PowerPoint PPT Presentation

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Ruthenium-Catalyzed Decarboxylative Allylation of Nonstabilized Ketone Enolates

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  1. Ruthenium-Catalyzed DecarboxylativeAllylation of Nonstabilized KetoneEnolates

  2. General procedure for catalyst preparation • In a Schlenk tube underargon, [Cp*RuCl]4 (2.5 mol %) and bipyridine (10 mol %) were dissolved in 2 mL of methylene chloride. The resulting deep purple solution was allowed to stir briefly.

  3. (C10H8N2)3RuCl2•6H2O $158.00 2G USD $54.6 1G USD $165.5 5G USD Dichloro(p-cymene)ruthenium(II) dimer