The chemical water quality of lake nipissing 2003 2004
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The Chemical Water Quality of Lake Nipissing 2003-2004. Andrew Paterson Dorset Environmental Science Centre Environmental Monitoring and Reporting Branch Ontario Ministry of the Environment. Canadian Shield. Ontario’s Inland Lakes. ~260,000 lakes majority on Canadian Shield

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The Chemical Water Quality of Lake Nipissing 2003-2004

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The chemical water quality of lake nipissing 2003 2004

The Chemical Water Quality of Lake Nipissing 2003-2004

Andrew Paterson

Dorset Environmental Science Centre

Environmental Monitoring and Reporting Branch

Ontario Ministry of the Environment


The chemical water quality of lake nipissing 2003 2004

Canadian Shield

Ontario’s Inland Lakes

  • ~260,000 lakes

  • majority on Canadian Shield

  • water quality is generally good

  • ↑ water quality = ↑ value


The chemical water quality of lake nipissing 2003 2004

“A lake is the landscape’s most beautiful and expressive feature.

It is earth’s eye; looking into which the beholder measures the depth of [his] own nature.”

- Henry David Thoreau (Walden)


The chemical water quality of lake nipissing 2003 2004

The economic value of good water quality in Ontario

  • ~2 million adult anglers per year

  • $1.7 billion on goods related to fishing

  • residents own ~1.2 million recreational boats

  • 5.6 million visitors engaged in resource-based tourism

    • (50% participating in water sports, 39% hunting/fishing)

  • $1.1 billion in spending from resource-based tourism

  • commercial fisheries (~$42.5 million)

(Multiple sources, 1998, 1999, 2002, 2003: Min. Natural Resources, Provincial Auditor of Ontario, Min. Tourism and Recreation)


Background

Background

  • In 2002, MOE Northern Region staff submitted a request to the Environmental Monitoring and Reporting Branch (EMRB) to undertake a water quality survey of Lake Nipissing

  • Surveys had been completed in 1971, 1974 and 1975 (no summary report), and 1988, 1989 and 1990 (Neary & Clark 1992)


Background1

Background

  • EMRB staff at Dorset coordinated a volunteer-based sampling program for 2003 and 2004

  • Results of this survey were compiled and compared with the 1988-90 survey in a report co-authored by Clark, Paterson, DeSellas & Ingram (2010)


The chemical water quality of lake nipissing 2003 2004

Clark, Paterson, DeSellas

& Ingram (2010) 57 pp.

Neary & Clark (1992) 66 pp.


The chemical water quality of lake nipissing 2003 2004

49%

45%

5%

Lake Nipissing

~82,200 ha

5

Lake Nipissing and its watershed

Watershed area : Lake area = ~16 : 1


Methods

Methods

  • In 2003-04 water samples were collected from a series of 26 stations that were originally sampled in the early 1970s and again in 1988-90

  • In all 3 surveys, samples were collected during the ice-free season:

    • in 1988-90 by a Dorset field technician monthly

    • in 2003-04 by volunteers on a roughly monthly schedule (3 stations were not sampled and the other stations were sampled 5-12 times)


The chemical water quality of lake nipissing 2003 2004

Lake Nipissing showing the 26 stations that were sampled in 1988-90 and re-sampled in 2003-04 (stations 2, 3 and 18 were not re-sampled). Also note that Cache Bay (#7), Callander Bay (#9) and West Bay (#19) are somewhat isolated from the main body of the lake.


Methods1

Methods

  • Water chemistry from the 1970s and 1988-90 surveys was analyzed by a commercial lab

  • Results from the 2003-04 survey were completed by the MOE water chemistry lab at Dorset

We know that the commercial lab values for total phosphorus were generally lower than the MOE Dorset lab results.


Methods2

Methods

  • A number of water chemistry parameters were measured in the 2003-04 survey including:

    • pH, alkalinity, aluminum, calcium (Ca), chloride (Cl), colour, conductivity, dissolved inorganic carbon, dissolved organic carbon (DOC), iron, potassium, magnesium, manganese, sodium, ammonium (NH4), nitrate/nitrite (NO3), total Kjeldahl nitrogen (TKN), phosphorus (TP), silica, and sulphate (SO4)


Acid rain ph alkalinity sulphate

Acid Rain: pH, alkalinity, sulphate


Nutrients nitrogen phosphorus

Nutrients: Nitrogen & Phosphorus

Results from a whole-lake experiment conducted at the Experimental Lakes Area, near Kenora, ON in 1973

Carbon & Nitrogen only

Barrier

Carbon, Nitrogen

& PHOSPHORUS

Phosphorus is a nutrient that is the limiting factor “controlling” algal growth in aquatic ecosystems


The chemical water quality of lake nipissing 2003 2004

Long-term declines in phosphorus – Dorset A lakes

Regional trend

Relative trends

Average decline in TP = 28%


The chemical water quality of lake nipissing 2003 2004

Large increases in nitrate between 1988-90 and 2003-04


The chemical water quality of lake nipissing 2003 2004

Seasonal nitrate in Callander Bay

1988

2003

1989

2004

1990


Other interesting results

Other interesting results

  • Is road salt affecting the lake?

  • Is dissolved organic carbon (DOC) changing?

  • Are calcium concentrations changing?


Are the lake nipissing biota healthy

Are the Lake Nipissing biota healthy?


Summary

Summary

  • Acid rain: both pH and sulphate (SO4) concentration have decreased

  • Nutrients:

    • Total Kjeldahl nitrogen (TKN) has not changed, but nitrate/nitrite (NO3) and ammonium (NH4) have increased

    • Total phosphorus (TP) has increased, but this may be a lab artefact (levels are lower than the 1970s)


Summary1

Summary

  • Other parameters:

    • Chloride (Cl) has increased

    • Dissolved Organic Carbon (DOC) has not changed

    • Calcium (Ca) has decreased


The chemical water quality of lake nipissing 2003 2004

Thank You

Are there any questions?


Moe north bay office

MOE – North Bay Office

  • District staff proactively inspect municipal STPs to ensure compliance with MOE issued Certificates of Approval. The district also inspects large sub-surface sewage systems that have a flow rate of >10,000 LPD (usually associated with resorts).

  • District staff conduct comprehensive inspections of hazardous waste generators, waste sites and industrial air dischargers, water users taking >50,000 LPD – all to ensure compliance with MOE issued approvals and permits.


Moe north bay office1

MOE – North Bay Office

  • District Environmental Officers respond to spills and other environmental incidents to ensure proper clean-up and compliance with Ontario’s environmental legislation such as the Environmental Protection Act, Ontario Water Resources Act, Pesticides Act.

  • District staff also conduct initial sampling for suspected Blue Green Algae complaints and forward results to the local Health unit for follow up action (if positive)


Moe north bay office2

MOE – North Bay Office

  • District staff conduct spring phosphorus sampling and in some cases dissolved oxygen surveys.

  • MOE also operates a 24 hour spill reporting center – 1-800-268-6060


Nitrogen components

Nitrogen Components

TN = TKN + NO3 = TIN + TON

TKN = TON + NH4

TON = TN – (NO3 + NH4) = TKN – NH4

TIN = NO3 + NH4


Observed changes over time

Observed Changes over Time

* - significant difference at P<0.05


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