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1 1 1 2 2 1 2 2 2 3

  • 1-1

    1-2

  • 2-1

    2-2

    2-3


1 1 1 2 2 1 2 2 2 3

.

/


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

.

1

15%

>5%1015

60/


1 1 1 2 2 1 2 2 2 3

1

1-1


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

1-2

  • PS

    Q


1 1 1 2 2 1 2 2 2 3

  • /

W1

W2

Q


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

Q

  • Q1 1

V1

1


1 1 3

1-1-3

1.


1 1 1 2 2 1 2 2 2 3

2.

1

PEIPP

(2)

  • HDPE( 135oC)120oCPP 134oCPP

    180oC)130oC


1 1 1 2 2 1 2 2 2 3

3.

PA

PET

  • 4H2SO4

    60%PET


1 1 1 2 2 1 2 2 2 3

1-2


1 2 1

1-2-1

PS

PMMA

PVA()

PANDMF


1 2 2

1-2-2

1.


1 1 1 2 2 1 2 2 2 3

  • <0

  • >0 T


2 hildebrand

2.Hildebrand

  • >0

VM


1 1 1 2 2 1 2 2 2 3

  • Hildebrand


1 1 1 2 2 1 2 2 2 3

3.

  • (1)Clapeyron-

    Clausius


1 1 1 2 2 1 2 2 2 3

3.

  • 2


1 1 1 2 2 1 2 2 2 3

A


1 1 1 2 2 1 2 2 2 3

B.

Q


1 1 1 2 2 1 2 2 2 3

V

M0

C.FF

E E


1 1 1 2 2 1 2 2 2 3

  • A

    B

    A

    B


1 1 1 2 2 1 2 2 2 3

  • Hildebrand

  • Hildebrand

    PANPAN

    PSPS


Thermodynamics of polymer solution

Thermodynamics of Polymer Solution

  • 2-1

  • 2-2

  • 2-3


1 1 1 2 2 1 2 2 2 3

2-1


1 1 1 2 2 1 2 2 2 3

  • 1

    2

    3

    4


1 1 1 2 2 1 2 2 2 3

+


1 1 1 2 2 1 2 2 2 3

2-2

  • >


1 1 1 2 2 1 2 2 2 3

2-3

  • 2-3-1 Flory-Huggins

    FloryHuggins


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

  • xx

    x


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

  • x x

    ()< ()< x


1 1 1 2 2 1 2 2 2 3

  • 0


1 1 1 2 2 1 2 2 2 3

.

1 2

  • 1-1 2-2 21-2

  • 1/2 1-1 2-2 1-2


1 1 1 2 2 1 2 2 2 3

  • -

  • -

  • -

  • -

  • -

    Huggins

    -


1 1 1 2 2 1 2 2 2 3

  • -11


1 1 1 2 2 1 2 2 2 3

.

Flory-Huggins


1 1 1 2 2 1 2 2 2 3

.

G


1 1 1 2 2 1 2 2 2 3

.


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

  • Flory-Huggins50FloryHuggins


2 3 2 flory huggins

2-3-2 Flory-Huggins

  • FloryHuggins


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

T

T


1 1 1 2 2 1 2 2 2 3

  • Flory-HugginsFlory


3 1 plasticization

3-1 plasticization

  • 1

  • plasticizer

  • PVC3050


1 1 1 2 2 1 2 2 2 3

  • 2


1 1 1 2 2 1 2 2 2 3


1 1 1 2 2 1 2 2 2 3

  • 3

  • -

  • -

    n


1 1 1 2 2 1 2 2 2 3

3-2

  • 1


1 1 1 2 2 1 2 2 2 3

  • 2


1 1 1 2 2 1 2 2 2 3


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