1 / 30

Catálisis y Cinética

Catálisis y Cinética. Henry Taube (1915 – 2005). Premio Nobel 1983 I became curious as well about the reasons underlying the enormous difference in rates of substitution for metal ions of the same charge and (approximately) the same radii. Efecto de la configuración electrónica.

nicki
Download Presentation

Catálisis y Cinética

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Catálisis y Cinética

  2. Henry Taube (1915 – 2005) • Premio Nobel 1983 • I became curious as well about the reasons underlying the enormous difference in rates of substitution for metal ions of the same charge and (approximately) the same radii.

  3. Efecto de la configuración electrónica

  4. Efecto de la configuración electrónica

  5. Mecanismos de Sustitución Disociativo

  6. Mecanismos de Sustitución Disociativo Asociativo

  7. Mecanismos de Sustitución Disociativo Asociativo Intercambio

  8. Efecto de la configuración electrónica

  9. Mecanismos de Sustitución Disociativo

  10. Mecanismos de Sustitución Disociativo Asociativo

  11. Mecanismos de Sustitución Disociativo Asociativo Intercambio

  12. Efecto del Ligando Saliente [Fe(CN)5L]3- + Mepz+  [Fe(CN)5Mepz]2- + L

  13. [Co(NH3)5X]3+ + H2O  [Co(NH3)5H2O]3+ + L

  14. Retención de la Configuración

  15. V = k1l[Comp] + k2[Comp][Y] V = (k1 + k2[Y]) [Comp]

  16. Efecto de la Temperatura

  17. Efecto trans Enlance Sigma Enlance 

More Related