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‡. G. D. N. Unfolding process. Folding process. Rate is determined by this barrier. Rate is determined by this barrier. ‡. G. D. N. ‡. ‡*. G. D, D*. D G D - N. D G* D - N. N, N*. ‡. D G ‡ - D  1/ k f. G. D G ‡ - N  1/ k u. D. D G D - N. N. ‡. ‡*. D G* ‡ - N.

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G

D

N


Unfolding process

Folding process

Rate is determined by this barrier

Rate is determined by this barrier

G

D

N


‡*

G

D, D*

DGD - N

DG*D - N

N, N*


DG‡ - D  1/kf

G

DG‡ - N 1/ku

D

DGD - N

N


‡*

DG*‡ - N

DG*‡ - D

DG‡ - D

DG‡ - N

G

D

D*

DG*D - N

N*

DGD - N

DDGD - N

N


‡*

DG‡ - D

DG‡ - N

G

DG*‡ - D

DG*‡ - N

D,

D*

DDGD - N

DGD - N

DG*D - N

N

N*


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