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The Chemical Basis of Life. Biology. All living organisms are made up of matter ( anything that takes up space & has mass ) Matter is composed of elements (the basic substance or chemical that cannot be broken down)

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chemical composition of living organisms

All living organisms are made up of matter (anything that takes up space & has mass)

Matteris composed of elements (the basic substance or chemical that cannot be broken down)

There are about 25 essential elements necessary for life; 4 make up 96% of the human body (in this order): O, C, H, & N

Most of the other 4%: Ca, P, K, S, Na, Cl, & Mg

Trace elementsare found in small quantities

chemical composition of living organisms
trace elements compounds

Look at your food labels. Most contain trace elements (ie. Fe, I, Cr, Co). Water is treated with F & I.

  • We need trace elements in our bodies. For example, Iodine (I) for the thyroid; Iron (Fe) for blood/O2 transport; Flourine (F) for prevention of tooth decay
  • Compoundsare substances of 2 or more different elements; ie. NaCl.
    • Pure Na is an explosive metal; pure Cl (chlorine) is a poisonous gas but when together they form an edible solid compound!
Trace Elements & Compounds
atoms have particles

Atoms, meaning indivisible, are the smallest units of matter, contain particles:

1. Protons (p+) have a positive charge and are located within the nucleus (center) of the atom.The proton # always remains the same.

2. Neutrons (n) have a neutral or no charge and are also located within the nucleus of the atom.

  • Electrons(e-) have a negative charge and orbit the nucleus of the atom in a cloud.
    • They move in 3D, not just in a circle. They are separated by levels and the further away from the nucleus, the greater the energy they have.
    • These take place in chemical reactions (rxns).
Atoms have Particles
slide6

An Atom:

http://www.csmate.colostate.edu/cltw/cohortpages/viney/atom.jpg

atoms have particles cont d

Elements have a unique # of p+; this is the atomic number. Ex.) Helium (He) has the atomic # of 2 and has 2 p+; C has 6 p+ and the atomic # of 6.

  • Generally, the proton # = the electron #
  • Atomic massis the p+ + the n or the sum of the nucleus. Ex.) He = 4; C = 12 (b/c the mass of the p+ = the mass of n)
  • When some atoms of the same element have different mass numbers, their n # is different. These are isotopes. The p+ and e- are the same! Ex.) C-12, C-13, and C-14 (written 12C, 13C, and 14C).
  • 14C is aradioactive isotope; this means the nucleus spontaneously decays (emitting radioactivity). This is used to date fossils.
Atoms have Particles, Cont’d
ionic bonds

Na has 1 e- in its outermost shell; Cl has 7 e- in its outermost shell. Cl is anxious to gain 1 e- to fill the octet rule while Na is more than willing to give up that 1 e- to satisfy that rule.

Ionic bondsform as the result of e- transfer; 1 element gives/donates an e- while the other element receives/accepts the e-. In this case, Na donates, Cl receives.

These bonds result in atoms (or molecules) w/ electrical charges and are a.k.a.ions.

The compounds that formed are saltswhich exist as crystals in nature and readily dissolve in water.

Ionic Bonds

http://www.findhealer.com/glossary/images/salt.gif

slide9

Ionic Bond between Na and Cl, forming NaCl:

http://chem.sci.utsunomiya-u.ac.jp/v9n2/MOzden/image/Figure7.jpg

covalent bonds

Covalent Bondsare strong bonds that share e-; these formmolecules.

  • These can be single (1 e- pair shared), double (2 e- pairs are shared, or 2 e-) or triple (3 e- pairs are shared, or 6 e-).
  • Some covalent bonds share e- equally; this is a nonpolar covalent bond. Ex.) H2, O2, CH4
Covalent Bonds

http://upload.wikimedia.org/wikibooks/en/c/c2/Covalent_bond_h.png

http://www.dlt.ncssm.edu/TIGER/Flash/bonding/CovalentBonding-TN.gif

covalent bonds cont d

However, most covalent bonds do not share e- equally. These are polar covalent bonds. Ex.) H2O.

  • Polar covalent bonds will result in a molecule that has atoms in a tug-of-war for the e-; the more electronegative an atom is, the closer the e- will be to that atom.
  • Electronegativityis an atom’s pull, or attraction, for shared e- (that is, those e- in a covalent bond).
  • Note: for the scope of this course, O is the most electronegative atom (N & F are also electronegative)
  • Let’s look at H2O: O will pull the e- a little closer to itself, leaving the H’s slightly positive (the O will be slightly negative as a result). This means the e- will hang out more often with the O than the H’s.
  • B/C this molecule forms a polar covalent bond & each atom has a slight charge, this is apolar molecule. There is an unequal distribution of charges.
Covalent Bonds, Cont’d
slide12

Polar Bonds: Water & Chloroform

http://cache.eb.com/eb/image?id=96904&rendTypeId=4

http://www.makingthemodernworld.org.uk/learning_modules/chemistry/03.TU.02/illustrations/03.IL.14.01.gif

hydrogen bonds

Hydrogen bondsare weak bonds that are crucialto the 3D shape of large molecules (DNA & proteins).

