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Learn how to name binary molecular compounds, diatomic elements, and acids with detailed rules and examples. Master the prefixes, suffixes, and formulas with ease using this comprehensive guide.
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Naming Molecular Compounds & Acids
Molecules • Molecule – two or more atoms covalently bound together • Diatomic molecule – two of the same atom bound together
Diatomic Elements • H, N, O, F, Cl, Br, I or the Magnificent 7 • Have No Fear Of Ice Cold Beverages • These elements exist as diatomic molecules in their most stable state. • For example: • Br Br2 • I I2 • N N2 • Cl Cl2 • H H2 • O O2 • F F2
Binary Molecular Compounds • Binary covalent compounds contain 2nonmetals • No Polyatomic Ions!!!!! • No Charges!!!!
Naming Binary Covalent Compounds • Before you can name binary covalent compounds, you MUST know the prefixes! • 1 • 2 • 3 • 4 • 5 • 6 • 7 • 8 • 9 • 10 • Mono • Di • Tri • Tetra • Penta • Hexa • Hepta • Octa • Nona • Deca
Rules for naming Binary Covalent Compoundsex. N2F4 • Name the prefix for the number of atoms of the first element (ex. Di-) • Then name the first element (ex. Dinitrogen) • Name the prefix for the number of atoms of the second element (ex. Dinitrogen tetra-) • Than name the root of the second element with the ending –ide (ex. Dinitrogen tetrafluoride)
Note… • If the 1st prefix is mono….DROP IT! • Ex. CO is carbon monoxide NOT monocarbon monoxide • When the prefix ends in an o or a, and the name of the element begins with a vowel, the o or a is often dropped • EX. CO4 would be carbon tetroxide NOT carbon tetraoxide
Examples • What is the name of N2O4? • N2 di nitrogen • O4 tetra oxide • Since oxide begins with a vowel, we will • drop the a in tetra • Dinitrogen tetroxide
More examples • Name SO2 • S mono sulfur • But mono is with the 1st element, so it will be dropped sulfur • O2 dioxide • Sulfur dioxide
More examples • Write the formula for dichlorine monoxide • Dichlorine Cl2 • Monoxide O • Cl2O
More examples • Write the formula for disulfur dichloride • Disulfur S2 • Dichloride Cl2 • S2Cl2
Acids • Acids can be recognized because the start with H • Examples • HCl • H2SO4 • HI
Acids • Acids are in aqueous solution (aq) • For the purposes of this class, we will assume that if it begins with H, we will name it according to the rules of naming acids
Rule #1 - naming acids • If the anion ends in –ide, the acid will be named… • Hydro (root) – ic acid • Examples • HCl • Hydrochloric acid • HI • Hydroiodic acid • H2S • Hydrosulfuric acid
Rule #2 – naming acids • If you have an H plus an anion ending in –ate, the acid will be named… • (root) – ic acid • Examples • H2SO4 • Sulfuric acid • HNO3 • Nitric acid • H3PO4 • Phosphoric acid
Rule # 3 – naming acids • If you have an H plus an anion ending in –ite, the acid will be named… • (root) – ous acid • Examples • H2SO3 • Sulfurous acid • HNO2 • Nitrous acid • H3PO3 • Phosphorous acid
Writing formulas for acids • When writing formulas for acids you MUST look at the charges of the anion and add as many hydrogens as needed to cancel out the negative charge (because hydrogen is +1) • Example: Phosphoric acid • Phosphate = PO4-3 • So, phosphoric acid = H3PO4
Remember… ate ic ite - ous
H2SO3 H2CO3 HF Nitrous acid Perchloric acid Iodic acid Sulfurous acid Carbonic acid Hydrofluoric acid HNO2 HClO4 HIO3 More examples
Rules for Writing Formulas • Three sets of rules, ionic, covalent, and acids • To decide which to use, decide what the first substance is. • If is a metal or polyatomic ion use ionic. • If it is a non-metal use covalent. • If it is hydrogen, use acid rules
Hydrates • Some compounds trap water crystals when they form. • These are hydrates. • Both the name and the formula needs to indicate how many water molecules are trapped. • In the name we add the word hydrate with a prefix that tells us how many water molecules.
Hydrates • In the formula you put a dot and then write the number of molecules. • Calcium chloride dihydrate = CaCl2·2H2O • Chromium (III) nitrate hexahydrate = Cr(NO3)3· 6H2O
KClO2 CO2 H2SO4 NH4Br CuCO3 Fe2O3 HClO Potassium chlorite Carbon dioxide Sulfuric acid Ammonium bromide Copper (II) carbonate Iron (III) oxide Hypochlorous acid Mixed examples(remember to figure out what type of compound it is 1st!)
Carbon tetrachloride Phosphorous pentachloride Aluminum oxide Copper (II) nitrate Chlorous acid Hydrophosphoric acid Iron (III) hydroxide CCl4 PCl5 Al2O3 Cu(NO3)2 HClO2 H3P Fe(OH)3 More Mixed Examples