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11.1 维生素的定义和分类 11.2 NAD + 和 NADP + 是尼克酸的衍生物 11.3 FAD 和 FMN 是含有核黄素的核苷酸 11.4 辅酶 A 是泛酸的衍生物 PowerPoint PPT Presentation


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第 11 章、维生素与 辅酶. 11.1 维生素的定义和分类 11.2 NAD + 和 NADP + 是尼克酸的衍生物 11.3 FAD 和 FMN 是含有核黄素的核苷酸 11.4 辅酶 A 是泛酸的衍生物 11.5 硫胺素焦磷酸是维生素 B 1 的衍生物硫胺素的衍生物 11.6 磷酸吡哆醛是维生素 B 6 的衍生物 11.7 生物素是某些羧化酶的辅基 11.8 四氢叶酸是蝶呤的衍生物 11.9 维生素 B 12 和它的辅酶形式都含有钴 11. 10 硫辛酸是参与酰基转移反应的辅助因子 11.11 维生素 C

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11.1 维生素的定义和分类 11.2 NAD + 和 NADP + 是尼克酸的衍生物 11.3 FAD 和 FMN 是含有核黄素的核苷酸 11.4 辅酶 A 是泛酸的衍生物

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11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11

11.1

11.2 NADNADP

11.3 FADFMN

11.4 A

11.5 B1

11.6 B6

11.7

11.8

11.9 B12

11. 10

11.11 C

11.12


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

AB

AB

AB


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.1


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

C

B

B1

B2

B3

B12

B6

A

D

E

K


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

B


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.2NADNADP

INADIINADP


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

NADNADPNADHNADPH


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.3FADFMN

FMNFAD

B256,7-


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

FADFMNFADFMN445~450nmFADH2FMNH2

FMNH2FADH2NADHNADPHNADHNADPHFMNH2FADH22

FMNHFADH


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.4 A

-SH-3-ADP

AA

ACoA

COA


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.5 B1

B1

TPP

TPP


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

2ACoA


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

B1


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

B1


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.6 B6

B6


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

PLPPLP- Schiff E-PLPPLPSchiff

R1R2R1R2


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.7

--


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

-


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.8

2--4-p-


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

5,6,7,8-FH4


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.9 B12

B12B12

B12 5-

CoACoACoA


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

B12

B12


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.10

C-6C-88a

-b

c

ANAD d


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

-


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

NAD


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.11 C

CCC

C

C


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

C


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

  • C

  • CE

  • CC


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

11.12

A. A

A1530-

A


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

1 cis

2cistrans

3

4

5cis

A


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

B.D

DD2D3DD37-

D1,25-D3


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

C.E

E-

EE


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

D. K

K-

-Ca2+-


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

1. NADNADPH-NADNADP4NADHNADPHHNADHNADPH340nmNADNADP

2. B2FADFMNFADFMNFADH2FMNH2FADHFMNH


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

3. ACoAATP

4. B1TPP-TPP

5. PLPPLPPLP

6. ATP-


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

7. dTMP

8. B12

9. -A


11 1 11 2 nad nadp 11 3 fad fmn 11 4 a

10. CCC

11.ADEKADCa2EK


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