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Transformation of Carbon Dioxide

Transformation of Carbon Dioxide. 郭昌 2009.10.31. Trend in CO 2 emissions from fossil fuel combustion. Global change in CO 2 emissions (2004-2005). Top-10 emitting countries in 2005. World CO2 emissions by sector. CO 2 EMISSIONS FROM FUEL COMBUSTION (2007 Edition).

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Transformation of Carbon Dioxide

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  1. Transformation of Carbon Dioxide 郭昌 2009.10.31

  2. Trend in CO2 emissions from fossil fuel combustion Global change in CO2 emissions (2004-2005) Top-10 emitting countries in 2005 World CO2 emissions by sector CO2 EMISSIONS FROM FUEL COMBUSTION (2007 Edition)

  3. Typical Transformations of Carbon Dioxide 一般意义上来说，可以将CO2看成是碳酸酐，可以很好的与碱性物质发生反应，比如， CO2与格式试剂在低温下就可以发生反应，同样也可以与水、醇盐、氨基等发生加成反应，生成相应的羧酸根。

  4. CO2与金属形成络合物

  5. CO2与金属形成晶体

  6. 氢化

  7. 超临界CO2应用

  8. 超临界CO2应用

  9. CO2形成五元金属杂环

  10. CO2形成五元金属杂环

  11. CO2形成6元金属杂环

  12. CO2插入反应 JACS, 2004, 126, 5956-5957 Ps: Ni(acac)2=5%, Et2Zn=4.5 equiv

  13. 与环氧形成五元环

  14. 与环氧形成五元环 Yield up to 100%

  15. 与环氧形成高聚物

  16. 与环氧形成高聚物 Zn, Cr, Al, Co, La, Mn, 等金属 可以催化CO2形成高聚物。

  17. CO2和 N-杂环丙烷的反应

  18. DBU吸收CO2

  19. 利用CO2合成尿素及异氰酸酯

  20. 利用CO2合成氨基甲酸酯 J. Org. Chem. 2001, 66, 1035-1037

  21. 利用CO2合成氨基甲酸酯

  22. CO2合成五元杂环

  23. CO2合成五元杂环

  24. 利用CO2合成有机羧酸

  25. 利用CO2合成有机羧酸

  26. CO2合成羧酸 Yield up to 50%

  27. CO2直接合成羧酸 JACS，ASAP

  28. CO2芳基化

  29. CO2与炔烃形成高聚物

  30. CO2合成六元环

  31. 基于CO2的串联反应

  32. Ugi反应

  33. 转化图

  34. 谢谢

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