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More Acid/Base Equilibria !!! 17.1 – 17.3. 17.1 The Common Ion Effect Consider the ionization of a weak acid, acetic acid: HC 2 H 3 O 2 ( aq )  H + ( aq ) + C 2 H 3 O 2 – ( aq )

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More Acid/Base Equilibria !!! 17.1 – 17.3

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More acid base equilibria 17 1 17 3

More Acid/Base Equilibria!!!17.1 – 17.3


More acid base equilibria 17 1 17 3

17.1 The Common Ion Effect

Consider the ionization of a weak acid, acetic acid: HC2H3O2(aq)  H+(aq) + C2H3O2–(aq)

If we increase the [C2H3O2–] ions by adding NaC2H3O2, the equilibrium will shift to the left. (Le Chatelier)

This reduces the [H+] and raises the pH (less acidic)

This phenomenon is called the common-ion effect.

Common ion equilibrium problems are solved following the same pattern as other equilibrium problems (ICE charts) EXCEPT the initial concentration of the common ion must be considered (it is NOT zero).


More acid base equilibria 17 1 17 3

Example 1:Does the pH increase, decrease, or stay the same on addition of each of the following?

(a) NaNO2 to a solution of HNO2

(b) (CH3NH3)Cl to a solution of CH3NH2

(c) sodium formate to a solution of formic acid

(d) potassium bromide to a solution of hydrobromic acid

(e) HCl to a solution of NaC2H3O2

  • HNO2 H+ + NO2-

    increases

  • CH3NH2 + H2O  CH3NH3+ + OH-

    decreases

  • HCHO2 H+ + CHO2-

    increases

    (d) HBr H+ + Br-

    no change

    (e) C2H3O2-1 + H2O  HC2H3O2 + OH-1

    decreases


More acid base equilibria 17 1 17 3

Example 2: Using equilibrium constants from Appendix D, calculate the pH of the solution containing 0.060 M KC3H5O2 and 0.085 M HC3H5O2

change:-x+x+x

Equilibrium:0.085-xx .060+ x

x2+.060013x-(1.105*10-6)=0

x=1.84*10-5

pH = -log(1.84*10-5) = 4.74


More acid base equilibria 17 1 17 3

17. 2 Buffered Solutions

A buffered solution or buffer is a solution that resists a change in pH after addition of small amounts of strong acid or strong base.

A buffer consists of a mixture of a weak acid (HX) and its conjugate base (X– ) or weak base (B) and its conjugate acid (HB+)

Thus a buffer contains both:

an acidic species to neutralize added OH–

When a small amount of OH– is added to the buffer solution, the OH– reacts with the acid in the buffer solution.

a basic species to neutralize added H+

When a small amount of H+ is added to the buffer solution, the H+ reacts with the base in the buffer solution.


More acid base equilibria 17 1 17 3

Composition of a Buffer - 4 ways to make a buffer solution:

1.)Weak acid + salt of the acid

HCN and NaCN

weak acid: HCN weak base: CN-1

2.)Weak base + salt of the base

NH3 and NH4Cl

weak acid: NH4+1 weak base: NH3

3.) EXCESSWeak acid + strong base

2 mol HCN + 1 molNaOH 1 molHCN + 1 molNaCN + H2O

weak acid: HCN weak base: CN-1

2 mol NH4Cl + 1 molNaOH 1 molNH4Cl + 1 molNH3+ NaCl

weak acid: NH4+1 weak base: NH3

4.)EXCESS Weak base + strong acid

2 mol NH3 + 1 molHCl 1 molNH3 and 1 molNH4Cl

weak acid: NH4+1 weak base: NH3

2 molNaF + 1 molHCl 1 molNaF + 1 mole HF + NaCl

weak acid: HF weak base: F-1


More acid base equilibria 17 1 17 3

Example 3: Explain why a mixture of HCl and KCl does not function as a buffer, whereas a mixture of HC2H3O2 and NaC2H3O2 does.

HCl is a strong acid - Cl-1 is a negligible base and will NOT react with added H+ - added H+will significantly change the pH of the solution

HC2H3O2 and C2H3O2-1 are a weak conjugate acid/base pair which act as a buffer

HC2H3O2 reacts with added base

C2H3O2-1 reacts with added acid

leaving the [H+1] and pH relatively unchanged


More acid base equilibria 17 1 17 3

Buffer Capacity and pH

Buffer capacityis the amount of acid or base that can be neutralized by the buffer before there is a significant change in pH.

