1 / 5

D G #

Ge. Me. Ge. Me. Me. D G #. eq. (eq->#; see below). G. ax. Ge. Me. Ge. Me. Me analysis:. D G #. (eq->#). Average:. D G # = D H # -T D S # => D H # = 3.92 kcal mol -1 ; D S # = +0.0089 kcal mol -1 K -1 / +8.9 cal mol -1 K -1. T corr. Analysis results:

lester
Download Presentation

D G #

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript


  1. Ge Me Ge Me Me

  2. DG# eq (eq->#; see below) G ax Ge Me Ge Me

  3. Me analysis: DG# (eq->#) Average: DG# = DH# -TDS# => DH# = 3.92 kcal mol-1; DS# = +0.0089 kcal mol-1K-1 / +8.9 cal mol-1K-1 Tcorr

  4. Analysis results: K (eq -> ax): + 0.78 DG(eq ->ax): + 0.057 kcal /mol (for T = 114 K) Average DG#(eq->#): 5.0 +/- 0.1 kcal/mol (4.97 +/- 0.08 kcal/mol) for temperature range 106 – 134 K

  5. Exp. Calc. T(K) keq,ax(s-1 ) 125 117 114 112 110 107 3800 1200 720 530 400 240 Dd/ppm

More Related