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National 5 Chemistry

National 5 Chemistry. Unit 2 – Nature’s Chemistry Section 7 – Everyday Consumer Products. Section 7 – Alcohols Pupils should be able to…. Identify that an alcohol molecule contains –OH as its functional group

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National 5 Chemistry

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  1. National 5 Chemistry Unit 2 – Nature’s Chemistry Section 7 – Everyday Consumer Products

  2. Section 7 – AlcoholsPupils should be able to… • Identify that an alcohol molecule contains –OH as its functional group • State that alcohols are straight chain molecules and can be represented by a general formula • State that alcohols are used a fuels as they are highly flammable. • State that they burn with clean flames • State that alcohols are often used as solvents • State that methanol, ethanol and propanol are miscible in water • State that after propanol solubility decreases as the size of the alcohol molecule increases • State and explain why as alcohol molecular size increases, the strength of the intermolecular force increases • Name straight chain alcohols containing no more that 8 carbons • Write molecular formulae and draw structural formulae from systematic names

  3. What is a Homologous Series? Homologous Series • A group of chemically similar compounds which can be represented by a general formula. • Physical properties change gradually as you go down the series • There are two groups that we are going to look at Alcohol 2. Carboxylic acids

  4. What makes a molecule an Alcohol? The chemical structure of an alcohol can be obtained by replacing one of the hydrogen atoms of an alkane with an –OH group, the hydroxyl functional group as shown below. • ethane

  5. Uses of Alcohols • Ethanol can be produced on a large scale by catalytic hydration of ethene. • This ethanol can be used as a fuel solvents, making medicines, printing inks and cosmetic products.

  6. Alcohols Methanol Monsters Ethanol Eat Propanol Pupils ButanolBut PentanolPrefer HexanolHairy HeptanolHaggis OctanolOccasionally

  7. Alcohol Structure 3D Full Structural  2D Full Structural Formula Formula

  8. Alcohols • Each member can be represented in three different ways: Methanol Propanol • Full Structural Formula • Shortened Structural Formula • Molecular Formula • CH3OH • CH3CH2CH2OH • CH3OH • C3H7OH

  9. Alcohol Information • The alcohols are a family of hydrocarbons that all share similar properties. • Single Carbon to carbon bonds (- C – C -) • Burn in plentiful of oxygen to produce carbon dioxide and water • Saturated hydrocarbons • Highly flammable • All share a General Formula

  10. Trends of the Alcohols

  11. Trends of the Alcohols

  12. Alcohol Trend Summary

  13. Alcohol General Formula • The number of Hydrogen atoms = 2 times the number of Carbon atoms plus 1 plus OH on the end General Formula for alcohols is CnH2n+1OH

  14. Alcohols – Physical Properties • B.p– gradual increase from methanol to octanol • Viscosity - increases as molecular size increases • Flammability – burns with a clean flame • Miscibility - methanol, ethanol and propanol are miscible in water • Solubility –solubility decreases after propanol as the size of the alcohol molecule increases

  15. Intermolecular Forces between Molecules • Larger molecules have more places for intermolecular forces. • More intermolecular forces requires more energy to overcome these forces thus the larger the molecule the higher the melting and boiling point.

  16. Naming Alcohols • Find the longest chain which includes the functional group. This will form the last part of the name. • Number the main chain so that it gives the functional lower number over positions to the side groups. • Side branch names end in “yl” and depend on the number of carbon atoms in them; 1 = methyl 2 = ethyl 3 = propyl etc • Alphabetically order is used if different side branches appear in the same structure e.g. ethyl before methyl • Hyphens are used before or after numbers that come next to letters within a name e.g. (2-ethyl-3-methyl…..) • Commas are used between numbers if there is more than one of the same side branch (e.g. 2,3,3 – trimethyl….)

  17. Name each of these Straight Chain Alcohols It has a chain of two carbon atoms and only single carbon to carbon bonds . It contains the hydroxyl functional group so this makes it ethanol It has a chain of 5 carbon atoms and only single carbon to carbon bonds. It contains the hydroxyl functional group so this makes it pentan-1-ol

  18. Name each of these Straight Chain Alcohols Butan-1-ol It has a chain of 4 carbon atoms and the hydroxyl functional group on the 1st carbon Butan-2-ol It has a chain of 4 carbon atoms and the hydroxyl functional group on the 2nd carbon Because these molecules have different structures we must give them different names

  19. Name these Straight Chain Alcohols Ethanol 3-methylbutan-1-ol pentan-1-ol 2-methylhexan-2-ol

  20. Section 7 – Carboxylic AcidsPupils should be able to… • Identify that a carboxylic acid molecule contains –COOH as its functional group • State that carboxylic acids are straight chain molecules and can be represented by a general formula • State uses of carboxylic acids as soaps, medicines and in the preparation of preservatives • Discuss the chemical and physical properties of vinegar a solution of ethanoic acid • State that methanoic, ethanoic, propanoic and butanoicare miscible in water • State that after butanoicsolubility decreases as the size of the acidmolecule increases • State and explain why as carboxylic acid molecular size increases, the strength of the intermolecular force increases • Name straight chain carboxylic acids containing no more that 8 carbons

  21. Section 7 – Carboxylic AcidsPupils should be able to… • Write molecular formulae and draw structural formulae from systematic names • State that solutions of carboxylic acids have a pH less than 7. • State that they can act as a base to react with metals, metal oxides, hydroxides and carbonates to form salts • Name salts formed from straight chain carboxylic acids containing no more that 8 carbons

  22. Carboxylic Acids • Carboxylic acids are a group of important straight chain organic chemicals. Vinegar contains ethanoic acid, which is a carboxylic acid. All carboxylic acids have a –COOH functional group, and have similar reactions as a result. • The carboxylic acids are a homologous series of organic compoundsso they can be represented by a general formula. • The names of carboxylic acids end in ‘-oicacid’ – egethanoic acid.