Buffer capacity depends on the concentrations of the components of the buffer - the greater the concentrations of the conjugate acid-base pair, the greater the buffer capacity.

The pH of the buffer is related to Kaand to the relative concentrations of the acid and base.


More acid base equilibria 17 1 17 3

Henderson-Hasselbalch equation – used for buffer solutions

(on AP equation sheet!!)

These equations technically use the equilibrium concentrations of the acid (base) and the conjugate base (acid).

However, since the acid/base in the buffer is WEAK – the amount of the conjugate produced by dissociation is generally small compared to the amount of the conjugate added as a salt. IF this is true (it is for all AP buffer problems!) we do not need to do an equilibrium problem – just use the INITIAL concentrations.


More acid base equilibria 17 1 17 3

Example 4 (Example 2 again!): Using equilibrium constants from Appendix D, calculate the pH of the solution containing 0.060 M KC3H5O2 and 0.085 M HC3H5O2


More acid base equilibria 17 1 17 3

Example 5: Calculate the pH of a buffer that is 0.12 M in lactic acid and 0.11 M in sodium lactate


More acid base equilibria 17 1 17 3

Example 6:A buffer is prepared by adding 20.0 g of acetic acid, HC2H3O2 and 20.0 g of sodium acetate to enough water to form 2.00 L of solution.

(a) Determine the pH of the buffer

(b) Write the complete ionic equation for the reaction that occurs when a few drops of hydrochloric acid are added to the buffer

(c) Write the complete ionic equation for the reaction that occurs when a few drops of sodium hydroxide are added to the buffer

(b) C2H3O2-1(aq) + H+1(aq) + Cl-1(aq) HC2H3O2 (aq) + Cl-1 (aq)

(c) HC2H3O2 (aq) + Na+1 (aq) + OH-1 (aq)  C2H3O2-1 (aq) + H2O (l) + Na+1 (aq)


More acid base equilibria 17 1 17 3

17.3 Acid-Base Titrations – Titration Curves

In an acid-base titration:

A solution of base (or acid) of known concentration (called standard) is added to an acid (or base).

Acid-base indicators or a pH meter are used to signal the equivalence point (when moles acid = moles base).

The plot of pH versus volume during a titration is called a pH titration curve.


More acid base equilibria 17 1 17 3

Strong acid added to strong base

Starts high

Ends low

Equivalence point = 7

equal moles of acid and base present

end

start


More acid base equilibria 17 1 17 3

Strong base added to strong acid

Starts low

Ends high

Equivalence point = 7

end

start


More acid base equilibria 17 1 17 3

Strong acid added to weak base

Starts med-high

Ends low

Equivalence point < 7

Buffer area – in this area there is weak base and some salt of the weak base

Actual pH depends on the salt formed

but it will be < 7


More acid base equilibria 17 1 17 3

Weak base added to strong acid

Starts low

Ends med-high

Equivalence point < 7

start

end


More acid base equilibria 17 1 17 3

Weak acid added to strong base

Starts high

Ends med-low

Equivalence point > 7

Actual pH depends on the salt formed

but it will be > 7

start

end


More acid base equilibria 17 1 17 3

Weak acid added weak base

Starts med-high

Ends med-low

Equivalence point = 7

start

end


More acid base equilibria 17 1 17 3

Strong base added to strong diprotic acid (H2SO4)


More acid base equilibria 17 1 17 3

Example 7: Predict whether the equivalence point of each of the following titrations is below, above or at pH 7:

a) NaHCO3 titrated with NaOH b) NH3 titrated with HCl

c) KOH titrated with HBr

At the equivalence point, only products are present in solution, so determine the products of the reaction and then determine if the solution is acidic, basic or neutral

a) NaHCO3 + NaOH Na2CO3 + H2O

weak acid strong base pH > 7

CO3-2 is basic, Na+ is neutral, H2O is neutral

b) NH3 + HCl NH4Cl

weak base strong acidpH < 7

NH4+1 is acidic, Cl- is neutral

c) KOH + HBrKBr + H2O

strong base strong acidpH = 7

K+ and Br- are both neutral


More acid base equilibria 17 1 17 3

Example 8: How many mL of 0.0850 M NaOH solution is required to titrate 40.0 mL of 0.0900 M HNO3?

