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1. Topic 5:DIFFUSION IN SOLIDS
2. Topic 5:DIFFUSION IN SOLIDS
3. DIFFUSIONPhenomenon of material transport by atomic or particle transport from region of high to low concentration What forces the particles to go from left to right?
Does each particle “know” its local concentration?
Every particle is equally likely to go left or right!
At the interfaces in the above picture, there are more particles going right than left ? this causes an average “flux” of particles to the right!
Largely determined by probability & statistics
4. DIFFUSION DEMO
5. DIFFUSION: THE PHENOMENA (1)
6. DIFFUSION: THE PHENOMENA (2)
7. DIFFUSION MECHANISMS
8. DIFFUSION MECHANISMS
9. ACTIVATION ENERGY FOR DIFFUSION Also called energy barrier for diffusion
10. DIFFUSION SIMULATION
11. INTERSTITIAL SIMULATION
12. PROCESSING USING DIFFUSION (1)
13. PROCESSING USING DIFFUSION (2)
14. MODELING DIFFUSION: FLUX
15. CONCENTRATION PROFILES & FLUX
16. STEADY STATE DIFFUSION
17. EX: STEADY STATE DIFFUSION
18. STEADY STATE DIFFUSION: ANOTHER PERSPECTIVE Hose connected to tap; tap turned on
At the instant tap is turned on, pressure is high at the tap end, and 1 atmosphere at the other end
After steady state is reached, pressure linearly drops from tap to other end, and will not change anymore
19. NON STEADY STATE DIFFUSION
20. EX: NON STEADY STATE DIFFUSION
21. EX: NON STEADY STATE DIFFUSION
22. PROCESS DESIGN EXAMPLE
23. DIFFUSION DEMO: ANALYSIS Typically, we let the experiment described on slide 2 run during the class; at this point in the class, the results are available for the class to look at.Typically, we let the experiment described on slide 2 run during the class; at this point in the class, the results are available for the class to look at.
24. DATA FROM DIFFUSION DEMO
25. PROCESSING QUESTION
26. DIFFUSION AND TEMPERATURE
27. ACTIVATION ENERGY FOR DIFFUSION Also called energy barrier for diffusion
28. DIFFUSION AND TEMPERATURE
29. SUMMARY:STRUCTURE & DIFFUSION