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Date: 2016-1-2

Date: 2016-1-2. Background. C1 Source CO, COCl 2 , HCHO CO 2 H igh abundance Low price Low toxicity. formic acid Acid Reductant Carbon source. Previous Work. Starting Point. R. Langer, G. Leitus, Y. Ben-David, D. Milstein, Angew. Chem. Int. Ed. 2011, 50, 2120–2124.

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Date: 2016-1-2

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  1. Date: 2016-1-2

  2. Background C1 Source CO, COCl2, HCHO CO2 • High abundance • Low price • Low toxicity formic acid • Acid • Reductant • Carbon source

  3. Previous Work

  4. Starting Point R. Langer, G. Leitus, Y. Ben-David, D. Milstein, Angew. Chem. Int. Ed. 2011, 50, 2120–2124. Y.-Y. Ohnishi, T. Matsunaga, Y. Nakao, H. Sato, S. Sakaki, J. Am.Chem. Soc. 2005, 127, 4021– 4032.

  5. Starting Point unstable

  6. Synthesis of 4

  7. Properties of 4

  8. Properties of 4

  9. Properties of 4 Comparison of others

  10. Mechanism

  11. Mechanism

  12. Outlook Features • Low price • Mildness • Good catalytic properties

  13. The End Thank You!

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