? mL 40.0 mL

0.0850 M 0.0900 M

NaOH + HNO3 H2O + NaNO3

1 mole 1 mole


More acid base equilibria 17 1 17 3

Example 9: A 20.0 mL sample of 0.200 M HBr solution is titrated with 0.200 M NaOH solution. Calculate the pH of the solution after the following volumes of base solution have been added:

(a) 15.0 mL (b) 19.9 mL (c) 20.0 mL (d) 20.1 mL (e) 35.0 mL

mLmLmLmol H+1mol OH-1 M ofpH

HBrNaOHTotal(M) (V)(M) (V)excess ion

(mol / tot vol)

(a)20.015.035.00.004000.003000.0286 M H+11.544

(b)20.019.939.90.004000.003980.0005 M H+13.3

(c)20.020.040.00.004000.004001 x 10-7 M H+1*7.0

(d)20.020.140.10.004000.004020.0005 M OH-110.7

  • 20.035.055.00.004000.007000.0545 M OH-112.736

    When molarity of H+ (or OH-) is less than 10-6 we must consider the autoionization of water!

    (H+ = 1.0*10-7)


More acid base equilibria 17 1 17 3

Example 10: Calculate the pH at the equivalence point for titrating 0.200 M solutions of each of the following bases with 0.200 M HBr: (a) NaOH (b) NH2OH

(a) strong acid/strong base titration so pH = 7

(b) HBr + NH2OH  Br- + NH2OH2+

strong acid weak base

.200M .200M

all product at equivalence point – no excess & Br- is neutral and will have no affect on pH

Volume doubles (equal molarity and 1:1 stoich ratio) so molarity halves

[NH2OH2+] = 0.200mol / 2 = 0.100 M

NH2OH2+ H+1 + NH2OH Kb = 1.1 x 10-8(appendix)

I.100 0 0

C -x +x +x

E0.100 – x xx

Ka = Kw / Kb = 1  10-14 / 1.1  10-8 = 9.1  10-7

(x2) / (0.100-x) = 9.1 x 10-7

x = 3.0 x 10-4 M = [H+1]

pH = - log(3.0 x 10-4) = 3.52


Acid base indicators

The equivalence point of an acid-base titration can be determined by measuring pH, but it can also be determined by using an acid-base indicator which marks the end point of a titration by changing color.

Although the equivalence point (defined by the stoichiometry) is not necessarily the same as the end point (where the indicator changes color), careful selection of the indicator can ensure that the difference between them is negligible.

Acid-base indicators are complex molecules that are themselves, weak acids (represented by HIn).

They exhibit one color when the proton is attached and a different color when the proton is absent.

Acid – Base Indicators


Acid base indicators1

Acid – Base Indicators

Bromthymol Blue Indicator

In Acid In Base


Acid base indicators2

Acid – Base Indicators

Methyl Orange Indicator

In Acid In Base


Acid base indicators3

Acid – Base Indicators

Phenolphthalein color at different pH values

pH values 5 6 7 8 9


Acid base indicators4

Consider a hypothetical indicator, HIn, a weak acid with Ka=1.0x10-8. It has a red color in acid and a blue color in base.

HIn(aq)  H+1(aq) + In-1(aq)

red blue

Acid – Base Indicators


Acid base indicators5

HIn(aq)  H+1(aq) + In-1(aq)

red blue

This ratio shows that the predominant form of the indicator is HIn, resulting in a red solution. As OH-1 is added (like in a titration) [H+1] decreases and the equilibrium shifts to the right, changing HIn to In-. At some point in the titration, enough of the In- form will be present so we start to notice a color change.

Acid – Base Indicators


Acid base indicators6

It can be shown (using the Henderson-Hasselbalch equation) that for a typical acid-base indicator with dissociation constant, Ka, the color transition occurs over a range of pH values given by pKa ± 1.

For example, bromthymol blue with Ka = 1.0 x 10-7 (pKa = 7), would have a useful pH range of 7 ± 1 or from 6 to 8.

You want to select an indicator whose pKa value is close to the pH you want to detect (usually the pH at the equivalence point)

Acid – Base Indicators


Acid base indicators7

Acid – Base Indicators


More acid base equilibria 17 1 17 3

The pH curve for the titration of 100.0 mL of 0.10 MHCl with 0.10 MNaOH. Neither of theindicators shown wouldbe useful for atitration. Bromthymolblue (pKa=7) would beuseful.


