1 / 5

50 likes | 190 Views

(+) ESI 9.4 T FT-ICR MS Deepwater Horizon Oil Spill Contaminant. Figure S1. Broadband. Quadrupole Isolation. m/z. 400. 600. 800. 1000. Figure S2. + 2.00424. = m/z 425.42390. (+) ESI 9.4 T FT-ICR MS. C 28 H 55 O 1 18 O 1 S/N<1. C 28 H 55 O 2 m/z 423.41966 * m/z 423.419657

Download Presentation
## Quadrupole Isolation

**An Image/Link below is provided (as is) to download presentation**
Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author.
Content is provided to you AS IS for your information and personal use only.
Download presentation by click this link.
While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server.
During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

**(+) ESI 9.4 T FT-ICR MS**Deepwater Horizon Oil Spill Contaminant Figure S1 Broadband Quadrupole Isolation m/z 400 600 800 1000**Figure S2**+ 2.00424 = m/z 425.42390 (+) ESI 9.4 T FT-ICR MS C28H55O118O1 S/N<1 C28H55O2 m/z 423.41966 *m/z 423.419657 S/N 605 150 ppb Quadrupole Isolation 500 Acquisitions Deepwater Horizon Oil Spill Contaminant 425.42 423.41 425.422 425.424 423.42 410 415 420 425 430 435 440 m/z**C28H55O118O1**S/N < 1 *Calculated C28H55O118O1 m/z 425.42390 *m/z 425.423904 21 ppb S/N 7.6 m/z 425.420 425.422 425.424 (+) ESI 9.4 T FT-ICR MS Deepwater Horizon Oil Spill Contaminant Figure S3 C27H43O2 13C2 S/N 53.1 Quad Isolation C27H53 N1O22D1 S/N<0 C24H46N1O2S113C1 S/N 28.2 C29H43O118O1 m/z 425.33010 *m/z 425.330003 219 ppb S/N = 6.4 C25H45O5 S/N 25.5 C27H43O2 13C2 S/N 135.9 SWIFT Isolation C29H43O118O1 m/z 425.33003 *m/z 425.330003 117 ppb S/N 19.8 C24H46N1O2S113C1 S/N 97.0 C25H45O5 S/N 65.7 C27H53 N1O22D1 S/N 4.4 m/z 425.326 425.330**(+) ESI 9.4 T FT-ICR MS**Heavy Crude Oil SWIFT A C33H54N1 S/N ≈ 2632 1 Acquisition C32H54N113C1 Figure S4 C33H54N1 S/N ≈ 1726 SWIFT B 1 Acquisition C32H54N113C1 m/z 464 465 466 464 465 466**Signal**Magnitude ≈ 1.6 (+) ESI 9.4 T FT-ICR MS Heavy Crude Oil C33H53N12D1 465.43129 *465.43125 S/N = 7.3 76 ppb 465.432 465.434 465.436 C33H53N12D1 465.43130 *465.43125 S/N = 14.0 105 ppb 465.432 465.434 465.436 C32H53N2 S/N 47.4 C33H5415N1 465.42211 *465.42211 S/N = 3.1 40 ppb SWIFT A C30H58 S115N1 S/N 13.3 1 Acquisition Figure S5 Signal Magnitude ≈ 1.3 C32H53N2 S/N 43.1 SWIFT B 1 Acquisition C33H5415N1 465.42200 *465.42211 S/N = 8.7 249 ppb *Calculated C30H58 S115N1 S/N 12.1 465.420 465.421 465.422 465.423 465.424 465.425 465.426 465.427

More Related