Research activities on biodiesel at indian institute of petroleum dehradun india
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Research Activities on Biodiesel at INDIAN INSTITUTE OF PETROLEUM DEHRADUN - INDIA. Activities on Biodiesel Technology Development. Research activities on process development for Biodiesel (methyl esters) carried out under a sponsored project by Department of Biotechnology, New Delhi

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Research Activities on Biodiesel at INDIAN INSTITUTE OF PETROLEUM DEHRADUN - INDIA

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Research activities on biodiesel at indian institute of petroleum dehradun india

Research Activities on Biodiesel at INDIAN INSTITUTE OF PETROLEUMDEHRADUN - INDIA


Research activities on biodiesel at indian institute of petroleum dehradun india

Activities on Biodiesel Technology Development


Research activities on biodiesel at indian institute of petroleum dehradun india

  • Research activities on process development for Biodiesel (methyl esters) carried out under a sponsored project by Department of Biotechnology, New Delhi

  • R&D preparation of ethyl esters of Jatropha curcas oil and its field trials on diesel vehicles is being pursued under a collaborative project with MNES, New Delhi.

  • Studies on bio-diesel from waste cooking oils and greases being carried under a sponsored project by PCRA, New Delhi


Feedstocks for biodiesel

Feedstocks for Biodiesel

  • Biodiesel is prepared from oils and fats.

  • Oils and fats are composed of molecules called triglycerides.

    USA : Soya Oil is predominant

    Europe : Canola, rapeseed oil largely used

    Other feedstock: Tallow, lard, yellow grease, palm oil Include etc.


Research activities on biodiesel at indian institute of petroleum dehradun india

Feedstocks in Indian Context

  • For India non-edible oils obtained from plants which can be grown on waste/ semi arid lands are more suitable. Species can be selected based on the regional climatic conditions

  • Most of the non-edible oils available in India contains high FFA (2-12%)


Research activities on biodiesel at indian institute of petroleum dehradun india

Non Edible Vegetable Oils

Available in India

Possible raw materials for biodiesel

RatanjyotJatropha curcas

KaranjaPongamia glabra

MahuaMadhuca indica

PiluSalvadora oleoides

SalShorea robusta

NahorMesua ferra linn

KamalaMallotus phillipines

KokamGarcinia indica

Rubber SeedHevea Brasilensis


Feedstocks tested at iip for biodiesel production

Feedstocks Tested at IIP for Biodiesel Production

  • Jatropha curcas

  • Pongamia glabra

  • Madhuca Indica

  • Salvadora Oleoides

  • Hevea Brasileusis (Rubber seed oil)

  • Palm stearin

  • Waste Palm oil

  • Prinspia Utilis

  • Sapindus Mukorossi

  • Soya oil

  • Rape seed oil

  • Mixed vegetable oils

  • Waste grease / oil from restaurants


Commercial biodiesel technologies

Commercial Biodiesel Technologies

Currently used technologies for producing biodiesel can be classified into three categories:

  • Base catalyzed transesterification with refined oils

  • Base catalyzed transesterification with low fatty acid greases and fats

  • Acid esterification followed by transesterification of lower or high free fatty acid fats and oils.

    Other process under development include – biocatalyzed transesterification, pyrolysis of vegetable oil/ seeds and transesterification in supercritical methanol.


Research activities on biodiesel at indian institute of petroleum dehradun india

The goal of all technologies is to produce fuel grade esters meeting standard specifications (e.g. ASTM/ European/BIS).

  • The key quality control issues involve :

    • complete (or nearly complete) removal of alcohol, catalyst, water, soaps, glycerine and unreacted or partially reacted triglycerides and free fatty acids (FFA).

  • Failure to remove these contaminants causes the biodiesel to fail one or more fuel standards.


Research activities on biodiesel at indian institute of petroleum dehradun india

Basic Process

The basic process involves transesterification of vegetable oil/fats in presence of a catalyst in batch or continuous mode. Continuous process may not be suitable, if the variation in quality of feedstocks are wide.


Research activities on biodiesel at indian institute of petroleum dehradun india

There are numerous variations of basic technology:

  • Different catalysts e.g. NaOH, KOH, MeONa, Non alkaline catalysts, acids, metal complexes and bio catalysts etc. can be used.

  • Anhydrous ethanol, isopropanol or butanol can be substituted for methanol.

  • Alcohols other than methanol may require additional process steps and quality control.

  • Basic transesterification is carried out at atmospheric pressure and temperature around 60°-70°C.

  • Some technologies use higher temperatures and elevated pressure, typically in super critical range of methanol.

  • For high FFA feedstocks – acid catalysed esterification followed by base catalysed transesterification is used or FFA can be removed first and the purified oil is transesterified.


Problems of biodiesel production

Problems of Biodiesel Production

Both base and acid catalyzed processes are associated with several inherent problems:

  • Free fatty acids interfere with transesterification deactivate the basic catalysts – loss of catalyst and biodiesel yield.

