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Thermal Physics. Temperature (Definition #1 – Macroscopic level ): a property that determines the direction of thermal energy transfer between two objects ▪ gives indication of the degree of hotness or coldness of a body, measured by thermometer.

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Thermal Physics


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slide3

Temperature (Definition #1 – Macroscopic level): a property that determines the direction of thermal energy transfer between two objects

▪ gives indication of the degree of hotness or coldness of a body, measured by thermometer

Temperature (Definition #2 – Microscopic level): a measure of the average random kinetic energy of all the particles of a system

▪ (absolute)temperature is directly proportional to the average kinetic energy of

the molecules of a substance: (KE)avg = kT (k is Boltzmann constant)

Kinetic energy of the molecules arises from random translational vibrational and rotational motion.

Potential energy of the molecules arises from the intermolecular forces (bonds).

Internal energy /Thermal energyistotal potential energy and random kinetic energy of the molecules of a substance

Heatis thethermal energytransferred from one body or system of higher temperature to another of lower temperature.

Thermal equilibrium occurs when all parts of the system are at the same temperature. There is nothermal energy transfer.(This is how a thermometer works)

slide4

Relative atomic mass is the mass of an atom in units of 1/12 of the mass

of a carbon-12 atom.

The moleis the amount of substance that contains the same number

of atoms/molecules as 0.012 kg of carbon-12.

Molar Mass is the mass of one mole of a substance (kg/mol).

1 mole of a gas at STP occupies 22.4 l (dm3) and contains

6.02 x 1023 molecules/mol.

slide5

Thermal Capacity is the amount of thermal energy needed to raise the temperature of a substance/object by one degree Kelvin.

Amount of energy needed to raise temperature of an object by ∆T K is

∆Q = C∆T

C = unit: (C) = J K-1

Specific heat capacity is the amount of thermal energy required to raise the temperature of one kilogram of a substance by one Kelvin.

Amount of energy needed to raise temperature of 1 kg of a substance

by ∆T K is

∆Q = cm∆T

c = unit: (c) = J kg-1K-1

The same amount of thermal energy is released when the temperature decreases by ΔT

homogeneous substance: C = mc

Thermal/heat capacity – object

“specific” is ‘per kg’ of a substance

slide6

Latent heat is the thermal energy that a substance/body absorbs or releases during a phase change at constant temperature.

L = Qatconst. temp.unit: J

Specific latent heat is the thermal energy required for a unit mass of a substance to undergo a phase change.

L = → Q = mLunit: (L) = J/kg

Ifelectrical energyis converted into increase of internal energy of the system, then:

  • Qadded = electrical energy = Pt = IVt = Qabosorbed
  • P – power, I – current, V – voltage, t - time
slide7

4 Phases (States) of Matter

solid, liquid, gas and plasma; ordinary matter – only three phases

changes of state

SOLID

LIQUID

GAS

Changes of State

Thermal energy added

sublimation

Deposition/desublimation

Melting/fusion

vaporisation

condensation

Freezing/solidification

Thermal energy given out

slide9

While melting, vibrational kinetic energy increases and particles gain enough thermal energy to break from fixed positions. Potential energy of system increases.

Melting point of a solid is the temperature at which it changes state from solid to liquid. Once at the melting point, any additional heat supplied does not increase the temperature. Instead is used to overcome the forces between the solid molecules increasing potential energy.

◌ At the melting point the solid and liquid phase exist in equilibrium.

While freezing, particles lose potential energy until thermal energy of the system is unable to support distance between particles and is overcome by the attraction force between them. Kinetic energy changes form from vibrational, rotational and part translational to merely vibrational.

Potential energy decreases

(It is negative!!! = attraction: intermolecular forces become stronger).

While boiling, substance gains enough potential energy to break free from inter-particle forces. Similar to evaporation, the only difference being that energy is supplied from external source so there is no decrease in temperature.

While condensing, the energy changes are opposite to that of boiling.

slide10

The distinguishing characteristic of a phase transition is an abrupt changein one or more physical properties, in particular the heat capacity, and the strength of intermolecular forces.

During a phase change, the thermal energy added or released is used to change (increase/decrease) the potential energy of the particles to either overcome or succumb to the inter-molecular force that pulls particles together. In the process, the average kinetic energy will not change, so temperature will not change.

slide11

Evaporationis a change of phase from the liquid state to the gaseous state that occurs ata temperature below the boiling point.

Evaporation causes cooling.