  • Can be found in molecules that have polar covalent bonds. Ex.) H2O + H2O
  • Are the reason for the properties of H2O.
  • Form between a H of 1 molecule AND a N OR O of another molecule.
  • They form and break quickly.
Hydrogen Bonds
slide14

Oxygen

Water Molecules

Hydrogen

http://academic.brooklyn.cuny.edu/biology/bio4fv/page/image12.gif

the properties of water

The properties of water are made possible b/c of hydrogen bonds.

  • Water is a requirement of life & the properties of water make it essential to live.

The properties of water include:

  • Cohesion, Adhesion, Surface Tension, Temperature Moderation, Existing in 3 States Naturally, & Solvent of Life
  • Cohesion is the ability/tendency of molecules (in this case H2O molecules) to stick together (to other H2O molecules).
    • IF water evaporates (from the leaves), water will travel up from the roots to the leaves b/c of cohesion (water sticks to water). This will also carry dissolved nutrients that the plant needs for survival.
The Properties of Water

Cohesion:

http://www.u413.com/images/Wallpaper/00838_drops_1280x1024.jpg

slide16

Adhesion is the ability of one molecule to stick to something else; in this case H2O can stick to the veins or cell walls of the plant.

  • This is howcapillary actionoccurs (water travels against gravity or up the plant thru the veins b/c water sticks to the sides of the plant’s walls).

Adhesion & Capillary Action:

Through cohesion and adhesion, capillary action occurs.

http://www.waters.com/webassets/cms/category/media/other_images/primer_b_%20thinlayer.jpg

the properties of water cont d

Surface Tension is the difficulty of H2O to stretch or break; H2O has a high surface tension (difficult to break).

  • Water’s moderate temperature is due to the H Bonds. H2O can resist temp changes; this keeps the Earth’s temp within limits (to sustain life).
    • Due to the large volume of H2O on Earth’s surface, climate is regulated. Water stores heat (from the sun) during warm times and releases heat during cold times.
    • Heat is the amount of energy to move atoms and molecules.
    • Temperature is the measurement of heat (average speed of atoms and molecules, not the total amount ofheat).
    • Evaporative cooling is the process of heat escaping from the body in the form of sweat. As sweat evaporates from the skin, cooling results.
The Properties of Water, Cont’d
slide18

Surface Tension: Jesus Lizard walking on Water:

Can Cohesion, Adhesion, and Surface Tension occur independently? http://www.societyofrobots.com/images/robot_JB_lizard1.jpg

the properties of water cont d1

Water exists naturally in 3 states: as a solid, liquid and a gas (water vapor).

When water freezes, it is less dense than when it is in liquid form. Why? H Bonds!

The H Bonds stabilize & hold a crystalline pattern (at arms length). This allows ice to float on water (in the liquid state).

This is an important property b/c only the top layer of water (in a body of water) will freeze & it will not sink.

This allows life in the water environment to survive. Also, the ice insulates the water (like a blanket from the cold air).

The Properties of Water, Cont’d
slide20

Frozen Oceans:

http://ngm.nationalgeographic.com/2007/06/vanishing-sea-ice/img/vanishing-sea-ice.jpg

http://www.naturetrek.co.uk/pics/t146-large1.jpg

the properties of water cont d2

Water is the solvent of life; this means it can dissolve many substances (due to its polarity).

  • When water is a solvent (agent that dissolves) & forms a solution (a liquid with 2 or more substances mixed together), water is anaqueous solution.
  • The soluteis the dissolved substance (salt, sugar, etc).
  • This property is important to life b/c many substances (polar and/or ionic) must be transported in the body (an organism). Ex.) Blood’s main component is H2O and is contains dissolved ions, salts, gases, wastes, sugars, and proteins for transport.
The Properties of Water, Cont’d
acids and bases

The hydrogen ionis the H+and cannot exist alone.

  • The hydroxide ionis the OH-and can exist alone. 
  • The hydronium ionis the H3O+.

Why is this important to life?

  • Ions regulate pH.
  • The pH Scaleis a range of numbers that indicate the amount or concentration of H+ or OH- in a solution. It ranges from 0-14.
  • A neutral solutionis a solution that has an equal concentration of both ions. The pH is 7 (mid-range). Pure water is neutral.
  • An acidic solutionis a solution that has an increased concentration of H+. It has a low pH (below 7). More H+, less OH-, low pH.
  • A basic solutionis a solution that has an increased concentration of OH-. It has a high pH (greater than 7). Less H+, more OH-, high pH.
Acids and Bases
acids and bases cont d

Human Blood is ~ 7.3-7.4(a person cannot live below 7 or above 7.8).

Buffersare substances that stabilize pH.

Acids and Bases, Cont’d

http://www.epa.gov/acidrain/education/site_students/images/phscale.gif

chemical reactions

Chemical Reactions- making and breaking bonds.

__H2+ __ O2 __H2O

  • Reactants (starting materials)  Products (results)
  • Always balance equation! This means the # of atoms (H, O, etc) on the left side of the equation MUST equal the # of atoms (H, O, etc) on the right side of the equation.

Try this:

  • __C6H12O6 + __O2 __CO2 + __H2O
Chemical Reactions
chemical reactions cont d

__C6H12O6 + __O2 __CO2 + __H2O

  • C6H12O6 + 6 O2 6 CO2 + 6 H2O

6 C 6 C

12 H 12 H

18 O 18 O

Chemical Reactions, Cont’d