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Understanding Addition Reactions Addition reactions are fundamental to organic chemistry. involve the addition of atoms or groups of atoms to a molecule, typically across a double or triple bond. They are crucial for synthesizing complex molecules and understanding reaction mechanisms. These reactions onlineorganicchemistrytutor.com
Types of Addition Reactions Nucleophilic Addition Reactions 01 02 Electrophilic Addition Reactions 03 Free-Radical Addition Reactions 04 Cycloadditions Reactions
Nucleophilic Addition Reactions These are the types of addition reactions in which a nucleophile reacts with a chemical species having an electrophilic double or triple bond. Example>> Hydrogen cyanide reacts with acetone to form acetone cyanohydrin.
Electrophilic Addition Reactions In this type of chemical reaction, an electrophile (created) forms a covalent bond with an unsaturated and electron-rich carbon-carbon double bond Example>> Ethene reacts with bromine to yield 1,2- dibromoethane
FREE-RADICAL ADDITION REACTIONS In these types of chemical reactions, free- radical species are involved. It can either occur between a radical and a non-radical or two radicals. EXAMPLE Addition of mineral acid to an alkene
CYCLOADDITIONS REACTIONS These are the chemical reactions in which parts of the same molecule or two or more unsaturated molecules react to form a cyclic product (adduct). EXAMPLE Diels–Alder reaction
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