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Super critical fluid dyeing

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Super critical fluid dyeing

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  1. Gas Evaporate Curve

  2. Prepared By : Prepared By : Mazadul Hasan sheshir ID: 2010000400008 13thBatch (session 2009-2013) Department : Wet Processing Technology Email: mazadulhasan@yahoo.com Blog : www. Textilelab.blogspot.com (visit) Southeast University Department Of Textile Engineering I/A 251,252 Tejgaon Dhaka Bangladesh

  3. Total Textile Process at a Glance

  4. Introduction The textile industry is believed to be one of the biggest consumers of water. In conventional textile dyeing, large amounts of water are used both in terms of intake of fresh water and disposal of wastewater. On average, an estimated 100–150 litres of water is needed to process 1 kg of textile material, with some 28 billion kilos of textiles being dyed annually. Water is used as a solvent in many pretreatment and finishing processes, such as washing, scouring, bleaching and dyeing. Hence, the elimination of process-water and chemicals would be a real breakthrough for the textile dyeing industry, and it seems this has now come to fruition , with the launch of the world’s first ever industrial dyeing machines that uses super carbon dioxide (CO2) as a replacement for water. The manufacturer behind thissystem is the Dutch company, DyeCooTextile Systems BV. Years of extensiveresearch and development has goneinto producing the novel, completelywater-free dyeing process which hasconsiderable lower operational dyeingprocesses. costscompared to conventional

  5. Principle ‘The principle of dyeing with CO2was invented in Germany twenty-five years ago. Developing a well functioning machine, however, turned out to be too expensive.’ DyeCoo Textile Systems’ parent company, Feyecon, began tackling this issue ten years ago in partnership with the Delft University of Technology and Stork. This ultimately resulted in DyeCoo (which was formed in 2008), which literally means dyeing with CO2.

  6. Different between conventional & supercritical CO2 dyeing

  7. Supercritical Fluid Properties Properties Properties A supercritical fluid is any substance at a temperature and pressure above its critical point, where distinct liquid and gas phases do not exist. It can effuse(spill,shed) through solids like a gas, and dissolve materials like a liquid. In addition, close to the critical point, small changes in pressure or temperature result in large changes in density, allowing many properties of a supercritical fluid to be "fine-tuned". Supercritical fluids are suitable as a substitute for organicsolvents in a range of industrial and laboratory processes. Carbon dioxide and water are the most commonly used supercritical fluids, being used for decaffeination and power generation, respectively. Critical properties of various solvents Molecular weight g/mol 44.01 18.015 Critical temperature K 304.1 647.096 Critical pressure MPa (atm) 7.38 (72.8) 22.064 (217.755) 4.60 (45.4) 4.87 (48.1) 4.25 (41.9) 5.04 (49.7) 4.60 (45.4) 8.09 (79.8) 6.14 (60.6) 4.70 (46.4) Critical density g/cm3 0.469 0.322 Solvent Carbon dioxide (CO2) Water (H2O) (acc. IAPWS) Methane (CH4) Ethane (C2H6) Propane (C3H8) Ethylene (C2H4) Propylene (C3H6) Methanol (CH3OH) Ethanol (C2H5OH) Acetone (C3H6O) 16.04 30.07 44.09 28.05 42.08 32.04 46.07 58.08 190.4 305.3 369.8 282.4 364.9 512.6 513.9 508.1 0.162 0.203 0.217 0.215 0.232 0.272 0.276 0.278

  8. shows density, diffusivity and viscosity for typical liquids, gases and supercritical fluids Comparison of Gases, Supercritical Fluids and Liquids Density (kg/m3) Gases 1 Supercritical Fluids Liquids 1000 In addition, there are: No surface tension in a supercritical fluid No liquid/gas phase boundary By changing the pressure and temperature of the fluid, can be "tuned" to be more liquid- or more gas Soluble in material in the fluid Solubility in a supercritical fluid tends to increase with density of the fluid (at constant temperature) Density increases with pressure, solubility tends to increase with pressure Relationship with temperature is a little more complicated At constant density, solubility will increase with temperature All supercritical fluids are completely miscible with each other so for a mixture a single phase can be guaranteed if the critical point of the mixture is exceeded. The critical point of a binary mixture can be estimated as the arithmetic mean of the critical temperatures and pressures of the two components, Tc(mix)= (mole fraction A) x TcA + (mole fraction B) x TcB. For greater accuracy, the critical point can be calculated using equations of state, such as the Peng Robinson, or group contribution methods. Other properties, such as density, can also be calculated using equations of state. Viscosity (µPa∙s) 10 50–100 Diffusivity (mm²/s) 1–10 0.01–0.1 100–1000 500–1000 0.001 • • • • • • • •

