Relationships of McMillan-Mayer and Lewis-Randall Framework. Kim, Yong-Soo Thermodynamics & Properties Lab. Korea University. Introduction. The need for a thermodynamic framework for prediction and correlation of phase equilibria
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Relationships of McMillan-Mayerand Lewis-Randall Framework
Thermodynamics & Properties Lab.
T, P0, X’
T, P=P0+П, X
chemical potentials of solvents and numer of moles of solutes
Solvents and Solutes
T, P, X
number of moles of solutes
Figure 1.Osmotic coefficients MM and LR for water+LiCl system at 60C
Figure 2. Correction (solid line) and ratio to total lnγLR(dashes)