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For the first time, a method for calculating formulas of homologous series of chemical compounds of the systems (Aa u2013 Bb u2013 Ccu2013) and {Zn2 u2013 Ge4 u2013 P3u2013} in a generalized form is presented. The calculation is confirmed by the literature experimentally obtained compounds: thirteen compounds of the system (Na u2013 Ti4 u2013 O2u2013), seven u2013 systems (Li u2013 Ti4 u2013 O2u2013), five u2013 systems (K u2013 V5 u2013 u2013 O2u2013), eight u2013 systems (Ba2 u2013 Cu2 u2013 O2u2013). Homological series in (Aa u2013 Bb u2013 Ccu2013) have the following generalized form: A{t u2013 ku00b7r nr u2013 r)bcBracC{t u2013 ku00b7r nr)ab and AtbcB{r u2013 ku00b7t nt u2013 t}acC (r u2013 ku00b7t
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