More acid base equilibria 17 1 17 3

The pH curve for the titration of 50 mL of 0.1 M HC2H3O2 with 0.1 M NaOH. Here, phenolphthalein is the indicator of choice. It has a pKa value of about 9.


More acid base equilibria 17 1 17 3

Example 11: Use the following table to determine which of the following would be the best indicator to use to indicate the equivalence point of the titrations described in Example 10.

  • pH at equivalence point was 7.0

    Bromthymol Blue

    b. pH at equivalence point was 3.52

    Methyl Yellow


Solubility equilibria complex ions

Solubility Equilibria & Complex Ions

17.4 – 17.6


More acid base equilibria 17 1 17 3

Know your solubility rules:

SOLUBILITY GUIDELINES

Soluble CompoundsExceptions

NOT precipitatesPRECIPITATES

NitratesNone

AcetatesNone

ChloratesNone

ChloridesAg+1, Hg2+2, Pb+2

BromidesAg+1, Hg2+2, Pb+2

IodidesAg+1, Hg2+2, Pb+2

SulfatesCa+2, Sr+2, Ba+2, Hg2+2, Pb+2

Insoluble CompoundsExceptions

PRECIPITATESNOT Precipitates

SulfidesNH4+1, Li+1, Na+1, K+1, Ca+2, Sr+2, Ba+2

CarbonatesNH4+1, Li+1, Na+1, K+1

PhosphatesNH4+1, Li+1, Na+1, K+1

HydroxidesLi+1, Na+1, K+1, Ca+2, Sr+2, Ba+2

ChromatesNH4+1, Li+1, Na+1, K+1, Ca+2, Mg+2

We classify these based on the

Solubility - maximum

amount of solute that dissolves

in water.


More acid base equilibria 17 1 17 3

17.4 Solubility Equilibria

The Solubility-Product Constant, Ksp

Consider a saturated solution of BaSO4 in contact with solid BaSO4.

We can write an equilibrium expression for the dissolving of the solid.

BaSO4(s)  Ba2+(aq) + SO42–(aq)

Since BaSO4(s) is a pure solid, the equilibrium expression depends only on the concentration of the ions.

Ksp= [Ba2+][ SO42–]

Ksp is the equilibrium constant for the equilibrium between an ionic solid solute and its saturated aqueous solution.

Ksp is called the solubility-product constant


More acid base equilibria 17 1 17 3

  • In general: the solubility product is equal to the product of the molar concentration of ions raised to powers corresponding to their stoichiometric coefficients.

Al2(CO3)3 2 Al+3 + 3 CO3-2

Ksp = [Al+3]2 [CO3-2]3


More acid base equilibria 17 1 17 3

Solubility and Ksp

Solubility is the amount of substance that dissolves to form a saturated solution.

This can be expressed as grams of solid that will dissolve per liter of solution.

Molar solubility- the number of moles of solute that dissolve to form a liter of saturated solution.

Solubility can be used to find Ksp and Ksp can be used to find solubility (see problems)


More acid base equilibria 17 1 17 3

Example 1:

a. If the molar solubility of CaF2 at 35oC is 1.24  10-3mol/L, what is Ksp at this temperature?

CaF2 Ca+2+ 2 F-1

E .00124M actually dissolves

Ksp= [Ca+2] [F-1]2 = (.00124 M)(.00248 M)2 = 7.63 x 10-9

b. It is found that 1.1  10-2 g of SrF2 dissolves per 100 mL of aqueous solution at 25oC. Calculate the solubility product of SrF2.

[SrF2] = (.011 g / 125.6 g/mole) / .100 L = .00088 M

SrF2 Sr+2 + 2 F-1

E .00088 M .00088 M 2(.00088) = .00176 M

Ksp = [Sr+2] [F-1]2 = (.00088 M)(.00176)2 = 2.7 x 10-9

.00124 M 2(.00124) = .00248 M


More acid base equilibria 17 1 17 3

c. The Ksp of Ba(IO3)2 at 25oC is 6.0  10-10. What is the molar solubility of Ba(IO3)2?

Ba(IO3)2 Ba+2 + 2 IO3-1

E x

(x) (2x)2 = 4 x3= 6.0 x 10-10

x = 5.3 x 10-4M

x 2 x


More acid base equilibria 17 1 17 3

17.5 Factors That Affect Solubility

Factors that have a significant impact on solubility are:

- The presence of a common ion

- The pH of the solution

Common-Ion Effect

Solubility is decreased when a common ion is added.

