Ch 9 Lecture 3 Constitutional Isomers and Structures. Constitutional Isomers = different ligands in coordination sphere Hydrate Isomerism = Solvent Isomerism Different members of inner sphere, but same overall formula Different compounds with different characteristics
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known in the solid state
Examples: Fe(CO)5 and PF5 give only one NMR peak each
Both geometries present would give 2 peaks
The NMR only sees the average structure
3) Many complexes that are 4-coordinate as an individual molecule are really 6-coordinate in the solid state
Capped Trigonal Prism