  9. Supercritical Carbon Dioxide(CO2) Carbon dioxide is a readily available, cheap, recyclable and is non-toxic and non- flammable. Above the temperature of 31.6 oC and pressure of 73 atm carbon dioxide exhibits physical properties, which are intermediate between those of gases and liquids. These conditions are called supercritical conditions and are readily achievable using commercially available equipment. Supercritical carbon dioxide is able to dissolve a range of chemical substances including organic substrates, catalysts, and light gases. Its main advantage however comes from the fact that this solvent can be easily turned into a gas by simply releasing the pressure leaving no solvent residues and requiring no evaporation or separation. Benefits •Applied a clean solvent •Improved control and fine-tuning of process •Developed a remarkably selective synthetic process •Minimised waste & Increased atom utilization •Minimised handling and purification procedures

  10. Supercritical Carbon Dioxide(CO2) Properties •Low cost •Non-Toxic •Density: liquid •Viscosity: Gas •Recycling up to 90% •Inert •Non-explosive •Low critical point •Pressure: 73.858 ± 0.005 bar •Temperature: 31.05 ± 0.05 ºC

  11. Supercritical Carbon Dioxide(CO2) Phase diagram Figure: CO2pressure-temperature & density-pressure phase diagram

  12. Investigation of Dye-Fiber Reactions in SC-CO2 Chemistry of Dyes •Reactive dyes for cotton, rayon, silk, and wool form stable chemical links with textile materials to produce colored fabrics with excellent overall fastness, other dyestuffs only form loose bonds with fibers (VS-dye) •Acetate, nylon, and polyester fibers colored with dispersed dyes retain their color even after repeated exposure to sunlight and washing (ES-dye) Conventional aqueous-based dye-fiber reaction

  13. Investigation of Dye-Fiber Reactions in SC-CO2 Dye-Fiber Reaction in SC CO2 Sulfonyl-azo-dyes

  14. Dyeing Procedure Dyeing Procedure 1. Add fiber and dye to vessel 2. Pressurize system (with CO2) up to 800 psi and stir at approximately 850 rpm 3. Heat to required temperature (100 -180 ºC) 4. Pressurize to 3500 psi; hold for 2 hours 5. Release pressure, remove fabric

  15. Dyeing Procedure CO2Dyeing System (1) Gas cylinder of CO2, (2) High pressure pump, (3) Autoclave reactor vessel with stirrer, V = 1000 ml, (4) Circulation pump- acquisition in future (5) Electrical heating jacket 3 5 2 1 4

  16. Dyeing Procedure High Pressure Batch Reactor

  17. Dyeing Procedure Testing Dye-Fiber Reaction •Measure color strength (K/S) of each dyed fiber •Wash fiber with acetone (remove surface dye) •Conduct soxhlet extraction using ethyl acetate (to remove unreacted dye) •Compare effect of vinylsulfone reactive group on dye fixation Results

  18. Dyeing Procedure Comparison of Dyed Fabrics

  19. Dyeing Procedure Initial Conclusions •Color depth improved with increasing temperature •Strong evidence for dye-fiber bond formation using vinylsulfone-based dye on nylon and wool •ES-dyeing on wool fibers showed extremely low color yields after extraction (no reaction) •94% fixation at 180oC/ 3500 psi on wool

  20. Dyeing Procedure Dyeing polyester with disperse dyes in supercritical CO2 Supercritical fluids are highly compressed gases which possess valuable properties of both a liquid and gas. Any gas above its critical temperature retains the free mobility of the gaseous state but with increasing pressure its density will increase towards that of a liquid. The properties which are intermediate between gases and liquids are controlled by pressure. Other attributes of carbon dioxide are •It is virtually an inexhaustible resource (atmosphere, combustion processes, and natural geologic deposits). •It is not only biodegradable as a nutrient promoting the growth of plants, but is an essential element of natural processes. •It does not affect the edibility of foodstuffs and will only have toxic effects at extremely high concentrations. •It has no disposal problems. It is recovered from the process in the form of an uncontaminated gas and can be reused. •It is easy to handle and combustible. •It has a critical point within the range which is readily manageable by technical means (31C and 73 bar). •It is non-toxic, non-hazardous and low cost. •It is nonflammable and non-corrosive.

