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Explore the evolution of knowledge on Hg and PCB loads, response times for sampling, data accuracy estimation, and watershed variability. Understand the importance of storm studies, particle concentrations, and sampling protocols.
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San Francisco Estuary Institute Item #4 Regional Data Review : What have we learned in eight years? Lester McKee Sources Pathways and Loadings Workgroup Monday December 8th 2008
Item #4 Evolution of knowledge - Hg loads(2000-2008):two loads studies make a large difference (Ref: McKee et al., 2008)
Item #4 Evolution of knowledge PCB loads(2002-2008 ):two loads studies make a large difference (Ref: McKee et al., 2008)
Zone 4 Line A (1.5 hrs) City Block (12 min) San Francisco Estuary Institute Item #4 How quick do people or instruments need to respond to collect samples? Guadalupe R. (8-10 hrs) (4 acres) (40 acres) (Ref: McKee et al., 2003)
Mercury Load = 0.025 – 1,075 kg Mercury Load = 6 – 440 kg Mercury Load = 80 – 220 kg San Francisco Estuary Institute Item #4 How many data do we need to estimate loads of a specified accuracy? (Ref: McKee et al., 2005)
San Francisco Estuary Institute Item #4 How many data do we need to estimate loads of a specified accuracy?
San Francisco Estuary Institute Item #4 How many data do we need to estimate loads of a specified accuracy?
San Francisco Estuary Institute Item #4 When within a year should we sample? Dry season Wet season Colma Ck. at S. San Francisco 57% urban, 41 km2 Coyote Ck. at Gilroy ??% urban, 275 km2 Alameda Ck. at Niles 10% urban, 1,650 km2 17% Water Discharge 1% Suspended Sediment Load
San Francisco Estuary Institute Item #4 Grain size and turbidity as a surrogate
San Francisco Estuary Institute Item #4 Is it better to measure or estimate concentrations and loads: the Guadalupe River example All loads in kg unless otherwise specified.
San Francisco Estuary Institute Item #4 How much do particle Hg concentrations vary between watersheds? • Z4LA < Coyote (non-urb) < Coyote (urb) < San Pedro < Guadalupe R.
San Francisco Estuary Institute Item #4 How much do particle PCB concentrations vary between watersheds? • Coyote (non-urb) < Coyote (urb) < Guadalupe R. < Z4LA
San Francisco Estuary Institute Item #4 How much do particle PBDE concentrations vary between watersheds? • Coyote (non-urb) < Guadalupe (non-urb) < Coyote (urb) < Guad (urb) < Z4LA
San Francisco Estuary Institute Item #4 Which storms need to be studied and does this vary for each POC? Z4LA WY 2007 data • If only storms of 10 cfs had been sampled for Hg, the estimated average particle concentration would be 1.7x higher than sampling 100 cfs • In contrast, the difference would be only 1.4x for PCBs • POC, method, and targeted storms matter
San Francisco Estuary Institute Item #4 Which and how many watersheds should be sampled? Export of POC during climatic years with 70% mean annual runoff (units: micrograms per square meter (µg/m2) unless otherwise specified
San Francisco Estuary Institute Item #4 Is mercury always particulate and inorganic?(San Pedro, Storm Drain (San Jose)) HgD(%) 65% MeHgT(%) 1%
San Francisco Estuary Institute Item #4 Is mercury always particulate and inorganic?(Z4LA, Storm Drain (Hayward)) 36% HgD(%) MeHgT(%) 4%