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More on symmetry

The story so far. In the lectures we have discussed point symmetry:RotationsMirrors. . . In the workshops we have looked at plane symmetry which involves translation ? = ua vb wcGlidesScrew axes. Back to stereograms and point symmetry. Example: 2-fold rotation perpendicular to plane (2).

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More on symmetry

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    1. More on symmetry Learning Outcomes: By the end of this section you should: have consolidated your knowledge of point groups and be able to draw stereograms be able to derive equivalent positions for mirrors, and certain rotations, roto-inversions, glides and screw axes understand and be able to use matrices for different symmetry elements be familiar with the basics of space groups and know the difference between symmorphic & non-symmorphic

    2. The story so far… In the lectures we have discussed point symmetry: Rotations Mirrors

    3. Back to stereograms and point symmetry Example: 2-fold rotation perpendicular to plane (2)

    4. More examples Example: 2-fold rotation in plane (2)

    5. Combinations Example: 2-fold rotation perpendicular to mirror (2/m)

    6. Roto-Inversions A rotation followed by an inversion through the origin (in this case the centre of the stereogram)

    7. Special positions When the object under study lies on a symmetry element ? mm2 example

    8. In terms of axes… Again, from workshop: Take a point at (x y z) Simple mirror in bc plane

    9. General convention Right hand rule (x y z) ? (x’ y’ z’)

    10. Back to the mirror… Take a point at (x y z) Simple mirror in bc plane

    11. Other examples

    12. More complex cases For non-orthogonal, high symmetry axes, it becomes more complex, in terms of deriving from a figure. 3-fold example:

    13. 3-fold and 6-fold It is “obvious” that 62 and 64 are equivalent to 3 and 32, respectively.

    14. 32 crystallographic point groups display all possibilities for the symmetry of space-filling shapes form the basis (with Bravais lattices) of space groups

    15. 32 crystallographic point groups Centrosymmetric – have a centre of symmetry Enantiomorphic – opposite, like a hand and its mirror * - polar, or pyroelectric, point groups

    16. Space operations These involve a point operation R (rotation, mirror, roto-inversion) followed by a translation ? Can be described by the Seitz operator:

    17. Glide planes The simplest glide planes are those that act along an axis, a b or c Thus the translation is ˝ way along the cell followed by a reflection (which changes the handedness: )

    18. n glide n glide = Diagonal glide Here the translation vector has components in two (or sometimes three) directions

    19. n glide Here the glide plane is in the plane xy (perpendicular to c)

    20. d glide d glide = Diamond glide Here the translation vector has components in two (or sometimes three) directions

    21. d glide Here the glide plane is in the plane xy (perpendicular to c)

    22. 17 Plane groups Studied (briefly) in the workshop Combinations of point symmetry and glide planes

    23. Another example Build up from one point:

    24. Screw axes Rotation followed by a translation Notation is nx where n is the simple rotation, as before x indicates translation as a fraction x/n along the axis

    25. Screw axes - examples Note e.g. 31 and 32 give different handedness

    26. Example P42 (tetragonal) – any additional symmetry?

    27. Matrix 4 fold rotation and translation of ˝ unit cell

    28. Symmorphic Space Groups If we build up into 3d we go from point to plane to space groups

    29. Example of Symmorphic Space group

    30. Example of Symmorphic Space group

    31. Systematic Absences #2 Systematic absences in (hkl) reflections ? Bravais lattices e.g. Reflection conditions h+k+l = 2n ? Body centred

    32. Space Group example P2/c

    33. Space Group example P21/c : note glide plane shifted to y=Ľ because convention “likes” inversions at origin

    34. Special positions Taken from last example If the general equivalent positions are:

    35. Space groups… Allow us to fully describe a crystal structure with the minimum number of atomic positions Describe the full symmetry of a crystal structure Restrict macroscopic properties (see symmetry workshop) – e.g. BaTiO3 Allow us to understand relationships between similar crystal structures and understand polymorphic transitions

    36. Example: YBCO Handout of Structure and Space group Most atoms lie on special positions YBa2Cu3O7 is the orthorhombic phase Space group: Pmmm

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