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www.bowhunting.net. EXPOSURE TO NATURALLY OCCURRING HAZARDOUS MINERALS DURING CONSTRUCTION ACTIVITY. ODOT GEO-HYDRO-HAZMAT CONFERENCE 2009. www.bowhunting.net. Clark Niewendorp Oregon Department of Geology and Mineral Industries. Organizations Sponsoring Research

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  1. www.bowhunting.net EXPOSURE TO NATURALLY OCCURRING HAZARDOUS MINERALS DURING CONSTRUCTION ACTIVITY ODOT GEO-HYDRO-HAZMAT CONFERENCE 2009 www.bowhunting.net Clark Niewendorp Oregon Department of Geology and Mineral Industries

  2. Organizations Sponsoring Research • Oregon Department of Transportation (ODOT) • Research Unit • 200 Hawthorne Ave. SE, Suite B-240 • Salem, OR 97301-5192 Phone: (503) 986-2700 • Federal Highway Administration (FHWA) • Washington, D.C. 20590 • Principal Investigator(s) • Clark Niewendorp • Oregon Department of Geology and Mineral Industries • 800 NE Oregon Street #28 • Portland, OR 97232 Phone: (971) 673-1540 • Technical Advisory Committee (TAC) Members • Bart Bretherton, ODOT • Michele Eraut, FHWA • Russell Frost, ODOT • Don Lewis, DOGAMI • Matthew Mabey, ODOT, Chair • Jeff Moore, ODOT • Richard Young, ODOT • Friends of the Committee • Jennie Armstrong, ODOT • David Brooks, ODOT • Kim Willoughby, WashDOT • Project Coordinator • Matthew Mabey, ODOT Research Unit • Project Champion • Paul Wirfs, ODOT This work is supported by the ODOT and FHWA Contract/Grant No. 686 and an Interagency Agreement with the ODOT and DOGAMI, No. 25296 ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  3. WHAT IS THIS PROJECT ABOUT… Determine where selected NOHM may intersect ODOT operations Assure that ODOT maintenance and construction activities take the presence of the selected NOHM into account Develop GIS datasets that inform ODOT personnel of the hazard characteristics of the selected NOHM ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  4. Approach - Project Deliverables: NOHM GIS Interpretive Layer & Final Report Catalog & Compile NOHM Database File(s) Sampling and Detecting Procedures: Development & Implementation Data Collection, Integration, and Processing to Tag NOHMs Methods of Detecting NOHMs List of NOHM Candidates ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  5. NOHM Selection Criteria… IARC (International Agency for Research on Cancer) classification Toxicity - undesirable health effects: 1) primary irritation 2) mutagenic (changes to genetic material) 3) reproductive (teratogenic) 4) tumorgenic 5) acute toxicity 6) other multiple dose toxicity ATSDR(Agency for Toxic substances and Disease Registry) ToxProfiles, 2007 MSDSMaterial Safety Data Sheet for certain minerals HAZ-MAP databaseThe United States National Laboratory of Medicine’s (National Institutes for Health) list of toxicants ScorecardThe Pollution Information Site (http://www.scorecard.org) ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  6. Selected NOHM… Class A • Asbestiform asbestos (includes talc with asbestiform component and asbestiform amphiboles) • Erionite • Arsenic • Mercury and its compounds • Antimony and its compounds • Chromium IV and its compounds (includes chromium III and its compounds) • Nickel and its compounds • Radionuclides (radon, radium, uranium) • Beryllium and its compounds • Cadmium • Lead and its compounds • Mineral fuels (including Bitumen) Class B • Cobalt and its compounds • Lithium and its compounds • Selenium and its compounds • Tin • Copper and zinc compounds ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  7. Sampling and Detecting Procedures: Development & Implementation Field truck and assay outfit used by the mining engineers of the Oregon Bureau of Mines and Geology, ca 1922 ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  8. Methods of Detection… Polarized Light Microscopy (PLM) Transmission Electron Microscopy (TEM) X-ray Diffraction (XRD) Scanning Electron Microscopy (SEM) Electron Microprobe (EPMA) Phase Contrast Microscopy (PCM) Imaging or Reflectance Spectroscopy Raman Spectroscopy Mossbauer Spectroscopy Inductively Coupled Plasma – Atomic Emission and Mass Spectroscopy Atomic Absorption Spectroscopy www.bahaiperspectives.com/wp-content/uploads/ ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  9. Data Collection… • Oregon Geologic Data Compilation – OGDC • Mineral Information Layer for Oregon – MILO • USGS Mineral Resources On-line Spatial Data • Geoanalytical Information Layer for Oregon – GILO • USGS Geochemical Landscape Datasets • Geothermal Information Layer for Oregon – GTILO • Soda Spring Database • Available Published & Unpublished