CHAPTER 6  Properties and Reactions of Haloalkanes:   Bimolecular Nucleophilic Substitution

CHAPTER 6 Properties and Reactions of Haloalkanes: Bimolecular Nucleophilic Substitution PowerPoint PPT Presentation


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Physical Properties of Haloalkanes. 6-1. The bond strength of C-X decreases as the size of X increases.A halogen uses a p orbital to overlap an sp2 orbital on a carbon atom.As the size of the halogen p orbital increases (F < Cl < Br < I), the percentage overlap with the smaller sp2 carbon orbital is less and the bond strength decreases..

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CHAPTER 6 Properties and Reactions of Haloalkanes: Bimolecular Nucleophilic Substitution

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1. CHAPTER 6 Properties and Reactions of Haloalkanes: Bimolecular Nucleophilic Substitution

2. Physical Properties of Haloalkanes

5. Nucleophilic Substitution

6. Nucleophilic Substitution

10. Reaction Mechanisms Involving Polar Functional Groups: Using “Electron-Pushing” Arrows

12. A Closer Look at the Nucleophilic Substitution Mechanism: Kinetics

13. A Closer Look at the Nucleophilic Substitution Mechanism: Kinetics

17. Frontside or Backside Attack? Stereochemistry of the SN2 Reaction

20. Consequences of Inversion in SN2 Reactions

23. Structure and SN2 Reactivity: The Leaving Group

26. Structure and SN2 Reactivity: The Nucleophile

40. Structure and SN2 Reactivity: The Substrate

46. Important Concepts

47. Important Concepts

48. Important Concepts

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