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Electron energy. Allowed Energies. 0 K. Add more heat. Model for a 3-atom solid as harmonic oscillators. n. 7 6 5 4 3 2 1 0. E n = n e = nh n. Energy. D E = 4h n - 3h n = h n. microstate. 2 1 0. Energy. 6 possible microstates. W = 2 Unique states: j=1 j=2. 2 1 0.

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Electron

energy

Allowed

Energies

0 K

Add more heat


Model for a 3-atom solid as harmonic oscillators

n

7

6

5

4

3

2

1

0

En = ne = nhn

Energy

DE = 4hn - 3hn = hn

microstate


2

1

0

Energy

6 possible microstates


W = 2

Unique states: j=1 j=2

2

1

0

Energy

W1 = 3 W2 = 3

W = W1 + W2 = 6 total microstates


7

6

5

4

3

2

1

0

Energy


G1,L

Gsep

GS

G

GL

Gsep,S

Gsep,S

XS

XL

X1

XB


GS

G

GL

C

B

A

XS

XL

X1

XB


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