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Chem 1310: Introduction to physical chemistry Part 5: Buffers and solubility

Chem 1310: Introduction to physical chemistry Part 5: Buffers and solubility

Chem 1310: Introduction to physical chemistry Part 5: Buffers and solubility. Peter H.M. Budzelaar. Buffers. Water has a very small [H 3 O + ] (10 -7 ). Adding just a little bit of acid or base can change the pH drastically. Add 0.001 M HCl: pH goes from 7 to 3!

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510 views • 21 slides
OrganoLithium Compounds

OrganoLithium Compounds

OrganoLithium Compounds. Peter H.M. Budzelaar. Organo-lithium compounds. Ionic character, electron-deficient oligomeric or polymeric structures Strongly basic and nucleophilic applications in organic synthesis Reducing unwanted side reactions. Organo Na, K compounds. "Purely" ionic

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1.22k views • 20 slides
OrganoMagnesium Compounds

OrganoMagnesium Compounds

OrganoMagnesium Compounds. Peter H.M. Budzelaar. Organo-Mg and Be compounds. Like Organolithium compounds, but milder : Ionic character, electron-deficient oligomeric or polymeric structures Basic and nucleophilic Mg: applications in organic synthesis (Grignard reagents !)

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1.26k views • 14 slides
Recombination of an Fe-Si-P Linkage to an Fe-P-Si Linkage through an Isolable Intermediate Phosphasilaferracyclopropane

Recombination of an Fe-Si-P Linkage to an Fe-P-Si Linkage through an Isolable Intermediate Phosphasilaferracyclopropane

Recombination of an Fe-Si-P Linkage to an Fe-P-Si Linkage through an Isolable Intermediate Phosphasilaferracyclopropane. Okazaki, M.; Yoshitomo, T.; Naito, J.; Sato, A.; Komuro, T.; Tobita, H. J. Am. Chem. Soc. 2008 , 130 , 17674-17675. Peter H.M. Budzelaar. Recombination . What happens ?

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309 views • 12 slides

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