  23. What makes a molecule a Carboxylic Acid? • The chemical structure of a carboxylic acid can be obtained by removing all of the hydrogen atoms of an alkane and replacing it with the carboxyl functional group - COOH as shown below. • Ethanoic Acid • ethane

  24. Carboxylic Acids MethanoicMonsters EthanoicEat PropanoicPupils ButanoicBut PentanoicPrefer HexanoicHairy HeptanoicHaggis OctanoicOccasionally

  25. Carboxylic AcidStructure 3D Full Structural  2D Full Structural Formula Formula

  26. Carboxylic Acid • Each member can be represented in three different ways: MethanoicPropanoic • Full Structural Formula • Shortened Structural Formula • Molecular Formula • HCOOH • CH3CH2COOH • HCOOH • C2H5COOH

  27. Carboxylic AcidInformation • The carboxylic acidsare a family of hydrocarbons that all share similar properties. • Single Carbon to carbon bonds (- C – C -) • All share a General Formula • All form weak acids when dissolved in water All act as a base, so react with metals, metal oxides, metal hydroxides and metal carbonates.

  28. Trends of the Carboxylic Acids

  29. Trends of the Carboxylic Acids

  30. Carboxylic Acid Trend Summary

  31. Carboxylic Acid General Formula • The number of Hydrogen atoms = 2 times the number of Carbon atoms plus 1, plus COOH on the end General Formula for alcohols is CnH2n+1COOH

  32. Carboxylic Acid – Physical Properties • B.p– gradual increase from methanoicto octanoic • Viscosity - increases as molecular size increases • pH – Solutions of carboxylic acids have a pH less than 7 They are weak acids because this functional group is only partly ionised in solution. • Solubility– Methanoic butanoic acid are miscible in water. After butanoic acid solubility decreases as the size of the molecule increases

  33. Properties of Carboxylic Acids • They dissolve in water to produce acidic solutions (pH less than 7). • Carboxylic acids can act as a based to react with metals, metal oxides, metal hydroxides and Metal carbonates. • They react with carbonates to produce carbon dioxide, a salt and water. For example: • calcium carbonate + ethanoic acid → calcium ethanoate + water + carbon dioxide

  34. Intermolecular Forces between Molecules • Larger molecules have more places for intermolecular forces. • More intermolecular forces requires more energy to overcome these forces thus the larger the molecule the higher the melting and boiling point. • As carboxylic molecular size increases, the strength of the intermolecular force increases.

  35. Naming Carboxylic Acids • Find the longest chain which includes the functional group. This will form the last part of the name. • Number the main chain so that it gives the functional lower number over positions to the side groups. • Side branch names end in “yl” and depend on the number of carbon atoms in them; 1 = methyl 2 = ethyl 3 = propyl etc • Alphabetically order is used if different side branches appear in the same structure e.g. ethyl before methyl • Hyphens are used before or after numbers that come next to letters within a name e.g. (2-ethyl-3-methyl…..) • Commas are used between numbers if there is more than one of the same side branch (e.g. 2,3,3 – trimethyl….)

  36. Name each of these Straight Chain Carboxylic Acids It has a chain of two carbon atoms and only single carbon to carbon bonds . It contains the carboxyl functional group so this makes it ethanoic It has a chain of 4carbon atoms and only single carbon to carbon bonds. It contains the hydroxyl functional group so this makes it buttanoic

  37. Uses of Carboxylic Acids • Soaps • Medicines • Food Preservation • Carboxylic Acids in Food

  38. 1. Soaps • As you should know from Unit 1, acids must produce H+ ions when dissolved in water. Carboxylic acids produce some H+ ions when dissolved in water e.g. • CH3COOH (aq) CH3COO-(aq) + H+(aq) • These are known as weak acids as they only partially ionise when they are added to water. HCl and H2SO4 are strong acids as the completely ionise when dissolved in water.

  39. 3. Food Preservation • Vinegar is a solution of ethanoic acid and is widely used to preserve food. Its low pH prevents bacteria and fungi from growing. This is an example of pickling e.g. onions and eggs

  40. 4. Carboxylic Acids in Food • Benzoic acid occurs naturally in foods such as raspberries and tea. It is synthesised and used as a food additive – E210, which acts as a preservative in fruit products and soft drinks • Sodium benzoate – E211, is similar and is used in bottled sauces and fruit juices. • Citric acid is found in citrus fruits and is responsible for their bitter taste. This is used as flavouring in fruit drinks and in cooking.

  41. Questions • 1.Draw the full structural formula of: • Butanoic acid • Ethanoic acid • 2. Name this structure: • 3. Can you work out the general formula of the carboxylic acids?

  42. Question 1 2019

  43. Question 2 ?

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