  21. Dyeing Procedure Advantage No waste water (problem in textile industry) No require additives No final drying Recycling Solvent Colorants Environmental friendly Both economic and ecological Having a low critical temperature Disadvantage Investment Solve colorants Time of process

  22. Dyeing Procedure Dyeing of polyester Supercritical CO2dyeings were performed using an SFE 400 supplied by SUPELCO, equipped with a 50 cm3internal volume vessel. The operating pressure could be set up to 6000 psi, managed in 100 psi increments. The oven temperature range (30 2000C) was controlled at 100C increments. The polyester fabrics (1 g) were suspended on a stainless steel net inside the vessel and the solid, pure dye was placed on the bottom of the vessel. A ratio of 1.5% dye omf was used. When the system reached the desired temperature and pressure, the liquid was let into the vessel. After 30 min under constant conditions, the system was expanded to atmospheric pressure and the dry samples were removed. Dyeings in aqueous medium were produced also in which polyester samples were dyed in a thermostatted bath (Linitest) using a 40:1 liquor ratio, at 1200C for 1 h (1.5% omf pure dye, 0.25% omf Na2SO4, 0.5% omfDispersogen-A, 40% omfLenol- O); Dispersogen-A and Lenol-O were Hoechst auxiliary products. 2.4.

  23. Dyeing Procedure Dyeing with CO2 “When carbon dioxide is heated to above 31 C and pressurised to above 74 bar, it becomes supercritical, a state of matter that can be seen as an expanded liquid, or a heavily compressed gas. In short, above the critical point, carbon dioxide has properties of both a liquid and a gas. In this way supercritical CO2, has liquid-like densities, which is advantageous for dissolving hydrophobic dyes, and gas-like low viscosities and diffusion properties, which can lead to shorter dyeing times compared to water. Compared to water dyeing, the extraction of spinning oils, the dyeing and the removal of excess dye can all be carried out in one plant in the carbon dioxide dyeing process which involves only changing the temperature and pressure conditions; drying is not required because at the end of the process CO2 is released in the gaseous state. The CO2 can be recycled easily, up to 90% after precipitation of the extracted matter in a separator.” To read more about supercritical fluid dyeing technology.

  24. Dyeing Procedure Fastness assessment 1. Wet fastness was determined according to UNI 7638 (ISO 105-C 01/03/04). 2. For the determination of fastness to artificial light, a Xenotest Hanau 150S (Heraeus) 3. apparatus was employed, equipped with a 1500 W xenon arc lamp, 4. according to UNI 7639 (ISO 105-B02).

  25. Dyeing Procedure Dyeing Conditions Extraction vessel: 40 Liter Fiber: 4 PET Packages Dye: C.1. Disperse Blue 79 Pressure: 4200 psi Temperature: 120ºC CO2 Recirculation: 5 Kgs/min Dye time: 40 minutes

  26. Results The results show that the concentration of dye absorbed by the fibre increased initially on increasing the pressure to 3500 psi, but was practically constant between 3500 and 4000 psi. Similar results were obtained when the study was carried out at 100 and 1200C. The data reported in Fig. 1. Variations in dye uptake (Df) by the fibre as a function of pressure at constant temp(800C).

  27. Table 1 Variation in dye uptake by the fibre as a function of pressure at constant temp (1000C) Fiber from the dyed packages was woven into a “sock” and evaluated for uniformity.

  28. Problems with Conventional Water-Dyeing Machine Problems 1.In conventional method of dyeing textiles undergo multiple processes. 2. In these processes water, dyes, and other auxiliaries are used to enhance the efficiency of dyeing process. 3. After dyeing a subsequent drying process with high energy consumption is necessary. 4.The cost of waste water treatment and of arranging water of acceptable quality is becoming serious concerns. Either the water available is too hard or not available in sufficient amount or therefore dyeing plants cannot be set up at some places. 5.By using scCO2dyeing machine we can overcome all these problems of conventional machine.

  29. Advantages of scCO2Dyeing Machine 1. Elimination of usage of water, water treatment and water pollution 2. Elimination of a drying step, thus reduces energy cost 3. Elimination of auxiliaries, such as, dispersing agent, leveling agent 4. Rapid diffusion and potential for high degree of dye exhaustions 5. Dyeing occurs with high degree of levelness 6. No after treatment is required 7. Time required for dyeing is very less 8. Gives good rubbing fastness 9. Dyeing houses may be started on sites where there is water scarcity 10. No air pollution due to recycling of CO2is accomplished 11. Economical and environmentally friendly.

  30. Disadvantages/Limitations 1. Initial investment is high. 2. High pressure and high temperature are required for dye solubility during the process. 3. It is a batch process. So processing of long length fabric (continuous) is not possible. 4. During polyester dyeing, the trimer is produced. This is removed using aqueous cleaning waterless scCO2as a problem to eliminate. 5. There is little data available about dyestuff solubility in scCO2. 6. At present, scCO2dyeing is confined to synthetic fibers.

