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Activating Catalysts with Mechanical Force

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Activating Catalysts with Mechanical Force - PowerPoint PPT Presentation


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Activating Catalysts with Mechanical Force. 1a : 3 mM , 6 o C , 60 min, conversion : 65 % (sonication) 1a : 3 mM , 6 o C 60 min, conversion : 3 % (without sonication) 1a : 0.6 mM , 95 o C , 45 min, conversion : 28%. Room temperature : no reaction 80 o C , 60 min, conversion : 94%.

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slide4

1a : 3 mM , 6 oC , 60 min, conversion : 65 % (sonication)

1a : 3 mM , 6 oC60 min, conversion : 3 % (without sonication)

1a : 0.6 mM , 95 oC ,45 min, conversion : 28%

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Room temperature : no reaction

80 oC ,60 min, conversion : 94%

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6a : 1 mM , 20 oC , 60 min, conversion : 14%

6b : 1 mM , 20 oC 60 min, conversion : 36%

7 : 1 mM , 20 oC , 150 min, conversion <1%

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1 mM 6c 20 oC (sonication) conversion : 90%

1 mM 6c 20 oC (no sonication) conversion : 2%

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