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Solid State Oxide Fluorides

Solid State Oxide Fluorides. Input Geometry. Output Geometry. Bridging F - Terminal O 2-. [Cu(3-apy) 4 ] 3 (Mo 2 O 6 F 3 ) 2. Of the three [Mo 2 O 6 F 3 ] 3- isomers shown above, there is only one that has a stable calculated geometry commensurate with the crystallographic data.

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Solid State Oxide Fluorides

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  1. Solid State Oxide Fluorides Input Geometry Output Geometry Bridging F- Terminal O2- [Cu(3-apy)4]3(Mo2O6F3)2 Of the three [Mo2O6F3]3- isomers shown above, there is only one that has a stable calculated geometry commensurate with the crystallographic data. Kenneth R. Poeppelmeier, Northwestern University, DMR-0312136 Goal: Specific identification of bridging or terminal ligands in the [Mo2O6F3]3- anion as either oxides or fluorides through combined experimental and theoretical analyses. • Structural comparisons with related oxide halide polyanions • Comparisons with other confacial bioctahedra • Geometry optimization calculations on uncoordinated [Mo2O6F3]3- Comparisons of single crystal data with those of related oxide halide polyanions support the theoretical findings.

  2. Solid State Oxide Fluorides Kenneth R. Poeppelmeier, Northwestern University, DMR-0312136 The NSF Division of Materials Research award supports a comprehensive and interdisciplinary educational program in inorganic solid state chemistry. Graduate Students:Dr. Paulette Guillory (Illinois Minority Graduate Incentive Program), Dr. Heather Izumi, Amy Kopf (PhD 2005), Mike Marvel (PhD 2007), Thomas Albrecht (PhD 2008), Julia Chamberlain (PhD 2009). Post Doctorals:Dr. Janet Kirsch, PhD University of Wyoming, Assistant Professor of Chemistry, University of Wisconsin – La Crosse 2005; Dr. Paul Maggard, PhD Iowa State, Assistant Professor of Chemistry, North Carolina State University 2002; Dr. Sylvie Malo, PhD Université de Caen, Maitre de Conferences (Assistant Professor), Université de Caen/Basse Normandie 2001. International Exchange:Professor Makoto Sasaki, Materials Science and Engineering Muroran Institute of Technology, Muroran, Japan, Dr. Keitaro Tezuka, PhD Hokkaido University, Dr. Masaaki Isobe, Advanced Materials Laboratory, National Institute for Materials Science, Tsukuba, Japan; Dr. Ha Kyun Jung, Advanced Materials Division, Korean Research Institute of Chemical Technology, Tacjon, Korea; Professor Tor Grande, Norwegian University of Science and Technology, Trondheim, Norway. Collaborators:Erin Sorensen (PhD 2005), ONR MURI Grant N00014-01-1-0810, Dr. John Vaughey, Argonne National Laboratory, Professor Shiv Halasyamani, University of Texas-Houston.

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