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1.7. OXYGEN VERSUS CARBON AS THE SITE OF ALKYLATION

1.7. OXYGEN VERSUS CARBON AS THE SITE OF ALKYLATION. Enolate anions are ambident nucleophiles. Alkylation of an enolate can occur at either carbon or oxygen. Most of the negative charge of the enolate is on the oxygen atom, so it might be supposed that O-alkylation would dominate.

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1.7. OXYGEN VERSUS CARBON AS THE SITE OF ALKYLATION