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Conjugate addition - PowerPoint PPT Presentation

Chapter 9

Chapter 9. Aldehydes and Ketones: Nucleophilic Addition Reactions. Chemistry of the Carbonyl Group. O Carbonyl group , ? C ?, (C=O). O Acyl group, R ? C ?, (-COR). Carbonyl compounds can be classified into two categories:.

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18.11 Effects of Conjugation in a,b -Unsaturated Aldehydes and Ketones

18.11 Effects of Conjugation in a,b -Unsaturated Aldehydes and Ketones. Relative Stability. aldehydes and ketones that contain a carbon-carbon double bond are more stable when the double bond is conjugated with the carbonyl group than when it is not

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CONJUGATE ADDITION

CONJUGATE ADDITION. MICHAEL ADDITION. Addition of Nucleophiles to Enones Conjugate Addition or Michael Addition. -. -. :. :. :. :. :. +. +. :Nu. :Nu. 1,2-addition. 1,4-addition. Nu. conjugate addition. Nu. CONJUGATE ADDITION. -. :. :. :. -. H-OH. :.

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Conjugate addition - PowerPoint PPT Presentation

Chapter 9

18.11 Effects of Conjugation in a,b -Unsaturated Aldehydes and Ketones

CONJUGATE ADDITION