  31. Benefits of scCO2M/C over Conventional M/C: An Overall Comparison Conventional Water-Dyeing High volume of water required Produces huge effluent Wastage of valuable dyestuffs Requires huge chemicals and auxiliaries High energy requirements Dyeing in Supercritical CO2 Completely avoids the use of water No waste water at all Unreacted dye remains as powder No need for dispersing and leveling agents Requires only 20% energy of conventional dyeing Only 2 to 2.5 hours per batch Dyeing, washing and drying times are 3-4 hours per batch Drying is required after dyeing process Not required as CO2is released in gaseous state No after treatment is required. CO2can be easily recycled upto 95% After treatment is a compulsory step Water treatment (ETP) and recycling is difficult and costly Dyeing factory need to establish where water is sufficiently available Overall cost comparing to scCO2is high Dyeing factory can be established where water is not available Machine cost is high

  32. Challenges The machine is not suitable for dyeing natural (hydrophilic) fibers in its current arrangement. For natural fibers the diffusion of scCO2is hampered by its inability to break the hydrogen bonds present in many natural fibers, including cotton, wool and silk. A further problem is that reactive dyes, direct dyes and acid dyes which are suitable for dyeing of natural fibers are insoluble in scCO2and also dye may be damaged at such high pressure and temperature. However, Investigators are trying to find out a solution for dyeing natural fibers in scCO2. Some possible approaches are chemically treating/modifying the fiber before dyeing or using improved dyestuffs, such as, disperse reactive dye.

  33. How we will be benefited? We can take all the advantages mentioned above if we go forward with this machine. It will reduce the usage of chemicals & auxiliaries, dyeing time, waste-water treatment cost and ultimately saves the capital. It will also save the environment. Again this will improve the company’s reputation and increases the future possibilities to get potential/more orders.

  34. Present situation 1. At this moment, the scCO2dyeing machine is only suitable for open-width dyeing of scoured polyester fabric with disperse dyes. 2. DyeCooin cooperation with another dye manufacturer Triade, are producing, marketing and distributing specially developed disperse dyes for this machine under the CooDye brand name. 3. Nike, the global sportswear giant, has entered into a strategic partnership with DyeCooin order to produce textiles dyed without water. 4. Yeh group dyeing the fabrics with this machine branded as DryDye™ Fabrics.

  35. Comparative Energy Requirements* (kJ): Conventional scCO2 Pretreatment 4555 4555 Dyeing 45250 30625 Post Treatment 3800 0 Total 53605 35180 Energy Savings 34.37%

  36. Supercritical fluid processing Machine

  37. Production machine The final partner of DyeCoo to make history is Tong Siang Co. Ltd (Thailand), part of the Yeh Group. The polyester textile producer will become the first textile mill to implement the commercial-scale supercritical fluid CO2machine into production, branding the process as DryDye. Supercritical fluid CO2enables polyester to be dyed with modified disperse dyes. It causes the polymer fibre to swell, allowing the disperse dye to diffuse and penetrate the pore and capillary structure of the fibres. The viscosity of the dye solution is lower, making the circulation of the dye solutions easier and less energy intensive. This deep penetration also provides effective coloration of polymers. Furthermore, dyeing and removing excess dye can be carried out in the same vessel; and residue dye is minimal and may be extracted and recycled. Currently, the process is limited to dyeing of scoured polyester fabric run in batches of 100–150 kg, although DyeCoo and its partners are developing reactive dyes for cellulosics to be available for use in this process in the not too distant future.

  38. Super-critical Dyeing and Treatment Supercritical dyeing using supercritical CO2, the ideal dyeing technology that uses no water at all. No wastewater, environmentally friendly, futuristic dyeing technology. HISAKA has built the largest dyeing equipment in the world, envisioned for actual production. Not only CO2supercritical technology dyes, but also washing and additional functions are among the special treatment uses we expect to see.

  39. http://www.textilelab.blogspot.com (Visit My Blog for more Info ) My Facebook Textile related Pages 1. Yarn Manufacturing Technology Link : http://www.facebook.com/pages/Yarn-Manufacturing-Technology/485014954866808 2. Fabric Manufacturing Technology Link : http://www.facebook.com/pages/Fabric-Manufacturing-Technology/459520217425605 3. Garments Manufacturing Technology Link : http://www.facebook.com/pages/Garments-Manufacturing- Technology/472364799463126 3. Wet processing Technology Link : http://www.facebook.com/pages/Wet-Processing-Technology-Dyeing-/468645219825404 4. Fashion-Design-and-Technology Link : http://www.facebook.com/pages/Fashion-Design-and- Technology/587655294583875?ref=ts&fref=ts

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