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The Periodic Table

The Periodic Table. Unit 4A. Ion = + or – charged atom. +1. Charge. 0. +2. 8. 1. Valance Electrons. +3. Skip. -2. -1. -3. 6. 7. 5. 2. 3. 4. Various positive charges. 2. Ions. Cations: Positively Charged Formed by the lost of electrons Metals form cations

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The Periodic Table

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  1. The Periodic Table Unit 4A

  2. Ion = + or – charged atom +1 Charge 0 +2 8 1 Valance Electrons +3 Skip -2 -1 -3 6 7 5 2 3 4 Various positive charges 2

  3. Ions Cations: • Positively Charged • Formed by the lost of electrons • Metals form cations • Silver always +1 • Zinc and Cadmium always +2 Anions: • Negatively Charged • Formed by gaining electrons • Nonmetals form anions • Noble gases never have a charge

  4. Why do atoms form ions? • Valance electrons are electrons in the outermost shell • The octet rule is a chemical rule of thumb that states that atoms of main-group elements tend to combine in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. • Exception: Hydrogen and Helium only need a duet (2 valance electrons) • Valance electrons are gained, lost, or shared in order to achieve an octet

  5. Polyatomic Ions • Monatomic ions- an atom with an overall charge consisting of one element • Polyatomic ion- A group of elements with an overall charge. Polyatomic ions act as one single unit. • Common polyatomic ions are listed on the back of your periodic table

  6. Examples

  7. Diatomic Molecules • Diatomic Molecules- 2 atoms of the same element chemically bonded together • 7 Diatomic Molecules • Br I N Cl H O F • They form a 7 on the Periodic Table

  8. How to count Atoms • If there is no numbers by the symbol of the element, assume only one • Na • MgO • A subscript is a number written at the lower right corner of the chemical symbol. If there is more than one, then a number is used. • H2 • Li2O

  9. How to count Atoms • A subscript outside a multiples all the elements inside the parenthesis. • Mg3(PO4)2 • A coefficient is a number written in front of a chemical symbol or in front of a chemical formula which indicates the number of atoms or molecules of the substance. • 3 C • 2 H2O

  10. Lets Practice counting Atoms… • NaCO3 • Ca3(PO4)2 • K2CrO4 • 3 BaCl2 • NH4C2H3O2 • 4 Al2(CO3)3 • Pb(NO3)2 • 2 (NH4)2Cr2O7 • 1 Na, 1 C, 3 O • 3 Ca, 2 P, 8 O • 2 K, 1 Cr, 4 O • 3 Ba, 6 Cl • 1 N, 7 H, 2 C, 2O • 8 Al, 12 C, 36 O • 2 Pb, 2 N, 6 O • 4 N, 16 H, 4 Cr, 14 O

  11. Periodic Trends • Atomic Radius • Ionic Radius • Ionization Energy • Electronegativity • Metallic Characteristic

  12. Atomic Radius • Atomic Radius is defined ½ the distance between nuclei of atoms bonded together • The radius decreases going across a row and increases going down a column.

  13. Atomic Radius Periodic Trends

  14. Atomic Radius Periodic Trends “9:30 trend” (arrows point in the increasing direction) • Atomic radius increase as we move from right to left • Atomic radius increases as we move from top to bottom • Where is the element with the largest atomic radius located? What element is it? • Bottom left corner • Francium (Fr)

  15. Why Atomic Radius Trends? • Why are atoms larger going down a group? • Atoms are larger because the higher the energy level, the more orbitals the atom has, which means the larger the electron orbitals are. • Why do atoms get smaller going to from left to right across the row? • There is an increases in nuclear charge (more protons)

  16. Practice- Atomic Radius Which of the following has the largest atomic radius? • Cobalt or Nickel • Phosphorous or Nitrogen • Potassium or Oxygen List the following in order of increasing atomic radius. • Fluorine, gallium, and carbon • Barium, iodine, and gold List the following in order of decreasing atomic radius. • Aluminum, Sulfur, and sodium F, C, Ga I, Au, Ba Na, Al, S

  17. Ionic Radius • Radius of the atom once it becomes an ion • A cation has a smaller radius than its atom • An anion has a larger radius than its atom

  18. Practice • Which of the following has a larger radius? • Calcium atom or calcium ion? • Calcium Atom • Manganese atom or manganese ion? • Manganese atom • Selenium atom or selenium ion? • Selenium ion • Chlorine atom or chlorine ion? • Chlorine ion

  19. Ionization Energy • Ionization Energy is the energy required to completely remove an electron from a atom or an ion. • “3 o’clock trend” • Increases from bottom to top • Increases from left to right *Ignore Noble Gases (they do not become ions)

  20. Practice- Ionization Energy Which of the following has the largest ionization energy? • Cobalt or Nickel • Phosphorous or Nitrogen • Potassium or Oxygen List the following in order of increasing ionization energy. • Fluorine, gallium, and carbon • Barium, iodine, and gold List the following in order of decreasing ionization energy. • Aluminum, Sulfur, and sodium Ga, C, F Ba, Au, I S, Al, Na

  21. Electronegativity • Electronegativity is a measure of attraction of an atom for the electrons in a chemical bond. • “3 o’clock trend” • Increases from bottom to top • Increases from left to right • *Ignore Noble Gases (they do not attract ions)

  22. Practice- Electronegativity Which of the following has the largest electronegativity? • Cobalt or Nickel • Phosphorous or Nitrogen • Potassium or Oxygen List the following in order of increasing electronegativity. • Fluorine, gallium, and carbon • Barium, iodine, and gold List the following in order of decreasing electronegativity. • Aluminum, Sulfur, and sodium Ga, C, F Ba, Au, I S, Al, Na

  23. Periodic Trends • Ionization Energy and Electronegativity have the same periodic trend (3 o’clock). • The electrons of smaller atoms are closer to the nucleus = stronger attraction = harder to pull electrons away from atom. • Larger atoms = valence electrons are further away = electrons are easier to steal

  24. Metal Reactivity and Metallic Characteristic “9:30 trend” (arrows point in the increasing direction) • Metal reactivity and Metallic characteristic increase as we move from right to left • Metal reactivity increases as we move from top to bottom • Where is the most reactive metal located? What element is it? • Bottom left • Francium (Fr)

  25. Metal Reactivity • Activity Series for Metals: shows common and ranks the metals from most reactive and least reactive

  26. Practice- Metallic Characteristic Which of the following has the most metallic characteristics? • Cobalt or Nickel • Phosphorous or Nitrogen • Potassium or Oxygen List the following in order of increasing metallic characteristics. • Fluorine, gallium, and carbon • Barium, iodine, and gold List the following in order of decreasing metallic characteristics. • Aluminum, Sulfur, and sodium F, C, Ga I, Au, Ba Na, Al, S

  27. Periodic Trends Summarized Electronegativity and Ionization Energy Atomic Radius, Metallic Characteristic and Metal Reactivity Electronegativity and Ionization Energy Atomic Radius, Metallic Characteristic and Metal Reactivity Electronegativity and Ionization Energy Atomic Radius, Metallic Characteristic and Metal Reactivity

  28. Periodic and Group trends

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