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Reactions of Enols and Enolates

Reactions of Enols and Enolates

Reactions of Enols and Enolates. Ketones and aldehydes are in equilibrium with a small amount of the corresponding enol . This can be problematic, if one desires to produce a stereogenic center a to a C=O.

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Reactions of Enols and Enolates

Reactions of Enols and Enolates

Reactions of Enols and Enolates. The Aldol Condensation Reaction. Ketone Enolate + Aldehyde. Intramolecular Aldol. Ester Enolate + Aldehyde. Ester Enolate + Ester = Claisen Condensation. Intramolecular Claisen Condensation = Dieckmann Condensation.

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The Aldol Condensation

The Aldol Condensation

The Aldol Condensation. In the presence of a strong base, two molecules of aldehyde or ketone may combine to form a b -hydroxyaldehyde or a b -hydroxyketone . This reaction is called the aldol condensation . The Aldol Condensation. Example. Another Example. One More:.

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1.07k views • 36 slides
The Aldol Condensation

The Aldol Condensation

The Aldol Condensation. In the presence of a strong base, two molecules of aldehyde or ketone may combine to form a b -hydroxyaldehyde or a b -hydroxyketone . This reaction is called the aldol condensation . The Aldol Condensation. Example. Another Example. One More:.

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835 views • 36 slides
The Aldol Condensation

The Aldol Condensation

The Aldol Condensation. In the presence of a strong base, two molecules of aldehyde or ketone may combine to form a b -hydroxyaldehyde or a b -hydroxyketone . This reaction is called the aldol condensation . The Aldol Condensation. Example. Another Example. One More:.

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1.35k views • 36 slides
Reactions of Enols and Enolates

Reactions of Enols and Enolates

Reactions of Enols and Enolates. The Aldol Condensation Reaction.

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284 views • 18 slides

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