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热力学 PowerPoint PPT Presentation


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第二篇 热学. 一、热学的研究对象 热现象与热运动,以及热运动与其它运动形式之间相互转换所遵循的规律。 热运动是热现象的微观本质 , 热现象是热运动的宏观表现。. 二、热学的主要内容:. 气体动理论. (微观角度,统计原理). 宏观量与微观量的关系. 热力学. (能量角度). 热功转换的关系及条件. 第六章 气体动理论. 基本内容: 理想气体状态方程 压强和温度的微观解释; 能量按自由度均分原理,理想气体的内能; 麦克斯韦速率分布律;. 斥力. r 0. r. O.

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热力学

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6337098


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r0

r

O

6.1

1

(10-7m310-10m)

2

3


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1

2


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PVT

1(V):

2(P)

Pa

3(T)

T ( K )

01atm1mol22.4


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6.2

1-

2

1

2

3


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1

P0V0T01mol


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(1)MPVT

MVPT

MTPV

(2)

2

-


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3

VT


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[1] 3105Pa27C0.24kg/m3

T=273+27=300K


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=

P

nkT

[2] 1cm3

P=1.013105PaT=273.15K


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6.3

1

(1)

(2)

16


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y

S1

c

S2

mvix

i

x

b

-mvix

a

z

2

x S1

Pix=-mvix-mvix=-2mvix

S12mvix

S1

S1:

S1S1:


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NxS1

NS1


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(1) P n

(2) Pn

1

1

=

+

+

=

+

+

2

2

P

p

p

n

m

v

n

m

v

L

L

1

2

1

1

1

2

2

2

3

3

(3)n1n2 ......


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:

1

2


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[3] 1eV

:T

[4] P1P2?

n1=n2T1T2

PnkT

P1P2


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6.4

1

2

3()


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M

1

l

M

2

1

M ( x,y,z )

3

M1(x1y1z1)M2(x2y2z2 )

65

5


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z

P

G

o

y

x

3

3

2

Gxyz

GP

GP

6

6


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3

0

3

5

2

3

6

3

3

( )

3 i

(He)

(H2O2N2)

(H2O)


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T


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T

:


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T

T

T

Ti

T1mol

T

KR


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[5]?

?

H21He 2

1 =21 = 2 1 = 2 = 1

11 = 22

1 = 52 = 3

MM1= M2 =M=1kg


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[6]10cm3T=300K510-6 mmHg1760 mmHg

N32

P = nkT = NkTV N=PVkT =1.611012


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6.5

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x

x

N

x

x

x

+

X


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(m/s)

100

1.4 %

1859

1920

100~200

8.1 %

200~300

16.5 %

300~400

21.4 %

400~500

20.6 %

500~600

15.1 %

600~700

9.2 %

700~800

4.8 %

800~900

2.0 %

900

0.9 %


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dN

N,

fv

vv


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Maxwell

1859Maxwell

vvdvdNN

1

TmkT,m

Maxwell

Maxwell

2


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f

(v)

dN

f (v)=

N

dv

v

v

dv

1fv:

vv+dv


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212

0

3

f(v)Tm.


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f (v)

f (v)

T

m

m

T

0

v

v

0

1

fvVp


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2

3


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f (v)

o

v

v

v

v

p

2

v

v

v

2

p


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7fvMaxwellvpn

0vp

vvdv


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v1v2

v1v2v1v2

N1v1v2N


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f

(v)

vp

v

8


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