Geologic Reports ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  10. OGDC – Statewide Geologic Compilation • Geologic Data is taken from • Published Federal and State Maps • Published and unpublished “gray literature” maps • Thesis and dissertation maps ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  11. OGDC – Derivatives Maps ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  12. GIS database that can be used to make derivative maps Tertiary Porphyry and Skarn Systems Baker City Record Mine ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  13. MILO – Mineral Information for Oregon Includes USGS Mineral Resources On-line Spatial Data n = 18,819 Aggregate Metals Industrial Minerals Coal Gemstones ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  14. GILO – Geoanalytical Information for Oregon Whole-rock Geochemistry & trace elements n = ?? ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  15. USGS Geochemical Landscape Datasets • NURE • water • sed • PLUTO • sed • Ig • soil • RASS • sed • soil • USGS • sed ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  16. GTILO – Geothermal Information Layer for Oregon Soda Spring Database Hot Springs n = 649 Soda Springs n = 36 ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  17. Compile & Catalog ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  18. OGDC & MILO ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  19. More toxic Less toxic Chrysotile (the dominant form used industrially in the US) Amosite Crocidolite Asbestiform Anthophyllite Asbestiform Tremolite/ Actinolite Asbestiform Erionite (a Zeolite) Six Federally Regulated Asbestiform Asbestos Minerals Serpentine (scrolled sheet silicate): Chrysotile:Mg3Si2O5(OH)4 Amphiboles (double chain silicate): Riebeckite asbestos (crocidolite):Na2(Fe2+3,Fe3+2)5Si8O22(OH)2 Grunerite asbestos (amosite): Fe2+7Si8O22(OH)2 Anthophyllite asbestos: Mg7Si8O22(OH)2 Tremolite asbestos: Ca2Mg5Si8O22(OH)2 Actinolite asbestos: Ca2(Mg,Fe2+)5Si8O22(OH)2 ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  20. NOHM Hazard Potential and Levels of Certainty Most commonly associated with serpentine or ultramafic rock May also occur in metamorphosed gabbro, basalt, carbonate rocks, or other metamorphic rocks May occur in faults or shear zones or at geologic boundaries ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  21. Asbestiform Asbestos ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  22. Erionite: The New Asbestos? • Sample formula: K2(NaCa0.5)[Al6Si30O72] · 28H2O • Found in vesicles (cavities) and veins of volcanic rocks such as basalts, rhyolites, and andesites • Forms as a devitrification product (the conversion of glass to crystalline material) of volcanic glass in tuffs Erionite sprays, Agate Beach, Lincoln Co., Oregon, USA. ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  23. Western Oregon Zeolites – Erionite? Near Buck Mountain, Lane County ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  24. Erionite’s type locality “The Amphitheater” near Durkee, Baker County The “Amphitheater” Modified after Prostka, 1967) ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  25. Rome Zeolite Deposits ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  26. Harney Lake Zeolites Zeolites were discovered in 1959 www.nps.gov ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  27. Metals: Au, Ag, As, Hg, Cu, Pb, Zn Drilling in 2003 by Malheur Mining Kerby: “Bonanza” Gold Feeder Mineralization ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  28. Hot Springs: Mercury and Uranium Association Harney Alvord Valley Malheur McDermitt Caldera ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  29. Detroit Lake Mineralization ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  30. Levels of Resource Potential: Catalog: NOHM Hazard Potential NOHM potential assignment criteria… ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  31. Catalog: Levels of Certainty Levels of Certainty: Based on Matrix ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  32. Project Deliverable… No Problem? ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  33. NOHM Hazard Potential and Levels of Certainty ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

  34. Clark Niewendorp Industrial Minerals Geologist Oregon Department of Geology and Mineral Industries 800 NE Oregon Street #28 Portland, OR 97232 Tele: 971.673.1540 Email: clark.niewendorp@dogami.state.or.us Mineral Evolution: Earth magazine ODOT Geo-Hydro-HazMat Technical Presentation, September, 2009 Clark Niewendorp

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