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Confirmation of the Improbable

Confirmation of the Improbable. Evidence for a Terminal Pt(IV)-oxo Complex Exhibiting Diverse Reactivity. Transition Metal Oxo (TMO) Complex. a multiple bond between oxygen and the metal. Some Application of TMO Complexes. The catalytic oxidation of organic molecules

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Confirmation of the Improbable

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  1. Confirmation of the Improbable Evidence for a Terminal Pt(IV)-oxo Complex Exhibiting Diverse Reactivity

  2. Transition Metal Oxo (TMO) Complex a multiple bond between oxygen and the metal

  3. Some Application of TMO Complexes • The catalytic oxidation of organic molecules • Some oxidative enzymatic transformations • 3. The activation of dioxygen on metal surfaces

  4. Methane Hydroxylation by FeO+ Acc. Chem. Res., 2006, 39 (6), 375-382

  5. Peroxo Shunt Mechanism of Monooxygenases Producing Compound I Complex I Inorg. Chem., 2005, 44 (20), 6879-6892

  6. Something about TMO Complexes The terminal oxo ligand is a strong -electron donor, so it readily forms stable complexes with high-valent early transition metals As the d orbitals are filled up with valence electrons, the terminal oxo ligand becomes destabilized

  7. Late Transition Metal Oxo (LTMO) Complexes Until 1993 M : late transition elementL: general ligands Oxo-trimesityl-iridium(v), C27H33Ir=O Polyhedron, 1993,12, 2009–2012

  8. Preparation of Terminal OxoComplex 2

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