A liquid at a particular temperature has a range of particle energies, so at any instant, a small fraction of the particles will have KE considerably greater than the average value. If these particles are near the surface of the liquid, they will have enough KE to overcome the attractive forces of the neighbouring particles and escape from the liquid as a gas. The escape of the higher-energy particles will lower the average kinetic energy and thus lower the temperature.

The rate of evaporation is the number of molecules escaping the liquid per second. Evaporation can be increased by

• increasingtemperature/more particles have a higher KE

• Increasingsurfacearea/more particles closer to the surface

• Increasing air flow above the surface (gives the particles somewhere

to go to)/ decreasing the pressure of the air above liquid

slide12

Distinguish between evaporation and boiling.

  • Evaporation – process whereby liquid turns to gas, as explained above
      • - occurs at any temperature below the boiling temperature
      • - occurs only at surface of liquid as molecules escape
      • - causes cooling of liquid
  • Boiling– process whereby liquid turns to gas when the vapor pressure
  • of the liquid equals the atmospheric pressure of its surroundings
      • - occurs at one fixed temperature, dependent on substance and pressure
      • - occurs throughout liquid as bubbles form, rise to surface and are released
  • temperature of substance remains constant throughout process
slide13

Kinetic Model of an Ideal Gas

P – pressure,

V – volume,

  • N – number of particles,

k – Boltzmann constant,

T - temperature

  • PV = NkT

Gas pressureis the force gas molecules exert due to

their collisions (with a wall – imaginary or real), per unit area.

P =

Assumptions of the kinetic model of an ideal gas.

• Gases consist of tiny hard spheres/particles called atoms or molecules.

• The total number of molecules in any sample of a gas is extremely large.

• The molecules are in constant random motion.

• The range of the intermolecular forces is small compared to the average separation

of the molecules

• The size of the particles is relatively small compared with the distance between them

• No forces act between particles except when they collide, and hence particles

move in straight lines.

• Between collisions the molecules obey Newton’s Laws of motion.

• Collisions of short duration occur between molecules and the walls of the container and the collisions are perfectly elastic

(no loss of kinetic energy).

slide14

Temperature is a measure of the average random kinetic energy of the molecules

of an ideal gas.

Macroscopic behavior of an ideal gas in terms of a molecular model.

• Increase intemperatureis equivalent of an increase in average kinetic energy (greater average speed). This leads to more collisions and collisions with greater impulse. Thus resulting in higher pressure.

• Decrease involume results in a smaller space for gas particles to move, and thus a greater frequency of collisions. This results in an increase in pressure. Also, depending on the speed at which the volume decreases, particles colliding with the moving container wall may bounce back at greater speeds. This would lead to an increase in average kinetic energy and thus an increase in temperature.

• An increase in volume would have an opposite effect.

slide15

Application of the "Kinetic Molecular Theory" to the Gas Laws

  • Microscopic justification of the laws
slide16

Pressure Law (Gay-Lussac’s Law)

  • Effect of a pressure increase at a constant volume
  • Macroscopically:
  • at constant volume the pressure of a gas is proportional to its temperature:
  • PV = NkT → P = (const) T
  • Microscopically:
  • ∎ As T increases, KE of molecules increase
  • ∎ That implies greater change in momentum when they hit the wall of the container
  • ∎ Thus microscopic force from each molecule on the wall will be greater
  • ∎ As the molecules are moving faster on average they will hit the wall more often
  • ∎ The total force will increase, therefore the pressure will increase
slide17

The Charles’s law

  • Effect of a volume increase at a constant pressure
  • Macroscopically:
  • at constant pressure, volume of a gas is proportional to its temperature:
  • PV = NkT → V = (const) T
  • Microscopically:
  • ∎ An increase in temperature means an increase in the average kinetic energy
  • of the gas molecules, thus an increase in speed
  • ∎ There will be more collisions per unit time, furthermore, the momentum
  • of each collision increases (molecules strike the wall harder)
  • ∎ Therefore, there would be an increase in pressure
  • ∎ If we allow the volume to change to maintain constant pressure,
  • the volume will increase with increasing temperature
slide18

Boyle-Marriott’s Law

  • Effect of a pressure decrease at a constant temperature
  • Macroscopically:
  • at constant temperature the pressure of a gas is inversely proportional to its volume:
  • PV = NkT → P = (const)/V
  • Microscopically:
  • ∎ Constant T means that the average KE of the gas molecules remains constant
  • ∎ This means that the average speed of the molecules, v, remains unchanged
  • ∎ If the average speed remains unchanged, but the volume increases, this means
  • that there will be fewer collisions with the container walls over a given time
  • ∎ Therefore, the pressure will decrease