This is an application of Le Châtelier’s principle:

Consider the solubility of CaF2:

CaF2(s)  Ca2+(aq) + 2F–(aq)

If more F– is added (say by the addition of NaF), the equilibrium shifts left to offset the increase.

Therefore, more CaF2(s) is formed (precipitation occurs).


More acid base equilibria 17 1 17 3

Example 2: Using Appendix D, calculate the molar solubility of AgBr in (a) pure water (b) 3.0  10-2 M AgNO3 solution (c) 0.50 M NaBr solution

(a) AgBr Ag+1 + Br-1Ksp = 5.0  10-13

E x x x

5.0  10-13 = x2

x = 7.1  10-7 M

(b) AgBr Ag+1 + Br-1Ksp = 5.0  10-13

E x .030 + x x

5.0  10-13 = (.030+x) x

x = 1.7  10-11 M

(c) AgBr Ag+1 + Br-1Ksp = 5.0  10-13

x x .50 + x

5.0  10-13 = x (.50+x)

x = 1.0  10-12 M

notice the DECREASED solubility with the common ion in (b) and (c)


More acid base equilibria 17 1 17 3

pH effects

Consider: Mg(OH)2(s)  Mg2+(aq) + 2 OH–(aq)

If OH– is removed, then the equilibrium shifts right and Mg(OH)2 dissolves.

OH– can be removed by adding a strong acid (lowering the pH):

OH–(aq) + H+(aq)  H2O(aq)

Another example:

CaF2(s)  Ca2+(aq) + 2 F–(aq)

If the F– is removed, then the equilibrium shifts right and CaF2 dissolves.

F– can be removed by adding a strong acid (or lowering pH):

F–(aq) + H+(aq)  HF(aq)


More acid base equilibria 17 1 17 3

Example 3: Calculate the molar solubility of Mn(OH)2 at (a) pH 7.0 (b) pH 9.5 (c) pH 11.8

the [OH-1] is set by the pH (or pOH)

(a) pH = 7.0 so pOH = 7.0 so [OH-1] = 1.00  10-7

Mn(OH)2 Mn+2 + 2 OH-1Ksp = 1.6  10-13

x x 1.00 x 10-7

Ksp = [Mn+2][OH-1]2

1.6  10-13 = (x) (1.00  10-7)2

x = 16 M

(b) pH = 9.5 so pOH = 4.5 so [OH-1] = 3.16  10-5

Mn(OH)2 Mn+2 + 2 OH-1Ksp = 1.6  10-13

x x 3.16 x 10-5

Ksp = [Mn+2][OH-1]2

1.6  10-13 = (x) (3.16  10-5)2

x = 1.7  10-4 M

(c) pH = 11.8 so pOH = 2.2 so [OH-1] = 6.31  10-3

Mn(OH)2 Mn+2 + 2 OH-1Ksp = 1.6  10-13

x x 6.31 x 10-3

Ksp = [Mn+2][OH-1]2

1.6  10-13 = (x) (6.31  10-3)2

x = 4.0  10-9 M

Common ion effect – increasing [OH-] decreases solubility


More acid base equilibria 17 1 17 3

Example 4: Which of the following salts will be substantially more soluble in acidic solution than in pure water:

(a) ZnCO3 (b) ZnS (c) BiI3 (d) AgCN (e) Ba3(PO4)2

If the anion of the salt is the conjugate base of a weak acid, it will combine with H+1, reducing the concentration of the anion and making the salt more soluble

ZnCO3 Zn+2 + CO3-2

the CO3-2 ion will react with the added H+

CO3-2 + H+ HCO3-1

Le Chatelier effect of removing CO3-2

more soluble in acid: ZnCO3, ZnS, AgCN, Ba3(PO4)2


More acid base equilibria 17 1 17 3

17.6 Precipitation and Separation of Ions

Consider the following:

BaSO4(s)  Ba2+(aq) + SO42–(aq)

At any instant in time, Q = [Ba2+][ SO42– ]

If Q > Ksp, (too many ions) precipitation occurs until Q = Ksp. If Q = Ksp equilibrium exists (saturated solution)

If Q < Ksp, (not enough ions) solid dissolves until Q = Ksp.

Selective Precipitation of Ions

Removal of one metal ion from a solution of two or more metal ions is called selective precipitation.

