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Comparative Electronic Spectroscopy of Co(III) Complexes in Different Geometries

Explore the electronic spectroscopy of Co(III) complexes with varying geometries, including octahedral, tetrahedral, and square planar. Compare band structures and absorption patterns of cis and trans isomers. Discuss the significance of different coordination geometries on the electronic spectra.

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Comparative Electronic Spectroscopy of Co(III) Complexes in Different Geometries

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  1. 600 PdCl42- 400 CoCl42- 200 Co(H2O)62+ (cm-1) 40000 30000 20000 10000 Espectroscopía electrónica: comparación de las diferentes geometrías (octaédrica, tetraédrica y cuadrado plana) 

  2. 60 cis-[Co(en)2F2] - 40 20 trans-[Co(en)2F2] - (cm-1) 28000 24000 20000 16000 En los complejos de Co(III) los isómeros trans presentan 3 bandas Espectroscopía electrónica: geometría octaédrica (cis- y trans-[Co(en)2F2] - 

  3. dx2-y2 PdCl42- 500 dxy dz2 dxz,dyz 300 Pd(H2O)42+ 100 (cm-1) 40000 30000 20000 10000 Espectroscopía electrónica: geometría cuadrado-plana

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