  • Water deactivates both basic and acidic catalysts. Drying of oil may be required.

  • Soaps formed with basic catalyst form emulsion and foam and difficult to remove.

  • When processing feed stocks with high free fatty acids additional steps must be taken.

  • After basic transesterification, the purification and adequate testing during processing is required to produce fuel grade esters.


Appropriate technology

Appropriate Technology

The selection of appropriate technology for production of biodiesel requires careful selection of processing steps, catalyst and downstream process integration. The quality of feed vegetable oil particularly FFA content plays and important role in identifying the suitable technology.


Research activities on biodiesel at indian institute of petroleum dehradun india

The important factors to be considered include:

  • Must be able to process variety of vegetable oils without or minimum modifications.

  • Must be able to process high free fatty containing oils/ feed stocks.

  • Must be able to process raw both expelled and refined oil.

  • Process should be environment friendly almost zero effluents.

  • Able to produce marketable by products glycerin, fatty acids, soap if any.

  • Must be able to produce fuel grade esters; Biodiesel produced should meet the standard specifications.

  • The process should be adaptable over a large range of production capacities.


Iip processes for biodiesel

IIP Processes for Biodiesel

India Institute of Petroleum has developed three processes for biodiesel from non-edible oils and under exploited oils including Jatropha curcas, Pongamia, Salvadora, Madhuca Indica and Mixed Oils.


Process i

Process – I

Base catalysed process:

  • This process is suitable for feed stocks having FFA content >1% to about 20%.

  • The oil is pretreated before transesterification at moderate temperature (60-80°C) in presence of a base catalyst.

  • FFA are also converted to biodiesel resulting in higher yield of biodiesel.


Research activities on biodiesel at indian institute of petroleum dehradun india

Vegetable oil

Oil Pretreatment

Methanol + catalyst

Transesterification

Crude glycerine

Crude Biodiesel

Methanol recovery

Refining

Glycerine refining

Biodiesel

Glycerine

IIP Processes for Biodiesel – Process – I


Main features of iip process i

Main Features of IIP Process – I

  • Flexibility for processing variety of vegetable oils separately or mixed without any modification.

  • Tolerance of higher levels of free fatty acids

  • Conversion of free fatty acids present in feed oils to biodiesel or alternatively free fatty acids can be recovered as byproduct or soap.

  • Biodiesel produced meets the standard specification (ASTM, European or proposed BIS).

  • Glycerin produced is ~ 99% pure.

  • Process can be adapted to wide range of production capacities.


Process ii

Process – II

Solid catalyst process:

  • This process is suited to feed stocks containing wide range of FFA or 100% FFA.

  • In this process esterification of FFA and transesterification of triglycerides is carried out in a single step over a heterogeneous catalyst at moderate temperature and pressure.


Research activities on biodiesel at indian institute of petroleum dehradun india

Fresh Vegetable Oil

Esterification &

Transesterfication

Fresh Methanol

Methanol Recovery

Recycle Methanol

BIODIESEL

Biodiesel Purification

Phase Separation

Glycerine Phase

Glycerine Refining

Glycerine

IIP Processes for Biodiesel : Process – II


Main features of iip process ii

Main Features of IIP Process – II

  • Flexibility for processing variety of vegetable oils separately or mixed.

  • Tolerance of higher levels of free fatty acids. Requires no pretreatment or removal of FFA.

  • Conversion of free fatty acids present in feed oils to biodiesel.

  • Tolerance of water in alcohol (aqueous ethanol can be used)

Continued...


Research activities on biodiesel at indian institute of petroleum dehradun india

…IIP Process – II

  • No emulsion or soap formation

  • Catalyst is recycled and is not deactivated either with water or FFA.

  • Biodiesel produced meets the standard specification (ASTM, European or proposed BIS).

  • Glycerine produced is ~ 99% pure.

  • Process can be adapted to wide range of production capacities.

  • The process is ecofriendly with almost zero effluents.


Heterogeneous catalyst process technological and economic benefits

…IIP Process – II

Heterogeneous catalyst Process….Technological and economic benefits

  • Use of heterogeneous catalyst has direct impact on the economics of biodiesel production.

  • Several neutralisation and washing steps needed for processes using homogeneous catalysts such as NaOH, KOH, MeONa etc. are eliminated.

  • Associated waste streams are eliminated.


Process iii

Process – III

Base catalyst-solvent process:

  • This process is suitable for feedstocks having upto about 6% FFA .

  • Transesterification is carried out at ambient conditions in presence of a base catalyst. After separation of glycerin biodiesel is purified by distillation.

  • Oil containing higher FFA can also be processed, if a pretreatment step is included.

  • From technical point of view this process is especially suitable for small scale operations.