Ions can be separated from each other based on the solubilities of their salt compounds.

Example: If HCl is added to a solution containing Ag+ and Cu2+, the silver precipitates (as AgCl) while the Cu2+ remains in solution

Generally, the less soluble ion is removed first!


More acid base equilibria 17 1 17 3

Example 5: Will Ca(OH)2 precipitate if the pH of a 0.050 M solution of CaCl2 is adjusted to 8.0?

if Q > than Ksp then precipitation will occur

pH = 8.0 so pOH = 6.0 so [OH-1] = 1.0  10-6 M

Ca(OH)2 Ca+2 + 2 OH-1Ksp = 6.5  10-6

.050 1.00 x 10-6

Q = [Ca+2] [OH-1]2

Q = (.050)(1.0  10-6)2 = 5.0  10-14

Q < K so no precipitation occurs


More acid base equilibria 17 1 17 3

Example 6: A solution contains 0.00020 M Ag+1 and 0.0015 M Pb+2 . If NaI is added, will AgI or PbI2 precipitate first? Specify the [I-1] needed to begin precipitation for each cation.

the cation needing the lower [I-1] will precipitate first

AgI Ag+1 + I-1Ksp = 8.3 x 10-17

.000200 x

Ksp = [Ag+1][x]

8.3  10-17 = (.00020)[x]

4.2  10-13 = x = [I-1]

PbI2 Pb+2 + 2 I-1Ksp = 1.4 x 10-8

0.0015 x

Ksp = [Pb+2][x]2

1.4  10-8 = (.0015)[x]2

3.1  10-3 = x = [I-1]

AgI will precipitate first at an [I-1] = 4.2  10-13


Complex ions

  • Complex ion – a metal ion bonded to one or more Lewis bases. (We saw this with water in chapter 16)

Complex Ions


More acid base equilibria 17 1 17 3

  • It can happen with other Lewis bases (things that have lone pairs of electrons)

  • Rule of thumb: The number of Lewis bases (ligands) that a metal ion attracts is equal to double its charge. (Works about 75% of the time!)


More acid base equilibria 17 1 17 3

  • Extra Stuff Below…


Acid base indicators8

How much In- must be present for the human eye to detect that the color is different? For most indicators, about 1/10 of the initial form must be converted to the other form before a color change is apparent. We can assume that in the titration of an acid with a base, the color change will occur at a pH where

Acid – Base Indicators


Acid base indicators9

Bromthymol blue, an indicator with a Ka = 1.0 x 10-7, is yellow in its HIn form and blue in its In- form. Suppose we put some strong acid in a flask, add a few drops of bromthymol blue and titrate with NaOH. At what pH will the indicator color change first be visible?

HIn(aq)  H+1(aq) + In-1(aq)

yellow blue

Acid – Base Indicators


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Selective Precipitation of Ions (continued)

Sulfide ion is often used to separate metal ions.

Example: Consider a mixture of Zn2+(aq) and Cu2+(aq).

CuS (Ksp= 6 x 10–37)is less soluble than ZnS (Ksp= 2 x 10–25).

Because CuS is LESS SOLUBLEthan ZnS, CuS will be removed from solution before ZnS.

As H2S is bubbled through the acidified green solution, black CuS forms.

When the precipitate is removed, a colorless solution containing Zn2+(aq) remains.

When more H2S is added to the solution, a second precipitate of white ZnS forms.


More acid base equilibria 17 1 17 3

Formula Type of Formula of Hydrolysis equation Hydrolysis equation

acid or conjugate of the acid of the base

base acid or base

HCl

HOCl

NH3

Ba(OH)2

KI

NaC2H3O2

Cl-1

HCl + H2O  H3O+1 + Cl-1

Strong acid

Cl-1 + H2O  X

Weak acid

OCl-1

HOCl + H2O  H3O+1 + OCl-1

OCl-1 + H2O  HOCl + OH-1

Weak base

NH4+1

NH3 + H2O  OH-1 + NH4+1

NH4+1 + H2O  H3O+1 + NH3

Strong base

OH-1 + H2O  X

H2O

H2O + H2O  H3O+1 + OH-1

K+1 or I-1

neutral

I-1 + H2O  X

K+1 + H2O  X

weak base

HC2H3O2

HC2H3O2 + H2O  H3O+1 + C2H3O2-1

C2H3O2-1 + H2O  HC2H3O2 + OH-1


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