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Homogeneous liquid: Molar free energy: G 1,L Average composition: X 1 Phase fractions: f L = 1 PowerPoint Presentation
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Homogeneous liquid: Molar free energy: G 1,L Average composition: X 1 Phase fractions: f L = 1 - PowerPoint PPT Presentation


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B atoms. A atoms. Homogeneous liquid: Molar free energy: G 1,L Average composition: X 1 Phase fractions: f L = 1. Spontaneous. B atoms. A atoms. L. S. Two-phase system: solid and liquid: Molar free energy: G sep Average composition: X 1 Composition of solid phase: X S

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Presentation Transcript
slide1

B atoms

A atoms

Homogeneous liquid:

Molar free energy: G1,L

Average composition: X1

Phase fractions: fL = 1

Spontaneous

B atoms

A atoms

L

S

Two-phase system: solid and liquid:

Molar free energy: Gsep

Average composition: X1

Composition of solid phase: XS

Composition of liquid phase: XL

Phase fractions: fL = ?

fS = ?

S

slide8

T > Tm,B > Tm,A

T = Tm,B > Tm,A

Tm,B > T1 > Tm,A

Tm,B > T1 > T2 > Tm,A

Tm,B > T2 > T3 > Tm,A

Tm,B > T = Tm,A

slide12

G1,L

Gsep

GS

G

GL

Gsep,S

Gsep,S

XS

XL

X1

XB

slide13

GS

G

GL

C

B

A

XS

XL

X1

XB