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Table 15-1, p. 612 - PowerPoint PPT Presentation


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Table 15-1, p. 612. Common Names of Carboxylic Acids. Table 15.1. Common Names of Dicarboxylic Acids. Table 15.1. p. 614. Table 15-2, p. 615. p. 615. Fig. 15-1, p. 616. p. 616. p. 618. p. 618. Electrophilic Aromatic Substitution. Fig. 9-16, p. 338.

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slide13

pKa’s of Substituted Benzoic Acids

Lower pKa

Higher pKa

Fig. 9-16, p. 338

slide14

Preparation of Carboxylic Acids : Review

  • Oxidation of 1 alcohols:
    • a. CrO3, H3O+
    • b. K2Cr2O7, H2SO4
  • Oxidation of 1 alcohols:

p. 620

slide15

Preparation of Carboxylic Acids : Review

  • 2. Oxidation of aldehydes:
    • a. KMnO4
    • b. CrO3, H3O+
    • c. K2Cr2O7, H2SO4 (Jones)
  • Oxidation of 1 alcohols:

p. 620

slide16

Preparation of Carboxylic Acids : Review

  • 3. Oxidative cleavage (of double bonds):
    • a. KMnO4
    • b. O3, H2O2
  • Oxidation of 1 alcohols:

p. 620

slide17

Preparation of Carboxylic Acids : Review

  • 3. Oxidative cleavage a- to arene:
    • a. KMnO4
    • b. CrO3, H3O+
  • Oxidation of 1 alcohols:

Methyl, 1° , 2°