Research activities on biodiesel at indian institute of petroleum dehradun india

Oil Feed

Removal of FFA

(Optional)

Solvent

Transesterification

Glycerine separation

Solvent

Recycle

Glycerine

Biodiesel purification

Biodiesel

MeOH + Catalyst

IIP Processes for Biodiesel – Process – III


Comparison of biodiesel iip processes with national international specifications

Comparison of Biodiesel (IIP Processes) With National & International Specifications


Research activities on biodiesel at indian institute of petroleum dehradun india

Any of these processes can be selected to produce biodiesel depending upon the characteristics of feed oil stock. Biodiesel produced meets standard specifications (ASTM / European / BIS proposed) by all three processes.


Economics

Economics

  • The cost analysis indicates that the cost of oil is major component (about 75-80 %) of total cost of biodiesel.

  • Use of lower cost feed stocks would have tremendous impact on biodiesel economics.

  • Another approach which leads to reduction in operating cost is improvement in technology


Research activities on biodiesel at indian institute of petroleum dehradun india

Effect of by-products on economics

  • Market value of glycerol produced as a by-product is an important factor in biodiesel economics.

  • Glycerol market is limited, any major increase in biodiesel capacity would undoubtedly lead to glycerol prices to decline, thereby affecting the over all economics of biodiesel.

  • Value addition to oil cake would have greater impact on economics


Economics of biodiesel production effect of technology improvements

Economics of Biodiesel production:Effect of Technology improvements -


Activities on quality and performance evaluation

Activities on Quality and Performance Evaluation


Corrosion behaviour of biodiesel on diesel engine parts

Corrosion Behaviour of Biodiesel on Diesel Engine Parts

  • Corrosion behavior of biodiesel produced from various non-edible oils was estimated during long duration static immersion test.

  • Biodiesel from Mohua & Karanj shows no corrosion on piston metal & piston liner where as salvadora biodiesel has a marked corrosion effect on both the metals indicating that this oil is not suitable for biodiesel production especially when Bharat III & Bharat IV norms will be implemented.

  • Higher corrosion with salvadora biodiesel is probably due to its high sulfur content, ~ 1600 ppm.

  • Jatropha curcas has slight corrosive effect on piston liner possibly due to the presence of linoleic acid 18:2 fatty acids.


Corrosion behavior of biodiesels on diesel engine parts using static immersion test for 300 days

Corrosion Behavior of Biodiesels on Diesel Engine Parts Using Static Immersion Test for 300 Days


Lubricity of lco diesel biodiesel blends

Lubricity of LCO/Diesel - Biodiesel Blends

The lubricity behavior of base fuel, Light cycle oil LCO/Diesel and biodiesel blends of Jatropha curcas and Pogamia glabra in LCO were assessed by HFRR test (ISO 12156 method).


Base fuel properties lco

Base Fuel Properties (LCO)


Base fuel properties diesel

Base Fuel Properties (Diesel)


Research activities on biodiesel at indian institute of petroleum dehradun india

HFRR Lubricity Evaluation for Biodiesel in LCO


Lubricity of biodiesel diesel blends

LUBRICITY OF BIODIESEL – DIESEL BLENDS


Studies on lubricity behaviour of biodiesel diesel blends

Studies on Lubricity Behaviour of Biodiesel-Diesel Blends

  • Addition of Bio-diesel to diesel / LCO Biodiesel improved the lubricity of diesel and LCO.


Thermoxidative stability of biodiesel diesel blends

Thermoxidative Stability of Biodiesel-Diesel Blends

  • Thermo-oxidative stability of Biodiesel-diesel blends determined by UOP-413 method.

  • Biodiesel reduced the sediments thereby suppressed the aging of fuel.


Thermo oxidative stability of biodiesel diesel blends test method uop 413

Thermo – Oxidative Stability of Biodiesel-diesel Blends (Test Method: UOP-413)


Detrioration of vegetable oils during storage

Detrioration of Vegetable oils during storage

  • Effect of aging on the physico-chemical characteristics of various non-edible vegetable oils were studied over a period of 30 months

  • Similar studies on Bio-diesel are in progress


Variation in acid value of vegetable oils with time

Variation in Acid Value of Vegetable Oils with Time


Current r d programmes on bio diesel

Current R &D Programmes on Bio-diesel

  • Continuous Pilot Plant testing of Heterogeneous Trans-esterification Process

  • Studies to evaluate various vegetable oils for bio-diesel production

  • Performance evaluation of Bio-diesel-Diesel blends in engines and field trials on Indigo cars

  • Effect of bio-diesel on spray characteristics in diesel engines using CFD.

  • Development of additives for Bio-diesel-Diesel blends


Status of technology

Status of Technology

  • Currently IIP is operating batch pilot plants (5-20 lit/ batch) producing biodiesel using base catalyst.

  • Heterogeneous catalyst is being tested in continuous pilot plant.

  • Engine testing of biodiesel and field trials on diesel car is in progress.

  • Developed Sulfur free Multifunctional additives (MFA)for diesel and bio-diesel Diesel blends.


Thank you

Thank you


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