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Phase Transitions. CHEE 490. 3.2. Crystalline State. Under appropriate conditions, some polymers can be cooled from a melt condition can generate an imperfect crystal structure.The basic units of crystalline polymer morphology are crystalline lamellae, consisting of folded chains.NonadjacentRegular adjacentIrregular adjacentreentry reentryreentryCrystallization/melting of polymer crystallites is a classical phase transition, identical to that of small molecules.Be1140

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phase transitions in polymer systems fried 4.1-4.3


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