Chapter 8: Addition Reactions. Addition Reactions to Alkenes (Section 8.1) Markovnikov’s Rule (Section 8.2) Stereochemistry of Ionic Addition to Alkenes (Section 8.3) H 2 SO 4 Additions to Alkenes (Section 8.4) H 2 O Additions to Alkenes (Section 8.5)
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Chapter 8 Relevant Text: Pages 328-376
In the ionic additions of an unsymmetrical reagent to a double bond, the positive portion of the adding reagent attaches itself to a carbon atom of the double bond so as to yield the MORE STABLE CARBOCATION as an INTERMEDIATE
This Addition “Preference” is Called REGIOSELECTIVITY
What is the MECHANISM for this reaction? Know this!
H and OH Delivered anti-Markovnikov to the
SAME FACE of the p Bond
Sections 8.8 and 8.9 Deal w/ Mechanistic Aspects. This is
Interesting, but is NOT Testable Material (You May Omit)