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What is Radical Reactions? Radical reactions involve chemical species with unpaired electrons, radicals, which are highly reactive and short-lived. These reactions play crucial roles in organic synthesis, combustion, and atmospheric chemistry. known as polymerization, onlineorganicchemistrytutor.com
TYPES OF RADICAL REACTIONS Dani Martinez 01 Initiation 03 Termination Propagation 02 onlineorganicchemistrytutor.com
INITIATION PHASE 01 The initiation phase describes the step that initially creates a radical species. In most cases, this is a homolytic cleavage event, and takes place very rarely due to the high energy barriers involved. Often the influence of heat, UV radiation, or a metal-containing catalyst is necessary to overcome the energy barrier. onlineorganicchemistrytutor.com
PROPAGATION PHASE 02 The propagation phase describes the 'chain' part of chain reactions. Once a reactive free radical is generated, it can react with stable molecules to form new free radicals Propagation steps often involve abstraction or addition of the radical to double bonds. hydrogen onlineorganicchemistrytutor.com
TERMINATION PHASE Termination occurs when two free radical species react with each other to form a stable, non-radical adduct. Although this thermodynamically downhill event, it is also very rare due to the low concentration of radical species and the small likelihood of two radicals colliding with one another 03 is a very onlineorganicchemistrytutor.com
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