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C p s = dq/dT

solid. liquid. q total at constant pressure = D H. C p l = dq/dT. D H m. C p s = dq/dT. (Dill and Bromberg, 2002). C V. C V undefined at the phase transition. T 1. T 2. D U. T (K). T m. liquid. solid. ~ a solid. ~(- k).

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C p s = dq/dT

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  1. solid liquid qtotal at constant pressure = DH Cpl = dq/dT DHm Cps = dq/dT

  2. (Dill and Bromberg, 2002)

  3. CV CV undefined at the phase transition T1 T2 DU T (K) Tm

  4. liquid solid ~asolid

  5. ~(-k)

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