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Coordination Chemistry II

Coordination Chemistry II

Coordination Chemistry II. Bonding, including crystal field theory and ligand field theory. Basis for Bonding Theories.

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2.39k views • 77 slides
Interplay between spin, charge, lattice and orbital degrees of freedom

Interplay between spin, charge, lattice and orbital degrees of freedom

Interplay between spin, charge, lattice and orbital degrees of freedom. Lecture notes Les Houches June 2006 lecture 3 George Sawatzky. Need multiband models to describe TM compounds.

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672 views • 47 slides
Coordination Chemistry Bonding in transition-metal complexes

Coordination Chemistry Bonding in transition-metal complexes

Coordination Chemistry Bonding in transition-metal complexes. Crystal field theory: an electrostatic model. The metal ion will be positive and therefore attract the negatively charged ligands. But there are electrons in the metal orbitals, which will experience repulsions

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1.07k views • 45 slides
Orbitals and energetics

Orbitals and energetics

Orbitals and energetics. Molecular symmetry Bonding and structure Molecular orbital theory Crystal field theory Ligand field theory Provide fundamental understanding of chemistry dictating radionuclide complexes Structure based on bonding Coordination important in defining structure

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572 views • 31 slides
Ligand Field Theory

Ligand Field Theory

Ligand Field Theory. Ligand Field Thoery (aka Crystal Field Theory) assumes that the only interaction between the metal and the ligands is purely ionic. Imagine the five d-orbitals in an isolated metal ion; energetically degenerate.

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9.43k views • 27 slides
Transition Metal Oxide Perovskites: Band Structure, Electrical and Magnetic Properties

Transition Metal Oxide Perovskites: Band Structure, Electrical and Magnetic Properties

Transition Metal Oxide Perovskites: Band Structure, Electrical and Magnetic Properties. Chemistry 754 Solid State Chemistry Lecture #24 May 27, 2003. Transition Metal Oxides.

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3.5k views • 19 slides
Comparing magnetic Sr M O 3 perovskites M= 3d vs. 4d

Comparing magnetic Sr M O 3 perovskites M= 3d vs. 4d

Comparing magnetic Sr M O 3 perovskites M= 3d vs. 4d. Leo Lamontagne MTRL 286G 6/2/2014. 3d vs. 4d magnetism. 3d: Smaller bandwidth leads to stoner instabilities Stronger correlation between electrons 4d: Greater orbital overlap gives more disperse bands

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356 views • 14 slides
MCE for Traders CWG/MCWG ERCOT Public October 30 2013

MCE for Traders CWG/MCWG ERCOT Public October 30 2013

MCE for Traders CWG/MCWG ERCOT Public October 30 2013. MCE for Traders. At its September 25, 2013 meeting CWG/MCWG requested ERCOT staff to return with a proposal for financial MCE for non-load/generation Counter-Parties.

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184 views • 5 slides

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